Recent advances and prospects in the palladium-catalyzed cyanation of aryl halides

Aryl nitriles are an inevitable part of synthetic organic chemistry. This review summarizes the recent developments in palladium-catalyzed cyanation of aryl halides from 2012–2020.

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Recent Developments in the Asymmetric Detrifluoroacetylative Reactions of in situ Generated Mono-Fluorinated Enolates

Current Organic Chemistry ◽

10.2174/1385272824999200801022712 ◽

2020 ◽

Vol 24 (18) ◽

pp. 2181-2191

Author(s):

Li Wang ◽

Ziyi Li ◽

Jiang Liu ◽

Jianlin Han ◽

Hiroki Moriwaki ◽

...

Keyword(s):

Organic Chemistry ◽

Bond Cleavage ◽

Synthetic Methodology ◽

Research Topics ◽

Synthetic Organic Chemistry ◽

Nucleophilic Reactions ◽

F Center ◽

Recent Developments

The development of an efficient and mild synthetic methodology for the construction of bioactive fluorine-containing molecules represents one of the hot research topics in general synthetic organic chemistry. In this review, some recent progresses achieved in the development of detrifluoroacetylatively generated mono-fluorinated enolates via CC bond cleavage and their asymmetric nucleophilic reactions for assembly of chiral quaternary C-F center containing compounds.

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Recent advances and perspectives in manganese-catalyzed C–H activation

Catalysis Science & Technology ◽

10.1039/d0cy02087g ◽

2021 ◽

Author(s):

Thaipparambil Aneeja ◽

Mohan Neetha ◽

C. M. A. Afsina ◽

Gopinathan Anilkumar

Keyword(s):

Organic Chemistry ◽

Synthetic Organic Chemistry ◽

Recent Advances

Manganese-catalyzed C–H activation has become an emerging area in organic chemistry. These efficient and eco-friendly manganese catalysed reactions provides new opportunities in the field of synthetic organic chemistry.

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Recent Advances in the Incorporation of CO2 for C-H and C-C bond Functionalization

Green Chemistry ◽

10.1039/d1gc02737a ◽

2021 ◽

Author(s):

Sandeep Pimparkar ◽

Aishwarya K. Dalvi ◽

Adithyaraj Koodan ◽

Siddhartha Maiti ◽

Shaeel Al-Thabaiti ◽

...

Keyword(s):

Organic Chemistry ◽

Carbon Dioxide ◽

Thermodynamic Stability ◽

Cost Effective ◽

Bond Functionalization ◽

Synthetic Organic Chemistry ◽

Recent Advances ◽

Carbon Dioxide Co2

Carbon dioxide (CO2) has emerged as one of the exciting cost-effective, abundant, and ready-to-use C1 sources in synthetic organic chemistry. However, the thermodynamic stability, as well as the kinetic inertness,...

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Recent Advances in Palladium-Catalyzed Isocyanide Insertions

Molecules ◽

10.3390/molecules25214906 ◽

2020 ◽

Vol 25 (21) ◽

pp. 4906

Author(s):

Jurriën W. Collet ◽

Thomas R. Roose ◽

Bram Weijers ◽

Bert U. W. Maes ◽

Eelco Ruijter ◽

...

Keyword(s):

Organic Synthesis ◽

Building Blocks ◽

Insertion Reactions ◽

Chemical Reagents ◽

The Past ◽

Recent Advances ◽

Recent Developments ◽

Palladium Catalyzed ◽

Made In ◽

Rapid Incorporation

Isocyanides have long been known as versatile chemical reagents in organic synthesis. Their ambivalent nature also allows them to function as a CO-substitute in palladium-catalyzed cross couplings. Over the past decades, isocyanides have emerged as practical and versatile C1 building blocks, whose inherent N-substitution allows for the rapid incorporation of nitrogeneous fragments in a wide variety of products. Recent developments in palladium catalyzed isocyanide insertion reactions have significantly expanded the scope and applicability of these imidoylative cross-couplings. This review highlights the advances made in this field over the past eight years.

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ChemInform Abstract: Functionalized Polymers: Recent Developments and New Applications in Synthetic Organic Chemistry

ChemInform ◽

10.1002/chin.199810286 ◽

2010 ◽

Vol 29 (10) ◽

pp. no-no

Author(s):

S. J. SHUTTLEWORTH ◽

S. M. ALLIN ◽

P. K. SHARMA

Keyword(s):

Organic Chemistry ◽

Functionalized Polymers ◽

Synthetic Organic Chemistry ◽

Recent Developments ◽

New Applications

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Recent Advances in the Applications of the Intramolecular Suzuki Cross-coupling Reaction in Cyclization and Heterocyclization: An Update

Current Organic Chemistry ◽

10.2174/1385272823666191023115842 ◽

2020 ◽

Vol 23 (22) ◽

pp. 2469-2488 ◽

Cited By ~ 2

Author(s):

Majid M. Heravi ◽

Masoumeh Malmir ◽

Razieh Moradi

Keyword(s):

Organic Chemistry ◽

Boronic Acid ◽

Heterocyclic Compounds ◽

Aryl Halide ◽

Coupling Reaction ◽

Cross Coupling ◽

Synthetic Organic Chemistry ◽

Previous Review ◽

Cross Coupling Reaction ◽

Palladium Catalyzed

: The palladium-catalyzed reaction of aryl halide and boronic acid for the formation of C–C bonds so-called Suzuki–Miyaura cross-coupling reaction has many applications in Modern Synthetic Organic Chemistry. In 2013, we emphasized the applications of the intramolecular Suzuki cross-coupling reaction in cyclization and heterocyclization. Due to a plethora relevant papers appeared in the chemical literature, herein, we wish to cover by updating our previous review, the applications of the intramolecular Suzuki cross-coupling reaction in cyclization and heterocyclization leading to various homocyclic and heterocyclic compounds reported during a period of 2013 to 2018.

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