Halide perovskites offer great promise for optoelectronic applications, but stability issues continue to hinder its
implementation and long-term stability. The stability of all-inorganic halide perovskites and the inherent quantum confinement of
low dimensional perovskites can be harnessed to synthesize materials with high PL efficiency. An example of such materials is the
recently reported new family of layered double perovskites, Cs4Mn1−xCdxBi2Cl12. Herein, we report a new synthetic procedure that
enhances the maximum PLQY of this family materials to up 79.5%, a 20% enhancement from previous reports and the highest
reported for a Mn-doped halide perovskite. Importantly, stability tests demonstrate that these materials are very stable towards
humidity, UV irradiation, and temperature. Finally, we investigated the photophysics, the effects of magnetic coupling and
temperature in the PL efficiency and proposed a mechanism for the emission process. Our results highlight the potential of this family
of materials and related layered all-inorganic perovskites for solid-state lighting and optoelectronic applications<p></p>
Low dimensional organic metal-halide hybrids : molecular design & optoelectronic properties
