Phosphorus-based metal-free Z-scheme 2D van der Waals heterostructures for visible-light photocatalytic water splitting: a first-principles study

2020 ◽  
Vol 22 (17) ◽  
pp. 9250-9256 ◽  
Author(s):  
Junyu Lang ◽  
Yun Hang Hu

BlueP/PN with a 2D van der Waals (vdW) heterostructure was proposed and theoretically investigated to construct a Z-scheme photocatalytic system for water splitting under visible light irradiation.

2018 ◽  
Vol 6 (39) ◽  
pp. 19167-19175 ◽  
Author(s):  
Yuxuan Chen ◽  
Tingting Shi ◽  
Pengyi Liu ◽  
Xinguo Ma ◽  
Lingling Shui ◽  
...  

Photocatalytic water splitting was observed on black phosphorus/BiVO4 heterostructure under visible light irradiation.


Nanoscale ◽  
2021 ◽  
Author(s):  
Hu Liu ◽  
Mengqi Shen ◽  
Peng Zhou ◽  
Zhi Guo ◽  
Xinyang Liu ◽  
...  

Developing an efficient single component photocatalyst for overall water splitting under visible-light irradiation is extremely challenging. Herein, we report a metal-free graphitic carbon nitride (g-CxN4)-based nanosheet photocatalyst (x = 3.2,...


2019 ◽  
Vol 43 (22) ◽  
pp. 8741-8745
Author(s):  
Ying Tong ◽  
Hao Pan ◽  
Weichao Huang ◽  
Wenzhao Qiu ◽  
Zhengxin Ding ◽  
...  

Graphene oxide sheets can function as a kind of metal-free photocatalyst for the trifluoromethylation of arenes under visible light irradiation.


2015 ◽  
Vol 44 (41) ◽  
pp. 18260-18269 ◽  
Author(s):  
Yongming Zhong ◽  
Jielin Yuan ◽  
Jiuqing Wen ◽  
Xin Li ◽  
Yuehua Xu ◽  
...  

NiS modified mpg-C3N4/CNT photocatalysts exhibit significantly enhanced photocatalytic H2-evolution activities under visible light irradiation.


2020 ◽  
Vol 16 ◽  
Author(s):  
Yuxue Wei ◽  
Honglin Qin ◽  
Jinxin Deng ◽  
Xiaomeng Cheng ◽  
Mengdie Cai ◽  
...  

Introduction: Solar-driven photocatalytic hydrogen production from water splitting is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. In this review, recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. In particular, the factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Background: Photocatalytic hydrogen evolution from water splitting using photocatalyst semiconductors is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. Methods: This review summarizes the recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation. Results: Recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. The factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Conclusion: The state-of-the-art CdS for producing hydrogen from photocatalytic water splitting under visible light is discussed. The future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are also described.


RSC Advances ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 6383-6394 ◽  
Author(s):  
Haishuai Li ◽  
Linlin Cai ◽  
Xin Wang ◽  
Huixian Shi

A noval ternary nanocomposite AgCl/Ag3PO4/g-C3N4 was successfully synthesized for photocatalytic degradation of methylene blue, methylparaben and inactivation of E. coli under visible light irradiation, showing excellent photocatalytic degradation performance and stability.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Panbing Hu ◽  
Yanmei Xin ◽  
Congfei Yao ◽  
Yuqing Miao

The In2S3/BiOI composites were synthesized at room temperature which significantly improved the photocatalytic degradation performance of tetracycline hydrochloride (TC) under visible light irradiation. Structure and morphology characterization have been performed...


2015 ◽  
Vol 3 (36) ◽  
pp. 18622-18635 ◽  
Author(s):  
Susanginee Nayak ◽  
Lagnamayee Mohapatra ◽  
Kulamani Parida

Dispersion of exfoliated CN over the surface of exfoliated LDH composite materials, and its photocatalytic water splitting under visible-light irradiation.


RSC Advances ◽  
2016 ◽  
Vol 6 (95) ◽  
pp. 93048-93055 ◽  
Author(s):  
R. Giovannetti ◽  
E. Rommozzi ◽  
M. Zannotti ◽  
C. A. D'Amato ◽  
S. Ferraro ◽  
...  

Graphene dispersion (GR) was prepared by liquid-phase sonication of graphite and evaluated by XRD, DLS and UV-Vis analysis. It was used to prepare PP@mgGR–TiO2, showing positive effects on ARS photodegradation under visible light irradiation.


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