scholarly journals Anomalous chemically induced electron spin polarization in proton-coupled electron transfer reactions: insight into radical pair dynamics

2020 ◽  
Vol 11 (24) ◽  
pp. 6268-6274
Author(s):  
Alexander M. Brugh ◽  
Malcolm D. E. Forbes
Keyword(s):  
Electron Transfer ◽  
Ruthenium Complex ◽  
Transfer Reactions ◽  
Electron Spin Polarization ◽  
Paramagnetic Resonance ◽  
Time Resolved ◽  
Proton Coupled Electron Transfer ◽  
Chemically Induced ◽  
Electron Paramagnetic ◽  
Insight Into

Time-resolved electron paramagnetic resonance (TREPR) spectroscopy has been used to study the proton coupled electron transfer (PCET) reaction between a Ruthenium complex (Ru(bpz)(bpy)2) and several substituted hydroquinones (HQ).

Chemically induced electron spin polarization in electron-transfer reactions

1974 ◽  
Vol 27 (3) ◽  
pp. 769-777 ◽  
Author(s):  
P.W. Atkins ◽  
A.J. Dobbs ◽  
G.T. Evans ◽  
K.A. McLauchlan ◽  
P.W. Percival
Keyword(s):  
Electron Transfer ◽  
Spin Polarization ◽  
Electron Spin ◽  
Transfer Reactions ◽  
Electron Spin Polarization ◽  
Electron Transfer Reactions ◽  
Chemically Induced

A mononuclear ruthenium complex showing multiple proton-coupled electron transfer toward multi-electron transfer reactions

2012 ◽  
Vol 41 (42) ◽  
pp. 13081 ◽  
Author(s):  
Masaya Okamura ◽  
Masaki Yoshida ◽  
Reiko Kuga ◽  
Ken Sakai ◽  
Mio Kondo ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Ruthenium Complex ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Proton Coupled Electron Transfer

Probing electron transfer between hemin and riboflavin using a combination of analytical approaches and theoretical calculations

2017 ◽  
Vol 19 (48) ◽  
pp. 32580-32588 ◽  
Author(s):  
Wen-Lan Wang ◽  
Yuan Min ◽  
Sheng-Song Yu ◽  
Wei Chen ◽  
Jie-Jie Chen ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Electron Transfer ◽  
Theoretical Calculations ◽  
Resonance Method ◽  
Paramagnetic Resonance ◽  
Electron Paramagnetic Resonance Method ◽  
Proton Coupled Electron Transfer ◽  
Analytical Approaches ◽  
Electron Paramagnetic ◽  
Transfer Mechanisms

Proton-coupled electron transfer mechanisms of riboflavin bound hemin in aqueous solution are elucidated by spectroelectrochemical analysis, the electron paramagnetic resonance method and theoretical calculations.

Sign in / Sign up

Export Citation Format

Share Document