Fluorinated D1(0.5)–A–D2(0.5)–A model terpolymer: ultrafast charge separation kinetics and electron transfer at the fluorinated D/A interface for power conversion

A fluorinated terpolymer has lower Coulomb binding energy and faster electron transfer at the fluorinated D/A interface than a non-fluorinated terpolymer.

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A Fully Coplanar D‐A Polymeric Semiconductor with Promoted Charge Separation Kinetics for Photochemistry

Angewandte Chemie ◽

10.1002/ange.202103992 ◽

2021 ◽

Author(s):

Zhi-An Lan ◽

Meng Wu ◽

Zhongpu Fang ◽

Xu Chi ◽

Xiong Chen ◽

...

Keyword(s):

Charge Separation ◽

Polymeric Semiconductor ◽

Separation Kinetics

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Coupling of photoinduced charge separation in reaction centers of photosynthetic bacteria with electron transfer to a chemically modified electrode

Biochimica et Biophysica Acta (BBA) - Bioenergetics ◽

10.1016/s0005-2728(89)80220-8 ◽

1989 ◽

Vol 976 (2-3) ◽

pp. 121-128 ◽

Cited By ~ 36

Author(s):

Eugenii Yu. Katz ◽

Anatolii Ya. Shkuropatov ◽

Olga I. Vagabova ◽

Vladimir A. Shuvalov

Keyword(s):

Electron Transfer ◽

Modified Electrode ◽

Charge Separation ◽

Photosynthetic Bacteria ◽

Chemically Modified Electrode ◽

Reaction Centers ◽

Chemically Modified ◽

Photoinduced Charge Separation ◽

Photoinduced Charge

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A Stepwise Electron-Transfer Relay Mimicking the Primary Charge Separation in Bacterial Photosynthetic Reaction Center

Journal of the American Chemical Society ◽

10.1021/ja9520676 ◽

1996 ◽

Vol 118 (1) ◽

pp. 155-168 ◽

Cited By ~ 65

Author(s):

Atsuhiro Osuka ◽

Shinji Marumo ◽

Noboru Mataga ◽

Seiji Taniguchi ◽

Tadashi Okada ◽

...

Keyword(s):

Electron Transfer ◽

Reaction Center ◽

Charge Separation ◽

Photosynthetic Reaction Center ◽

Primary Charge Separation ◽

Bacterial Photosynthetic Reaction Center

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Ultrafast Electron Transfer with Long-Lived Charge Separation and Spin Polarization in WSe2/C60 Heterojunction

The Journal of Physical Chemistry Letters ◽

10.1021/acs.jpclett.1c00848 ◽

2021 ◽

pp. 3691-3697

Author(s):

Chang Zhao ◽

Weijian Tao ◽

Zeng Chen ◽

Hongzhi Zhou ◽

Chi Zhang ◽

...

Keyword(s):

Electron Transfer ◽

Spin Polarization ◽

Charge Separation ◽

Ultrafast Electron Transfer

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Morpholine-Phthalocyanine (Donor–Acceptor) Construct: Photoinduced Intramolecular Electron Transfer and Triplet Formation from its Charge Separation State

The Journal of Physical Chemistry A ◽

10.1021/jp202997e ◽

2011 ◽

Vol 115 (31) ◽

pp. 8597-8603 ◽

Cited By ~ 21

Author(s):

Xian-Fu Zhang ◽

Jing Wang

Keyword(s):

Electron Transfer ◽

Charge Separation ◽

Intramolecular Electron Transfer ◽

Donor Acceptor ◽

Triplet Formation

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Charge separation in photoinitiated electron transfer reactions induced by a polyelectrolyte

The Journal of Physical Chemistry ◽

10.1021/j100506a005 ◽

1978 ◽

Vol 82 (17) ◽

pp. 1879-1885 ◽

Cited By ~ 39

Author(s):

D. Meyerstein ◽

J. Rabani ◽

M. S. Matheson ◽

D. Meisel

Keyword(s):

Electron Transfer ◽

Charge Separation ◽

Transfer Reactions ◽

Electron Transfer Reactions

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Photo- and thermally induced coloration of a crystalline MOF accompanying electron transfer and long-lived charge separation in a stable host–guest system

Chemical Communications ◽

10.1039/c2cc33823h ◽

2012 ◽

Vol 48 (65) ◽

pp. 8114 ◽

Cited By ~ 90

Author(s):

Yu Zeng ◽

Zhiyong Fu ◽

Hengjun Chen ◽

Changchun Liu ◽

Shijun Liao ◽

...

Keyword(s):

Electron Transfer ◽

Charge Separation ◽

Thermally Induced ◽

Guest System

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New development of photoinduced electron-transfer catalytic systems

Pure and Applied Chemistry ◽

10.1351/pac200779060981 ◽

2007 ◽

Vol 79 (6) ◽

pp. 981-991 ◽

Cited By ~ 55

Author(s):

Shunichi Fukuzumi

Keyword(s):

Electron Transfer ◽

Organic Solar Cells ◽

Charge Separation ◽

Energy Charge ◽

High Energy ◽

Significant Loss ◽

Catalytic Systems ◽

Molecular Electron ◽

New Development ◽

Donor Acceptor

As an alternative to conventional charge-separation functional molecular models based on multi-step long-range electron transfer (ET) within redox cascades, simple donor-acceptor dyads have been developed to attain a long-lived and high-energy charge-separated (CS) state without significant loss of excitation energy. In particular, a simple molecular electron donor-acceptor dyad, 9-mesityl-10-methylacridinium ion (Acr+-Mes), is capable of fast charge separation but extremely slow charge recombination. Such a simple molecular dyad has significant advantages with regard to synthetic feasibility, providing a variety of applications for photoinduced ET catalytic systems, including efficient photocatalytic systems for the solar energy conversion and construction of organic solar cells.

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How can infra-red excitation both accelerate and slow charge transfer in the same molecule?

Chemical Science ◽

10.1039/c8sc00092a ◽

2018 ◽

Vol 9 (30) ◽

pp. 6395-6405 ◽

Cited By ~ 8

Author(s):

Zheng Ma ◽

Zhiwei Lin ◽

Candace M. Lawrence ◽

Igor V. Rubtsov ◽

Panayiotis Antoniou ◽

...

Keyword(s):

Electron Transfer ◽

Charge Transfer ◽

Charge Separation ◽

Charge Recombination ◽

Recombination Rates ◽

Infra Red ◽

Induced Changes

A UV-IR-Vis 3-pulse study of infra-red induced changes to electron transfer (ET) rates in a donor–bridge–acceptor species finds that charge-separation rates are slowed, while charge-recombination rates are accelerated as a result of IR excitation during the reaction.

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