Visible-light-promoted E-selective synthesis of α-fluoro-β-arylalkenyl sulfides via the deoxygenation/isomerization process
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Highly E-selective synthesis of α-fluoro-β-arylalkenyl sulfides: regioselective synthesis of α-fluoro-β-arylalkenyl sulfides has been established with gem-difluoroalkenes and sodium arysulfinates via visible-light-induced deoxygenation of S–O bonds and isomerization of alkenes. Moreover, the strategy is also applied in the late-stage modification of complex natural products and drugs.
2020 ◽
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2019 ◽
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2020 ◽
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