Superior adsorptive removal of anionic dyes by MIL-101 analogues: the effect of free carboxylic acid groups in the pore channels

CrystEngComm ◽  
2019 ◽  
Vol 21 (38) ◽  
pp. 5824-5833 ◽  
Author(s):  
Ji-Min Yang ◽  
Run-Zhi Zhang ◽  
Ying-Yan Liu

MIL-101-COOH nanoparticles functionalized with free carboxylic acid groups exhibited superior CR, MO, and AC adsorption capacities via their distinctive adsorption mechanisms.

2020 ◽  
Vol 49 (20) ◽  
pp. 6651-6660
Author(s):  
Ji-Min Yang ◽  
Wei Zhang ◽  
Run-Zhi Zhang ◽  
Meng-Xuan Tong

MIL-101-SO3H analogues functionalized with –SO3H groups exhibited superior CR, MO and AC adsorption capacities because of their distinct adsorption mechanisms.


Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 502
Author(s):  
Hanene Belkahla ◽  
Andrei Alexandru Constantinescu ◽  
Tijani Gharbi ◽  
Florent Barbault ◽  
Alexandre Chevillot-Biraud ◽  
...  

Tumor necrosis factor (TNF)-related apoptosis-inducing ligand (TRAIL) is a member of the TNF cytokine superfamily. TRAIL is able to induce apoptosis through engagement of its death receptors DR4 and DR5 in a wide variety of tumor cells while sparing vital normal cells. This makes it a promising agent for cancer therapy. Here, we present two different ways of covalently grafting TRAIL onto maghemite nanoparticles (NPs): (a) by using carboxylic acid groups of the protein to graft it onto maghemite NPs previously functionalized with amino groups, and (b) by using the amino functions of the protein to graft it onto NPs functionalized with carboxylic acid groups. The two resulting nanovectors, NH-TRAIL@NPs-CO and CO-TRAIL@NPs-NH, were thoroughly characterized. Biological studies performed on human breast and lung carcinoma cells (MDA-MB-231 and H1703 cell lines) established these nanovectors are potential agents for cancer therapy. The pro-apoptotic effect is somewhat greater for CO-TRAIL@NPs-NH than NH-TRAIL@NPs-CO, as evidenced by viability studies and apoptosis analysis. A computational study indicated that regardless of whether TRAIL is attached to NPs through an acid or an amino group, DR4 recognition is not affected in either case.


Author(s):  
T. G. Ambaye ◽  
M. Vaccari ◽  
E. D. van Hullebusch ◽  
A. Amrane ◽  
S. Rtimi

AbstractCurrently, due to the rapid growth of urbanization and industrialization in developing countries, a large volume of wastewater is produced from industries that contain chemicals generating high environmental risks affecting human health and the economy if not treated properly. Consequently, the development of a sustainable low-cost wastewater treatment approach has attracted more attention of policymakers and scientists. The present review highlights the recent applications of biochar in removing organic and inorganic pollutants present in industrial effluents. The recent modes of preparation, physicochemical properties and adsorption mechanisms of biochar in removing organic and inorganic industrial pollutants are also reviewed comprehensively. Biochar showed high adsorption of industrial dyes up to 80%. It also discusses the recent application and mechanism of biochar-supported photocatalytic materials for the degradation of organic contaminants in wastewater. We reviewed also the possible optimizations (such as the pyrolysis temperature, solution pH) allowing the increase of the adsorption capabilities of biochar leading to organic contaminants removal. Besides, increasing the pyrolysis temperature of the biochar was seen to lead to an increase in its surface area, while it decreases their amount of oxygen-containing functional groups, consequently leading to a decrease in the adsorption of metal (loid) ions present in the medium. Finally, the review suggests that more research should be carried out to optimize the main parameters involved in biochar production and its regeneration methods. Future efforts should be also carried out towards process engineering to improve its adsorption capacity to increase the economic benefits of its implementation.


2014 ◽  
Vol 5 (8) ◽  
pp. 3061-3070 ◽  
Author(s):  
Yohei Kotsuchibashi ◽  
Ravin Narain

Dual-temperature and pH responsive (ethylene glycol)-based nanogels were synthesized. Both the core and the shell of the nanogels showed a lower critical solution temperature (LCST) and the LCST of the shell was strongly affected by the solution pH and salt concentration due to the presence of carboxylic acid groups at the nanogel surface.


2005 ◽  
Vol 99 (3) ◽  
pp. 697-705 ◽  
Author(s):  
Bernabé L. Rivas ◽  
Benita Quilodrán ◽  
Eduardo Quiroz

1992 ◽  
Vol 4 (4) ◽  
pp. 769-775 ◽  
Author(s):  
Harry R. Allcock ◽  
Richard J. Fitzpatrick ◽  
Lawrence Salvati

2007 ◽  
Vol 17 (7) ◽  
pp. 616 ◽  
Author(s):  
Rola Mouawia ◽  
Ahmad Mehdi ◽  
Catherine Rey? ◽  
Robert Corriu

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