Realizing the ultimate goal of fully solution-processed organic solar cells: a compatible self-sintering method to achieve silver back electrode

2020 ◽  
Vol 8 (12) ◽  
pp. 6083-6091 ◽  
Author(s):  
Xinjun He ◽  
Yong Wang ◽  
Haifei Lu ◽  
Dan Ouyang ◽  
Zhanfeng Huang ◽  
...  

Isolated silver nanoparticles are sintered by a compatible self-sintering strategy to form connected silver back electrode. The highest power conversion efficiency of 9.73% among reported evaporation-free organic solar cells is achieved.

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
S. Wageh ◽  
Mahfoudh Raïssi ◽  
Thomas Berthelot ◽  
Matthieu Laurent ◽  
Didier Rousseau ◽  
...  

AbstractPoly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) mixed with single-wall nanotubes (SWNTs) (10:1) and doped with (0.1 M) perchloric acid (HClO4) in a solution-processed film, working as an excellent thin transparent conducting film (TCF) in organic solar cells, was investigated. This new electrode structure can be an outstanding substitute for conventional indium tin oxide (ITO) for applications in flexible solar cells due to the potential of attaining high transparency with enhanced conductivity, good flexibility, and good durability via a low-cost process over a large area. In addition, solution-processed vanadium oxide (VOx) doped with a small amount of PEDOT-PSS(PH1000) can be applied as a hole transport layer (HTL) for achieving high efficiency and stability. From these viewpoints, we investigate the benefit of using printed SWNTs-PEDOT-PSS doped with HClO4 as a transparent conducting electrode in a flexible organic solar cell. Additionally, we applied a VOx-PEDOT-PSS thin film as a hole transporting layer and a blend of PTB7 (polythieno[3,4-b] thiophene/benzodithiophene): PC71BM (phenyl-C71-butyric acid methyl ester) as an active layer in devices. Zinc oxide (ZnO) nanoparticles were applied as an electron transport layer and Ag was used as the top electrode. The proposed solar cell structure showed an enhancement in short-circuit current, power conversion efficiency, and stability relative to a conventional cell based on ITO. This result suggests a great carrier injection throughout the interfacial layer, high conductivity and transparency, as well as firm adherence for the new electrode.


2015 ◽  
Vol 3 (5) ◽  
pp. 1910-1914 ◽  
Author(s):  
Huitao Bai ◽  
Yifan Wang ◽  
Pei Cheng ◽  
Jiayu Wang ◽  
Yao Wu ◽  
...  

A novel small molecule based on indacenodithiophene and 1,1-dicyanomethylene-3-indanone was synthesized and used as an electron acceptor in solution processed organic solar cells, which exhibited a power conversion efficiency as high as 3.93%.


2014 ◽  
Vol 2 (36) ◽  
pp. 7614-7620 ◽  
Author(s):  
Jie Min ◽  
Yuriy N. Luponosov ◽  
Alexander N. Solodukhin ◽  
Nina Kausch-Busies ◽  
Sergei A. Ponomarenko ◽  
...  

A star-shaped D–π–A small molecule based on a tris(2-methoxyphenyl)amine donor unit for solution-processed organic solar cells achieves a power conversion efficiency up to 4.38%.


2015 ◽  
Vol 51 (77) ◽  
pp. 14439-14442 ◽  
Author(s):  
Song Chen ◽  
Liangang Xiao ◽  
Xunjin Zhu ◽  
Xiaobing Peng ◽  
Wai-Kwok Wong ◽  
...  

A series of new A–D–A structural 5,15-dialkylated porphyrin-cored small molecules have been developed as donors in bulk heterojunction organic solar cells, and the highest power conversion efficiency of 6.49% has been achieved.


2017 ◽  
Vol 1 (11) ◽  
pp. 2349-2355 ◽  
Author(s):  
Wuyue Liu ◽  
Zichun Zhou ◽  
Thomas Vergote ◽  
Shengjie Xu ◽  
Xiaozhang Zhu

A molecular donor STB-4 with a dithieno[2,3-d′:2′,3′-d′]benzo[1,2-b:4′,5′-b′]dithiophene core was synthesized for organic solar cells with a power conversion efficiency of 8.17%.


2016 ◽  
Vol 4 (13) ◽  
pp. 4952-4961 ◽  
Author(s):  
Jianhua Chen ◽  
Linrui Duan ◽  
Manjun Xiao ◽  
Qiong Wang ◽  
Bin Liu ◽  
...  

A series of Ar(A–D)2 type small molecules containing a pyrene core were synthesized. A significantly improved power conversion efficiency of 5.88% was obtained for ThDPP2Py based organic solar cells.


2019 ◽  
Vol 16 (3) ◽  
pp. 236-243 ◽  
Author(s):  
Hui Zhang ◽  
Yibing Ma ◽  
Youyi Sun ◽  
Jialei Liu ◽  
Yaqing Liu ◽  
...  

In this review, small-molecule donors for application in organic solar cells reported in the last three years are highlighted. Especially, the effect of donor molecular structure on power conversion efficiency of organic solar cells is reported in detail. Furthermore, the mechanism is proposed and discussed for explaining the relationship between structure and power conversion efficiency. These results and discussions draw some rules for rational donor molecular design, which is very important for further improving the power conversion efficiency of organic solar cells based on the small-molecule donor.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Zhenrong Jia ◽  
Shucheng Qin ◽  
Lei Meng ◽  
Qing Ma ◽  
Indunil Angunawela ◽  
...  

AbstractTandem organic solar cells are based on the device structure monolithically connecting two solar cells to broaden overall absorption spectrum and utilize the photon energy more efficiently. Herein, we demonstrate a simple strategy of inserting a double bond between the central core and end groups of the small molecule acceptor Y6 to extend its conjugation length and absorption range. As a result, a new narrow bandgap acceptor BTPV-4F was synthesized with an optical bandgap of 1.21 eV. The single-junction devices based on BTPV-4F as acceptor achieved a power conversion efficiency of over 13.4% with a high short-circuit current density of 28.9 mA cm−2. With adopting BTPV-4F as the rear cell acceptor material, the resulting tandem devices reached a high power conversion efficiency of over 16.4% with good photostability. The results indicate that BTPV-4F is an efficient infrared-absorbing narrow bandgap acceptor and has great potential to be applied into tandem organic solar cells.


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