scholarly journals Ce regulated surface properties of Mn/SAPO-34 for improved NH3-SCR at low temperature

RSC Advances ◽  
2020 ◽  
Vol 10 (66) ◽  
pp. 40047-40054
Author(s):  
Qizhi Chen ◽  
Yong Yang ◽  
Hang Luo ◽  
Zuohua Liu ◽  
Zhangfa Tong ◽  
...  

Ce modified MnOx/SAPO-34 was prepared and investigated for low-temperature selective catalytic reduction of NOx with ammonia (NH3-SCR).

RSC Advances ◽  
2018 ◽  
Vol 8 (34) ◽  
pp. 19301-19309 ◽  
Author(s):  
Kai Cheng ◽  
Weiyu Song ◽  
Ying Cheng ◽  
Huiling Zheng ◽  
Lu Wang ◽  
...  

A series of FeαCu1−αTiOx catalysts with variable Cu doping amounts was directly synthesized by the sol–gel method and their catalytic performances were tested for the selective catalytic reduction of NO with ammonia.


Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 259
Author(s):  
Siva Sankar Reddy Putluru ◽  
Leonhard Schill ◽  
Anker Degn Jensen ◽  
Bernard Siret ◽  
Frank Tabaries ◽  
...  

Preparation of Mn/TiO2, Mn-Fe/TiO2, and Mn-Fe-Ce/TiO2 by the deposition-precipitation (DP) method can afford very active catalysts for low-temperature NH3-SCR (selective catalytic reduction of NO with NH3). The effect of precursor choice (nitrate vs. acetate) of Mn, Fe, and Ce on the physiochemical properties including thermal stability and the resulting SCR activity were investigated. The resulting materials were characterized by N2-Physisorption, XRD (Powder X-ray diffraction), XPS (X-ray photoelectron spectroscopy), H2-TPR (temperature-programmed reduction with hydrogen), and the oxidation of NO to NO2 measured at 300 °C. Among all the prepared catalysts 5MnAce/Ti, 25Mn0.75AceFe0.25Nit/Ti, and 25Mn0.75AceFe0.20NitCe0.05Ace/Ti showed superior SCR activity at low temperature. The superior activity of the latter two materials is likely attributable to the presence of amorphous active metal oxide phases (manganese-, iron- and cerium-oxide) and the ease of the reduction of metal oxides on TiO2. Enhanced ability to convert NO to NO2, which can promote fast-SCR like pathways, could be another reason. Cerium was found to stabilize amorphous manganese oxide phases when exposed to high temperatures.


RSC Advances ◽  
2015 ◽  
Vol 5 (44) ◽  
pp. 35155-35165 ◽  
Author(s):  
Meiqing Shen ◽  
Chenxu Li ◽  
Jianqiang Wang ◽  
Lili Xu ◽  
Wulin Wang ◽  
...  

The promotion effect of Cu on the V/WTi catalyst for the selective catalytic reduction of NOx by NH3 was investigated in the temperature range of 150–400 °C.


2012 ◽  
Vol 27 (5) ◽  
pp. 495-500 ◽  
Author(s):  
Da-Wang WU ◽  
Qiu-Lin ZHANG ◽  
Tao LIN ◽  
Mao-Chu GONG ◽  
Yao-Qiang CHEN

2019 ◽  
Vol 9 (3) ◽  
pp. 718-730 ◽  
Author(s):  
Jian-Wen Shi ◽  
Yao Wang ◽  
Ruibin Duan ◽  
Chen Gao ◽  
Baorui Wang ◽  
...  

Non-manganese-based metal oxides are promising catalysts for the NH3-SCR (selective catalytic reduction) of NOx at low temperatures.


2022 ◽  
Author(s):  
Zhitao Han ◽  
Huan Du ◽  
Duo Xu ◽  
Yu Gao ◽  
Shaolong Yang ◽  
...  

FeMn/SnxTiO2 catalysts were synthesized by introducing Sn as an additive to modify TiO2 supports, and the Sn doping could improve the SO2 tolerance and low-temperature SCR activity significantly.


Sign in / Sign up

Export Citation Format

Share Document