Poly(Vinylidene Fluoride)-Passivated CsPbBr3 Perovskite Quantum Dots with Near-Unity Photoluminescence Quantum Yield and Superior Stability

Author(s):  
Lin Yang ◽  
Bowen Fu ◽  
Xu Li ◽  
Hao Chen ◽  
Lili Li

All inorganic perovskite quantum dots (QDs) have received great attention owing to their excellent performance in optoelectronic applications. However, they often suffer from the defect-related photoluminescence (PL) quenching and phase...

Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 710 ◽  
Author(s):  
Sujeong Jung ◽  
Jae Ho Kim ◽  
Jin Woo Choi ◽  
Jae-Wook Kang ◽  
Sung-Ho Jin ◽  
...  

We determine the influence of substitutional defects on perovskite quantum dots through experimental and theoretical investigations. Substitutional defects were introduced by trivalent dopants (In, Sb, and Bi) in CsPbBr3 by ligand-assisted reprecipitation. We show that the photoluminescence (PL) emission peak shifts toward shorter wavelengths when doping concentrations are increased. Trivalent metal-doped CsPbBr3 enhanced the PL quantum yield (~10%) and air stability (over 10 days). Our findings provide new insights into the influence of substitutional defects on substituted CsPbBr3 that underpin their physical properties.


Nanoscale ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 2484-2491 ◽  
Author(s):  
Yue Zhai ◽  
Xue Bai ◽  
Gencai Pan ◽  
Jinyang Zhu ◽  
He Shao ◽  
...  

Co-doping of cation (La3+) and anion (F−) ions is a feasible method to improve the optical properties of CsPbCl3 QDs, and high photoluminescence quantum yield of 36.5% is achieved in CsPb(Cl0.7F0.3)3:La3+ QDs.


2020 ◽  
Vol 5 (3) ◽  
pp. 580-585 ◽  
Author(s):  
Yalong Shen ◽  
Jun Yin ◽  
Bo Cai ◽  
Ziming Wang ◽  
Yuhang Dong ◽  
...  

Lead-free Bi-based perovskite FA3Bi2X9 (X = Cl, Br, and I) quantum dots (QDs) are synthesized for the first time at room temperature. The ligand-passivated FA3Bi2Br9 QDs exhibit blue emission at 437 nm with photoluminescence quantum yield (PLQY) up to 52%.


Nanoscale ◽  
2021 ◽  
Author(s):  
Sisi Wang ◽  
Liang Du ◽  
Selin Donmez ◽  
Yan Xin ◽  
Hedi Mattoussi

Colloidal lead halide perovskite quantum dots (PQDs) are relatively new semiconductor nanocrystals with great potential for use in optoelectronic applications.


ACS Nano ◽  
2017 ◽  
Vol 11 (10) ◽  
pp. 10373-10383 ◽  
Author(s):  
Feng Liu ◽  
Yaohong Zhang ◽  
Chao Ding ◽  
Syuusuke Kobayashi ◽  
Takuya Izuishi ◽  
...  

2018 ◽  
Vol 122 (9) ◽  
pp. 5151-5160 ◽  
Author(s):  
Chenghao Bi ◽  
Shixun Wang ◽  
Wen Wen ◽  
Jifeng Yuan ◽  
Guozhong Cao ◽  
...  

Nanoscale ◽  
2018 ◽  
Vol 10 (29) ◽  
pp. 14067-14072 ◽  
Author(s):  
Yanan Liu ◽  
Gencai Pan ◽  
Rong Wang ◽  
He Shao ◽  
He Wang ◽  
...  

The photoluminescence quantum yield (PLQY) of blue-violet emission for CsPbCl3 quantum dots (QDs) is still low, which has limited its application in multi-colour displays.


2020 ◽  
Vol 8 (41) ◽  
pp. 14439-14445 ◽  
Author(s):  
Hengxiang Yang ◽  
Wenxu Yin ◽  
Wei Dong ◽  
Long Gao ◽  
Ching-Hong Tan ◽  
...  

Inorganic perovskite CsPbBr3 quantum dots (QDs) have emerged as a promising candidate for optoelectronic applications due to their narrow emission and color purity, among other things.


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