“Water soluble” palladium nanoparticle engineering for C–C coupling, reduction and cyclization catalysis

2019 ◽  
Vol 21 (24) ◽  
pp. 6646-6657 ◽  
Author(s):  
A. Iben Ayad ◽  
C. Belda Marín ◽  
E. Colaco ◽  
C. Lefevre ◽  
C. Méthivier ◽  
...  
Keyword(s):  
Aqueous Media ◽  
Water Soluble ◽  
Organic Reactions ◽  
Palladium Nanoparticle ◽  
High Turnover ◽  
Highly Efficient ◽  
Ppm Level

Water stable Pd-NPs prepared in an eco-friendly manner enable highly efficient catalysis of 6 organic reactions in aqueous media with quantities of Pd down to the ppm level and high turnover frequencies.

scholarly journals Resin-Immobilized Palladium Nanoparticle Catalysts for Organic Reactions in Aqueous Media: Morphological Aspects

Molecules ◽  
2015 ◽  
Vol 20 (10) ◽  
pp. 18661-18684 ◽  
Author(s):  
Piero Mastrorilli ◽  
Maria Dell’Anna ◽  
Antonino Rizzuti ◽  
Matilda Mali ◽  
Mauro Zapparoli ◽  
...  
Keyword(s):  
Aqueous Media ◽  
Organic Reactions ◽  
Palladium Nanoparticle ◽  
Nanoparticle Catalysts ◽  
Morphological Aspects

Highly efficient and selective photocatalytic CO2 to CO conversion in aqueous solution

2020 ◽  
Vol 56 (27) ◽  
pp. 3851-3854 ◽  
Author(s):  
Xiaomin Chai ◽  
Hai-Hua Huang ◽  
Huiping Liu ◽  
Zhuofeng Ke ◽  
Wen-Wen Yong ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Photocatalytic Performance ◽  
Aqueous Media ◽  
Highly Efficient ◽  
Co Conversion

A Co-based complex displayed the highest photocatalytic performance for CO2 to CO conversion in aqueous media.

scholarly journals Non-Enzymatic Desymmetrization Reactions in Aqueous Media

Symmetry ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 720
Author(s):  
Satomi Niwayama
Keyword(s):  
Natural Products ◽  
Total Synthesis ◽  
Functional Groups ◽  
Organic Compounds ◽  
Recent Progress ◽  
Aqueous Media ◽  
Building Blocks ◽  
Organic Reactions ◽  
Environmentally Benign ◽  
Enzymatic Desymmetrization

Symmetric organic compounds are generally obtained inexpensively, and therefore they can be attractive building blocks for the total synthesis of various pharmaceuticals and natural products. The drawback is that discriminating the identical functional groups in the symmetric compounds is difficult. Water is the most environmentally benign and inexpensive solvent. However, successful organic reactions in water are rather limited due to the hydrophobicity of organic compounds in general. Therefore, desymmetrization reactions in aqueous media are expected to offer versatile strategies for the synthesis of a variety of significant organic compounds. This review focuses on the recent progress of desymmetrization reactions of symmetric organic compounds in aqueous media without utilizing enzymes.

scholarly journals Self-Healing Polymer-Clay Hybrids by Facile Complexation of a Waterborne Polymer with a Clay

2021 ◽  
Author(s):  
Aranee Pleng Teepakakorn ◽  
Makoto Ogawa
Keyword(s):  
Vinyl Alcohol ◽  
Aqueous Media ◽  
Water Soluble ◽  
Poly Vinyl Alcohol ◽  
Self Healing ◽  
Soluble Polymer ◽  
Water Soluble Polymer ◽  
Smectite Clay

Water-induced self-healing materials were prepared by the hybridization of a water-soluble polymer, poly(vinyl alcohol), with a smectite clay by mixing in an aqueous media and subsequent casting. Without using chemical...

Dissociation of imino proton(s) of a highly water-soluble metal-free phthalocyanine and determination of its pKa value in water

2013 ◽  
Vol 17 (06n07) ◽  
pp. 447-453 ◽  
Author(s):  
Hiroaki Isago ◽  
Harumi Fujita
Keyword(s):  
Aqueous Media ◽  
Thermal Reaction ◽  
Water Soluble ◽  
Acid Dissociation ◽  
Acid Dissociation Constant ◽  
Metal Free ◽  
Imino Proton ◽  
Pka Value ◽  
Triton X

Dissociation of imino proton(s) in the cavity of the macrocycle of a highly water-soluble, metal-free phthalocyanine ( H 2( H 4 tsppc ); where H 4 tsppc denotes tetrakis{(2′,6′-dimethyl-4′-sulfonic acid)phenoxy}phthalocyaninate) in ethanolic and aqueous solutions has spectrophotometrically been investigated. The spectral changes associated with reaction with NaOH have been found to involve one-proton transfer process in aqueous media while two-protons process in ethanolic media. The acid-dissociation constant of the first imino proton in water (in the presence of Triton X-100) has been determined to be 12.5 ± 0.2 (as pKa) at 25 °C. The doubly deprotonated species in EtOH has been easily converted to its corresponding cobalt(II) derivative by thermal reaction with anhydrous CoCl 2.

Highly efficient water-soluble visible light photoinitiators

2015 ◽  
Vol 54 (4) ◽  
pp. 473-479 ◽  
Author(s):  
Stephan Benedikt ◽  
Jieping Wang ◽  
Marica Markovic ◽  
Norbert Moszner ◽  
Kurt Dietliker ◽  
...  
Keyword(s):  
Visible Light ◽  
Water Soluble ◽  
Highly Efficient

Highly Efficient, Water-Soluble Polarizing Agents for Dynamic Nuclear Polarization at High Frequency

2013 ◽  
Vol 125 (41) ◽  
pp. 11058-11061 ◽  
Author(s):  
Claire Sauvée ◽  
Melanie Rosay ◽  
Gilles Casano ◽  
Fabien Aussenac ◽  
Ralph T. Weber ◽  
...  
Keyword(s):  
Dynamic Nuclear Polarization ◽  
High Frequency ◽  
Nuclear Polarization ◽  
Water Soluble ◽  
Highly Efficient
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