N-heterocyclic carbene-functionalized metal–organic frameworks for the chemical fixation of CO2

2020 ◽  
Vol 49 (20) ◽  
pp. 6548-6552
Author(s):  
Yilin Jiang ◽  
Xu Zhang ◽  
Honghan Fei
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Frameworks ◽  
High Catalytic Activity ◽  
Chemical Fixation ◽  
Metal Free ◽  
Metal Organic

We have summarized the recent in situ generation approaches to form metal-free NHC-functionalized MOFs, which are a unique class of CO2-conversion catalysts with high catalytic activity, selectivity and stability.

From Ru nanoparticle-encapsulated metal–organic frameworks to highly catalytically active Cu/Ru nanoparticle-embedded porous carbon

2017 ◽  
Vol 5 (10) ◽  
pp. 4835-4841 ◽  
Author(s):  
Pradip Pachfule ◽  
Xinchun Yang ◽  
Qi-Long Zhu ◽  
Nobuko Tsumori ◽  
Takeyuki Uchida ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Temperature ◽  
Porous Carbon ◽  
Metal Organic Frameworks ◽  
Ammonia Borane ◽  
Carbon Composites ◽  
High Catalytic Activity ◽  
Catalytically Active ◽  
Metal Organic

High-temperature pyrolysis of Ru nanoparticle-encapsulated MOF (Ru@HKUST-1) afforded ultrafine Cu/Ru nanoparticle-embedded porous carbon composites (Cu/Ru@C), which show high catalytic activity for ammonia borane hydrolysis.

Controllable synthesis of urchin-like hierarchical superstructure MOFs with high catalytic activity and stability

2021 ◽  
Author(s):  
Zhanke Wang ◽  
Lei Ge ◽  
Guangxu Zhang ◽  
Rongrong Gao ◽  
Hao Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
High Activity ◽  
Metal Organic Frameworks ◽  
High Catalytic Activity ◽  
Controllable Synthesis ◽  
Metal Organic ◽  
Self Assembled

A novel dissolution-crystallization strategy was developed to synthesize urchin-like superstructure metal-organic frameworks (MOFs) with self-assembled 1D nanorods. The superstructure MOFs not only inherit the high activity of nano-sized MOFs but...

A metal–organic framework with in situ generated low-coordinate binuclear Cu(i) units as a highly effective catalyst for photodriven hydrogen production

2020 ◽  
Vol 56 (49) ◽  
pp. 6700-6703
Author(s):  
Ning-Yu Huang ◽  
Hai He ◽  
Hao Li ◽  
Pei-Qin Liao ◽  
Xiao-Ming Chen
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Production ◽  
Synergistic Effect ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Binuclear Copper ◽  
Metal Organic ◽  
Cu Ions ◽  
Organic Framework

Here, we report a metal–organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g−1 h−1) for photodriven H2 generation, which is attributed to the synergistic effect between the two Cu ions.

The photo-, electro- and photoelectro-catalytic properties and application prospects of porous coordinate polymers

2018 ◽  
Vol 6 (15) ◽  
pp. 6130-6154 ◽  
Author(s):  
Haolin Zhu ◽  
Dingxin Liu ◽  
Dianting Zou ◽  
Jianyong Zhang
Keyword(s):  
Catalytic Activity ◽  
Specific Surface ◽  
Surface Area ◽  
Gas Adsorption ◽  
Catalytic Properties ◽  
Metal Organic Frameworks ◽  
High Catalytic Activity ◽  
Large Specific Surface Area ◽  
Metal Organic ◽  
Application Prospects

Since the discovery of metal–organic frameworks (MOFs), covalent–organic frameworks (COFs) and zeolite–imidazole frameworks (ZIFs), many of their outstanding properties have been explored such as their large specific surface area, significant gas adsorption, and high catalytic activity.

SO3H-functionalized metal organic frameworks: an efficient heterogeneous catalyst for the synthesis of quinoxaline and derivatives

RSC Advances ◽  
2016 ◽  
Vol 6 (41) ◽  
pp. 35135-35143 ◽  
Author(s):  
Radoelizo S. Andriamitantsoa ◽  
Jingjing Wang ◽  
Wenjun Dong ◽  
Hongyi Gao ◽  
Ge Wang
Keyword(s):  
Catalytic Activity ◽  
Heterogeneous Catalyst ◽  
Metal Organic Frameworks ◽  
Good Stability ◽  
High Catalytic Activity ◽  
General Applicability ◽  
Metal Organic ◽  
Efficient Heterogeneous Catalyst

The high dispersed –SO3H groups in the framework of MIL-101-Cr–NH–RSO3H ensure high catalytic activity for the condensation of 1,2-diamines with benzil. The catalyst exhibits good stability, general applicability and excellent recycling performance.

scholarly journals Ferrocene particles incorporated into Zr-based metal–organic frameworks for selective phenol hydroxylation to dihydroxybenzenes

RSC Advances ◽  
2017 ◽  
Vol 7 (61) ◽  
pp. 38691-38698 ◽  
Author(s):  
Bin Li ◽  
Wubin Wu ◽  
Tianyong Zhang ◽  
Shuang Jiang ◽  
Xingwei Chen ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Room Temperature ◽  
Metal Organic Frameworks ◽  
Phenol Hydroxylation ◽  
High Catalytic Activity ◽  
Metal Organic

Ferrocene@UiO-66 exhibited high catalytic activity for phenol hydroxylation with H2O2 at room temperature in water.

In-situ cleavage and rearrangement synthesis of an easy-obtained and high stable Cu(II)-based MOF for efficient heterogeneous catalysis of carbon dioxide conversion

CrystEngComm ◽  
2021 ◽  
Author(s):  
Lan Qin ◽  
Yu Pan ◽  
Lei Yu ◽  
Ranran Huai ◽  
Lu Yang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Heterogeneous Catalysis ◽  
Metal Organic Frameworks ◽  
Chemical Fixation ◽  
Cyclic Carbonates ◽  
Carbon Dioxide Conversion ◽  
Metal Organic ◽  
Carbon Dioxide Co2

Cycloaddition into cyclic carbonates has been attracted substantial attentions for metal-organic frameworks based catalysis of carbon dioxide (CO2) chemical fixation, not only due to the contributions that solving the environmental...

Formation of β-Ga2O3 nanorings from metal–organic frameworks and their high catalytic activity for epoxidation of alkenes

2021 ◽  
Vol 9 (1) ◽  
pp. 349-357
Author(s):  
Wei Ping Wang ◽  
Le Xin Song ◽  
Yao Li ◽  
Yue Teng ◽  
Juan Xia ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Structural Transformation ◽  
Metal Organic Frameworks ◽  
High Catalytic Activity ◽  
Metal Organic ◽  
Epoxidation Of Alkenes

β-Ga2O3 nanorings fabricated by structural transformation of concave Ga-MOF nanodisks exhibit high catalytic activity for epoxidation of alkenes.

Phosphotungstic acid encapsulated in the mesocages of amine-functionalized metal–organic frameworks for catalytic oxidative desulfurization

2014 ◽  
Vol 43 (31) ◽  
pp. 11950-11958 ◽  
Author(s):  
Xu-Sheng Wang ◽  
Yuan-Biao Huang ◽  
Zu-Jin Lin ◽  
Rong Cao
Keyword(s):  
Catalytic Activity ◽  
Phosphotungstic Acid ◽  
Metal Organic Frameworks ◽  
Oxidative Desulfurization ◽  
High Catalytic Activity ◽  
Exchange Method ◽  
Mild Conditions ◽  
Amine Functionalized ◽  
Catalytic Oxidative Desulfurization ◽  
Metal Organic

PTA@MIL-101(Cr)-NH2 has been prepared via an anion exchange method, and showed high catalytic activity for oxidative desulfurization under mild conditions.

Oxidation of benzyl alcohol over metal organic frameworks M-BTC (M = Co, Cu, Fe)

2017 ◽  
Vol 41 (8) ◽  
pp. 2891-2894 ◽  
Author(s):  
Ling Peng ◽  
Shujie Wu ◽  
Xiaoyuan Yang ◽  
Jing Hu ◽  
Xiaoran Fu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Benzyl Alcohol ◽  
Metal Organic Frameworks ◽  
High Catalytic Activity ◽  
Oxidation Of Benzyl Alcohol ◽  
Metal Organic

Co-BTC showed high catalytic activity and selectivity in the oxidation of benzyl alcohol with air as the oxidant.

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