scholarly journals RAFT-photomediated PISA in dispersion: mechanism, optical properties and application in templated synthesis

2019 ◽  
Vol 10 (18) ◽  
pp. 2316-2326 ◽  
Author(s):  
Vitalii Tkachenko ◽  
Camélia Matei Ghimbeu ◽  
Cyril Vaulot ◽  
Loïc Vidal ◽  
Julien Poly ◽  
...  

Diblock copolymer nanoparticles were prepared by photomediated polymerization-induced self-assembly (“photo-PISA”) in dispersion.

2003 ◽  
Vol 771 ◽  
Author(s):  
Pavel I. Lazarev ◽  
Michael V. Paukshto ◽  
Elena N. Sidorenko

AbstractWe report a new method of Thin Crystal Film deposition. In the present paper we describe the method of crystallization, structure, and optical properties of Bisbenzimidazo[2,1-a:1',2',b']anthra[2,1,9-def:6,5,10-d'e'f']-diisoquinoline-6,9-dion (mixture with cis-isomer) (abbreviated DBI PTCA) sulfonation product. The Thin Crystal Film has a thickness of 200-1000 nm, with anisotropic optical properties such as refraction and absorption indices. X-ray diffraction data evidences a lyotropic liquid crystalline state in liquid phase and crystalline state in solid film. Anisotropic optical properties of the film make it useful in optical devices, e.g. liquid crystal displays.


e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Dong Chen ◽  
Ruixue Liu ◽  
Zhifeng Fu ◽  
Yan Shi

AbstractAmphiphilic diblock copolymer poly(methyl methacrylate)-b-poly(acrylic acid) (PMMA-b-PAA) was prepared by 1,1-diphenylethene (DPE) method. Firstly, free radical polymerization of methyl methacrylate was carried out with AIBN as initiator in the presence of DPE, giving a DPE-containing PMMA precursor with controlled molecular weight. tert-Butyl acrylate (tBA) was then polymerized in the presence of the PMMA precursor, and PMMA-b-PtBA diblock copolymer with controlled molecular weight was prepared. Finally, amphiphilic diblock copolymer PMMA-b-PAA was obtained by hydrolysis of PMMA-b-PtBA. The formation of PMMA-b-PAA was confirmed by 1H NMR spectrum and gel permeation chromatography. Transmission electron microscopy and dynamic light scattering were used to detect the self-assembly behavior of the amphiphilic diblock polymers in methanol.


2006 ◽  
Vol 16 (18) ◽  
pp. NA-NA
Author(s):  
S. Kronholz ◽  
S. Rathgeber ◽  
S. Karthäuser ◽  
H. Kohlstedt ◽  
S. Clemens ◽  
...  

2017 ◽  
Vol 50 (4) ◽  
pp. 1482-1493 ◽  
Author(s):  
Sarah J. Byard ◽  
Mark Williams ◽  
Beulah E. McKenzie ◽  
Adam Blanazs ◽  
Steven P. Armes

2020 ◽  
Vol 28 (17) ◽  
pp. 24981
Author(s):  
Jacopo Pedrini ◽  
Paolo Biagioni ◽  
Andrea Ballabio ◽  
Andrea Barzaghi ◽  
Maura Bonzi ◽  
...  

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