Interface engineering of NiV-LDH@FeOOH heterostructures as high-performance electrocatalysts for oxygen evolution reaction in alkaline conditions

2020 ◽  
Vol 56 (65) ◽  
pp. 9360-9363 ◽  
Author(s):  
Weiwei Bao ◽  
Lei Xiao ◽  
Junjun Zhang ◽  
Zhifeng Deng ◽  
Chunming Yang ◽  
...  

The NiV-LDH@FeOOH heterostructures exhibit an extremely low overpotential of ∼297 mV at 100 mA cm−2 current output, and excellent long-term durability.

Coatings ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 695 ◽  
Author(s):  
Mengjie Zhang ◽  
Wenchang Zhu ◽  
Xingzhe Yang ◽  
Meng Feng ◽  
Hongbin Feng

Few-layer exfoliated black phosphorus (Ex-BP) has attracted tremendous attention owing to its promising applications, including in electrocatalysis. However, it remains a challenge to directly use few-layer Ex-BP as oxygen-involved electrocatalyst because it is quite difficult to restrain structural degradation caused by spontaneous oxidation and keep it stable. Here, a robust carbon-stabilization strategy has been implemented to prepare carbon-coated Ex-BP/N-doped graphene nanosheet (Ex-BP/NGS@C) nanostructures at room temperature, which exhibit superior oxygen evolution reaction (OER) activity under alkaline conditions. Specifically, the as-synthesized Ex-BP/NGS@C hybrid presents a low overpotential of 257 mV at a current density of 10 mA cm−2 with a small Tafel slope of 52 mV dec−1 and shows high durability after long-term testing.


2019 ◽  
Vol 7 (37) ◽  
pp. 21338-21348 ◽  
Author(s):  
Jia Zhao ◽  
Xu Zhang ◽  
Ming Liu ◽  
Yi-Zhan Jiang ◽  
Min Wang ◽  
...  

Metal–organic-framework-derived porous 3D heterogeneous NiFex/NiFe2O4@NC nanoflowers were prepared as an oxygen-evolution reaction electrocatalyst that exhibit a low overpotential of 262 mV and long-term stability of up to 150 h.


2020 ◽  
Vol 4 (12) ◽  
pp. 6311-6320
Author(s):  
Choel-Hwan Shin ◽  
Yi Wei ◽  
Gisang Park ◽  
Joonhee Kang ◽  
Jong-Sung Yu

A novel binder-free Fe–Ni hydroxide-loaded nickel foam (NF) electrode is prepared by simple corrosion of NF in a home-made piranha solution containing Fe3+ and exhibits remarkable electrochemical OER activity and long-term stability.


Catalysts ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 564 ◽  
Author(s):  
Kyoung Ryeol Park ◽  
Jae Eun Jeon ◽  
Ghulam Ali ◽  
Yong-Ho Ko ◽  
Jaewoong Lee ◽  
...  

High-performance oxygen evolution reaction (OER) electrocatalysts are needed to produce hydrogen for energy generation through a carbon-free route. In this work, the solution combustion synthesis (SCS) method was employed to synthesize mixed phases of Co- and Mn-based oxides, and the relationships between the crystalline structure and the catalytic properties in the mixed phases were established. The mixed phases of Co- and Mn-based oxides shows promising OER properties, such as acceptable overpotential (450 mV for 10 mA∙cm−2) and Tafel slope (35.8 mV∙dec−1), highlighting the use of the mixed phases of Co- and Mn-based oxides as a new efficient catalysts for water splitting. Electronic structure of the mixed phases of Co- and Mn based oxides is studied in detail to give insight for the origin of high catalytic activities. In addition, excellent long-term stability for OER in alkaline media is achieved for the mixed phase of Co- and Mn based oxides.


2021 ◽  
Author(s):  
Ning Liu ◽  
Qiaoqiao Zhang ◽  
Jingqi Guan

Seeking for low-cost and high-performance electrocatalysts for oxygen evolution reaction (OER) has drawn enormous research interest in the last few years. Reported herein is the topotactic construction of a binuclear...


Author(s):  
Shuya Zhao ◽  
Yurui Xue ◽  
Zhongqiang Wang ◽  
Zhiqiang Zheng ◽  
Xiaoyu Luan ◽  
...  

Developing highly active, stable and low-cost electrocatalysts capable of an efficient oxygen evolution reaction (OER) is urgent and challenging.


Author(s):  
Yoo Sei Park ◽  
Jooyoung Lee ◽  
Myeong-Je Jang ◽  
Juchan Yang ◽  
Jae Hoon Jeong ◽  
...  

Seawater electrolysis is a promising technology for the production of hydrogen energy and seawater desalination. To produce hydrogen energy through seawater electrolysis, highly active electrocatalysts for the oxygen evolution reaction...


Author(s):  
Davood Taherinia ◽  
Seyyed Heydar Moravvej ◽  
Mohammad Moazzeni ◽  
Elham Akbarzadeh

The development of efficient and cost-effective catalysts for the oxygen evolution reaction is highly desirable for applications that are based on sustainable and clean technologies. In this study, we report...


2021 ◽  
Vol 5 (6) ◽  
pp. 1801-1808
Author(s):  
Jie Yu ◽  
Tao Zhang ◽  
Changchang Xing ◽  
Xuejiao Li ◽  
Xinyang Li ◽  
...  

NiS2/Fe-P nanospheres were developed as an efficient oxygen evolution reaction electrocatalyst with a low overpotential (218 mV @ 10 mA cm−2 and 306 mV @ 800 mA cm−2) and Tafel slope (47.5 mV dec−1).


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