Rapid mechanochemical synthesis of metal–organic frameworks using exogenous organic base

2020 ◽  
Vol 49 (45) ◽  
pp. 16238-16244 ◽  
Author(s):  
Zihao Wang ◽  
Zongzhe Li ◽  
Marcus Ng ◽  
Phillip J. Milner
Keyword(s):  
Mechanochemical Synthesis ◽  
Metal Organic Frameworks ◽  
Solvent Free ◽  
Organic Base ◽  
Metal Organic ◽  
First Time ◽  
Solvent Free Synthesis

We describe the mechanochemical, solvent-free synthesis of metal–organic frameworks using liquid organic base for the first time.

scholarly journals Gas–solid two-phase flow (GSF) mechanochemical synthesis of dual-metal–organic frameworks and research on electrochemical properties

2020 ◽  
Vol 2 (12) ◽  
pp. 5682-5687
Author(s):  
Jun Zhao ◽  
Bo Jin ◽  
Rufang Peng
Keyword(s):  
Electrochemical Properties ◽  
Mechanochemical Synthesis ◽  
Two Phase Flow ◽  
Metal Organic Frameworks ◽  
Phase Flow ◽  
Two Phase ◽  
Alternative Approach ◽  
Metal Organic ◽  
Dual Metal ◽  
First Time

As an alternative approach for conventional mechanochemical synthesis, a novel gas–solid two-phase flow (GSF) synthetic technique for the mechanochemical synthesis of dual metal–organic frameworks (DMOFs) was reported for the first time.

Mechanochemical synthesis of two-dimensional metal-organic frameworks

2019 ◽  
Vol 34 (2) ◽  
pp. 119-123 ◽  
Author(s):  
Omar Barreda ◽  
Gregory R. Lorzing ◽  
Eric D. Bloch
Keyword(s):  
Mechanochemical Synthesis ◽  
Metal Organic Frameworks ◽  
Isophthalic Acid ◽  
Organic Ligands ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Synthesis Routes ◽  
Solvent Free Synthesis

Powder X-ray diffraction was used to monitor the solvent-free synthesis of two-dimensional (2D) metal–organic frameworks (MOFs) via mechanochemical methods. For four isophthalic acid-based, alkoxide-functionalized organic ligands, optimal milling times were found to vary from 12 to 48 min. This work confirms that mechanochemical synthesis routes can be utilized to afford highly-crystalline, 2D MOFs.

Mineral neogenesis as an inspiration for mild, solvent-free synthesis of bulk microporous metal–organic frameworks from metal (Zn, Co) oxides

2013 ◽  
Vol 15 (8) ◽  
pp. 2121 ◽  
Author(s):  
Cristina Mottillo ◽  
Yuneng Lu ◽  
Minh-Hao Pham ◽  
Matthew J. Cliffe ◽  
Trong-On Do ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Solvent Free ◽  
Metal Organic ◽  
Solvent Free Synthesis

scholarly journals Solvent-free synthesis of heterometallic metal–organic frameworks for the electrocatalytic reduction of carbon dioxide

2018 ◽  
Vol 74 (a2) ◽  
pp. e282-e282
Author(s):  
Maite Perfecto Irigaray ◽  
Jonathan Albo ◽  
Garikoitz Beobide ◽  
Oscar Castillo ◽  
Angel Irabien ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Solvent Free ◽  
Electrocatalytic Reduction ◽  
Metal Organic ◽  
Solvent Free Synthesis

A direct solvent-free conversion approach to prepare mixed-metal metal–organic frameworks from doped metal oxides

2021 ◽  
Vol 57 (29) ◽  
pp. 3587-3590
Author(s):  
Beili Yi ◽  
Haojie Zhao ◽  
Yue Zhang ◽  
Xiaomeng Si ◽  
Guanqun Zhang ◽  
...  
Keyword(s):  
Metal Oxides ◽  
Metal Organic Frameworks ◽  
Solvent Free ◽  
Mixed Metal ◽  
Synthesis Strategy ◽  
Metal Metal ◽  
Metal Organic

We propose a novel solvent-free conversion strategy of Pt–ZnO to Pt-ZIF-8. This synthesis strategy may facilitate the discovery of MMOFs that have not been reported previously.

Sign in / Sign up

Export Citation Format

Share Document