Selective N-formylation/N-methylation of amines and N-formylation of amides and carbamates with carbon dioxide and hydrosilanes: promotion of the basic counter anions of the zinc catalyst
A Zn(OAc)2 catalyst bearing the 1,10-phenanthroline (phen) ligand was efficient in the N-formylation of organic amine derivatives (e.g., amines, amides, and carbamates) using carbon dioxide (CO2) and hydrosilanes.
1974 ◽
Vol 32
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1970 ◽
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