An Inorganic-rich SEI Induced by LiNO3 Additive for Stable Lithium Metal Anode in Carbonate Electrolyte

2021 ◽  
Author(s):  
Dongdong Liu ◽  
Xunhui Xiong ◽  
Qianwen Liang ◽  
Xianwen Wu ◽  
Haikuo Fu
Keyword(s):  
Donor Number ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Li Metal Anode ◽  
Carrier Solvent

The dissolution of LiNO3 in carbonate electrolytes is achieved by introducing pyridine as a new carrier solvent owing to its higher Gutmann donor number than NO3-. The Li metal anode...

scholarly journals Functional metal–organic framework boosting lithium metal anode performance via chemical interactions

2017 ◽  
Vol 8 (6) ◽  
pp. 4285-4291 ◽  
Author(s):  
Wen Liu ◽  
Yingying Mi ◽  
Zhe Weng ◽  
Yiren Zhong ◽  
Zishan Wu ◽  
...  
Keyword(s):  
Ion Transport ◽  
Metal Organic Framework ◽  
Lithium Metal ◽  
Chemical Interactions ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Metal Organic ◽  
Li Ion ◽  
Li Metal Anode ◽  
Organic Framework

Stable-cycling Li metal anode is realized with a MOF layer regulating Li-ion transport and Li deposition via chemical interactions.

Depressing the irreversible reactions on a three-dimensional interface towards a high-areal capacity lithium metal anode

2019 ◽  
Vol 7 (11) ◽  
pp. 6267-6274 ◽  
Author(s):  
Wei Deng ◽  
Shanshan Liang ◽  
Xufeng Zhou ◽  
Fei Zhao ◽  
Wenhua Zhu ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Lithium Metal ◽  
Current Collectors ◽  
Metal Anode ◽  
Irreversible Reaction ◽  
Conductive Coating ◽  
Lithium Metal Anode ◽  
Li Metal Anode ◽  
Areal Capacity

An ultrathin and conformal ion conductive coating is realized on 3D current collectors for preventing the irreversible reaction between the electrolyte and Li metal, which has been confirmed by in situ optical observation. At the high areal capacity of 10 mA h cm−2 for the Li metal anode, a stable CE of 98.9% for 800 h can be achieved.

Stable artificial solid electrolyte interphase films for lithium metal anode via metal–organic frameworks cemented by polyvinyl alcohol

2020 ◽  
Vol 8 (1) ◽  
pp. 251-258 ◽  
Author(s):  
Lishuang Fan ◽  
Zhikun Guo ◽  
Yu Zhang ◽  
Xian Wu ◽  
Chenyang Zhao ◽  
...  
Keyword(s):  
Polyvinyl Alcohol ◽  
Metal Organic Framework ◽  
Solid Electrolyte Interphase ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Sei Film ◽  
Metal Organic ◽  
Li Metal Anode ◽  
The Stability

Polyvinyl alcohol (PVA) as a “glue” to cement the metal organic framework (Zn-MOF) sheet as a reasonable artificial SEI film. The artificial SEI film can efficiently adapt to the changes of the volume during the cycle, significantly improve the stability of the Li metal anode.

A scalable slurry process to fabricate a 3D lithiophilic and conductive framework for a high performance lithium metal anode

2019 ◽  
Vol 7 (21) ◽  
pp. 13225-13233 ◽  
Author(s):  
Yuanming Liu ◽  
Xianying Qin ◽  
Shaoqiong Zhang ◽  
Lihan Zhang ◽  
Feiyu Kang ◽  
...  
Keyword(s):  
High Performance ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Li Metal Anode

A 3D lithiophilic hybrid Cu network was scalable fabricated for high-performance Li metal anode.

In Situ Formed Flexible Three-Dimensional Honeycomb-like Film for LiF/Li3N-riched Hybrid Organic-Inorganic Interphase on Li Metal Anode

2021 ◽  
Author(s):  
Daobin Mu ◽  
Chengwei Ma ◽  
Ge Mu ◽  
Haijian Lv ◽  
Chengcai Liu ◽  
...  
Keyword(s):  
Solid Electrolyte Interphase ◽  
Three Dimensional ◽  
High Energy ◽  
Liquid Electrolyte ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Li Metal Anode ◽  
Storage Batteries

The solid-electrolyte interphase (SEI) plays an important role in stabilizing lithium metal anode for high-energy storage batteries. However, the SEI between lithium metal anode and liquid electrolyte is usually unstable...

Lithium electrodeposited on lithiophilic LTO/Ti3C2 substrate as a dendrite-free lithium metal anode

2020 ◽  
Vol 8 (39) ◽  
pp. 20650-20657
Author(s):  
Ruiyi Gan ◽  
Yiling Liu ◽  
Na Yang ◽  
Cheng Tong ◽  
Mingming Deng ◽  
...  
Keyword(s):  
Electrochemical Deposition ◽  
Lithium Metal ◽  
Metal Anode ◽  
Layered Architecture ◽  
Lithium Metal Anode ◽  
Li Metal Anode

A stable, dendrite-free Li metal anode with a hairy-layered architecture is realized though a facile electrochemical deposition of Li on a lithiophilic LTO/Ti3C2 composite.

Favorable lithium deposition behaviors on flexible carbon microtube skeleton enable a high-performance lithium metal anode

2018 ◽  
Vol 6 (39) ◽  
pp. 19159-19166 ◽  
Author(s):  
Changzhi Sun ◽  
Tian Wu ◽  
Jianing Wang ◽  
Wenwen Li ◽  
Jun Jin ◽  
...  
Keyword(s):  
High Performance ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Lithium Deposition ◽  
Li Metal Anode

Favorable lithium deposition behaviors were investigated on FCMS for a high-performance Li metal anode.

A Protective Layer for Lithium Metal Anode: Why and How

Small Methods ◽  
2021 ◽  
pp. 2001035
Author(s):  
Zhiyuan Han ◽  
Chen Zhang ◽  
Qiaowei Lin ◽  
Yunbo Zhang ◽  
Yaqian Deng ◽  
...  
Keyword(s):  
Protective Layer ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode

scholarly journals Artificial dual solid-electrolyte interfaces based on in situ organothiol transformation in lithium sulfur battery

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Wei Guo ◽  
Wanying Zhang ◽  
Yubing Si ◽  
Donghai Wang ◽  
Yongzhu Fu ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Interface Reaction ◽  
Interfacial Instability ◽  
Anode Surface ◽  
Commercial Application ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Lithium Sulfur

AbstractThe interfacial instability of the lithium-metal anode and shuttling of lithium polysulfides in lithium-sulfur (Li-S) batteries hinder the commercial application. Herein, we report a bifunctional electrolyte additive, i.e., 1,3,5-benzenetrithiol (BTT), which is used to construct solid-electrolyte interfaces (SEIs) on both electrodes from in situ organothiol transformation. BTT reacts with lithium metal to form lithium 1,3,5-benzenetrithiolate depositing on the anode surface, enabling reversible lithium deposition/stripping. BTT also reacts with sulfur to form an oligomer/polymer SEI covering the cathode surface, reducing the dissolution and shuttling of lithium polysulfides. The Li–S cell with BTT delivers a specific discharge capacity of 1,239 mAh g−1 (based on sulfur), and high cycling stability of over 300 cycles at 1C rate. A Li–S pouch cell with BTT is also evaluated to prove the concept. This study constructs an ingenious interface reaction based on bond chemistry, aiming to solve the inherent problems of Li–S batteries.

Sign in / Sign up

Export Citation Format

Share Document