Recent Advances in the Incorporation of CO2 for C-H and C-C bond Functionalization

2021 ◽  
Author(s):  
Sandeep Pimparkar ◽  
Aishwarya K. Dalvi ◽  
Adithyaraj Koodan ◽  
Siddhartha Maiti ◽  
Shaeel Al-Thabaiti ◽  
...  

Carbon dioxide (CO2) has emerged as one of the exciting cost-effective, abundant, and ready-to-use C1 sources in synthetic organic chemistry. However, the thermodynamic stability, as well as the kinetic inertness,...

Author(s):  
Thaipparambil Aneeja ◽  
Mohan Neetha ◽  
C. M. A. Afsina ◽  
Gopinathan Anilkumar

Manganese-catalyzed C–H activation has become an emerging area in organic chemistry. These efficient and eco-friendly manganese catalysed reactions provides new opportunities in the field of synthetic organic chemistry.


Molecules ◽  
2020 ◽  
Vol 25 (7) ◽  
pp. 1675 ◽  
Author(s):  
Xiang Gao ◽  
Jiao Liu ◽  
Xin Zuo ◽  
Xinyue Feng ◽  
Ying Gao

Benzothiazoles have played an important role in the field of biochemistry and medicinal chemistry due to their highly pharmaceutical and biological activity. The development of synthetic processes is undoubtedly one of the most significant problems facing researchers. In this review paper, we provided recent advances in the synthesis of benzothiazole compounds related to green chemistry from condensation of 2-aminobenzenethiol with aldehydes/ketones/acids/acyl chlorides and the cyclization of thioamide or carbon dioxide (CO2) as raw materials, and the future development trend and prospect of the synthesis of benzothiazoles were anticipated.


ChemInform ◽  
2014 ◽  
Vol 46 (2) ◽  
pp. no-no
Author(s):  
Alba E. Diaz-Alvarez ◽  
Javier Francos ◽  
Pascale Croche ◽  
Victorio Cadierno

2018 ◽  
Vol 11 (3) ◽  
pp. 1833-1849 ◽  
Author(s):  
Martin Kunz ◽  
Jost V. Lavric ◽  
Christoph Gerbig ◽  
Pieter Tans ◽  
Don Neff ◽  
...  

Abstract. Unmanned aircraft systems (UASs) could provide a cost-effective way to close gaps in the observation of the carbon cycle, provided that small yet accurate analysers are available. We have developed a COmpact Carbon dioxide analyser for Airborne Platforms (COCAP). The accuracy of COCAP's carbon dioxide (CO2) measurements is ensured by calibration in an environmental chamber, regular calibration in the field and by chemical drying of sampled air. In addition, the package contains a lightweight thermal stabilisation system that reduces the influence of ambient temperature changes on the CO2 sensor by 2 orders of magnitude. During validation of COCAP's CO2 measurements in simulated and real flights we found a measurement error of 1.2 µmol mol−1 or better with no indication of bias. COCAP is a self-contained package that has proven well suited for the operation on board small UASs. Besides carbon dioxide dry air mole fraction it also measures air temperature, humidity and pressure. We describe the measurement system and our calibration strategy in detail to support others in tapping the potential of UASs for atmospheric trace gas measurements.


RSC Advances ◽  
2020 ◽  
Vol 10 (35) ◽  
pp. 20784-20793 ◽  
Author(s):  
Abdanne Weyesa ◽  
Endale Mulugeta

Recently, quinoline has become an essential heterocyclic compound due to its versatile applications in the fields of industrial and synthetic organic chemistry.


2015 ◽  
Vol 03 (01n02) ◽  
pp. 1540007 ◽  
Author(s):  
Rebecca Shu Hui Khoo ◽  
He-Kuan Luo ◽  
Pierre Braunstein ◽  
T. S. Andy Hor

Carbon dioxide ( CO 2) is an attractive C1 resource because it is cheap and abundant and its more extensive use would be beneficial for the environment. However, its high thermodynamic stability and poor reactivity have seriously limited its utilization as a ready carbon source. The scientific challenges facing CO 2 transformation are accordingly very attractive. This paper summarizes recent advances made in transformation of CO 2 to value-added high-molecular-weight materials such as polymers, star-shaped molecules and nanocarbons.


Compounds ◽  
2022 ◽  
Vol 2 (1) ◽  
pp. 3-24
Author(s):  
Njomza Ajvazi ◽  
Stojan Stavber

The iodination of organic compounds is of great importance in synthetic organic chemistry. It opens comprehensive approaches for the synthesis of various biologically active compounds. The recent advances in iodination of organic compounds using elemental iodine or iodides, covering the last thirteen years, are the objective of the present review.


2013 ◽  
Vol 1 (1) ◽  
pp. 51-65 ◽  
Author(s):  
Alba E. Díaz-Álvarez ◽  
Javier Francos ◽  
Pascale Croche ◽  
Victorio Cadierno

Synlett ◽  
2021 ◽  
Author(s):  
Xiao-Guang Yang ◽  
Ze-Nan Hu ◽  
Meng-Cheng Jia ◽  
Feng-Huan Du ◽  
Chi Zhang

Nowadays, hypervalent iodine chemistry has remarkably advanced in parallel with the emergence of novel hypervalent iodine reagents. Hypervalent iodine reagents, due to their outstanding characteristics including rich reactivities, excellent chemo-selectivity, stability, and environmental friendliness, are becoming more and more popular in the synthetic organic chemistry. In this minireview, a number of recent elegant research works and our perspective on the future of hypervalent iodine chemistry have been presented.


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