Solvatomorphs of (Bu4N)2[{Ag(N2-py)}2Mo8O26]: structure, colouration and phase transition

CrystEngComm ◽  
2021 ◽  
Author(s):  
Pavel A Abramov ◽  
Vladislav Komarov ◽  
Denis P Pishchur ◽  
Veronica S. Sulyaeva ◽  
Enrico Benassi ◽  
...  

Self-assembly of (Bu4N)4[β-Mo8O26], AgNO3 and N2-py (N2-py = 2,6-diaminopyridine) in DMF solution results in (Bu4N)2[β-{Ag(N2-py)}2Mo8O26] complex which crystallises as two phases: one (OP) is orange in colour and consists of...

2017 ◽  
Author(s):  
Niamh Mac Fhionnlaoich ◽  
Stephen Schrettl ◽  
Nicholas B. Tito ◽  
Ye Yang ◽  
Malavika Nair ◽  
...  

The arrangement of nanoscale building blocks into patterns with microscale periodicity is challenging to achieve via self-assembly processes. Here, we report on the phase transition-driven collective assembly of gold nanoparticles in a thermotropic liquid crystal. A temperature-induced transition from the isotropic to the nematic phase leads to the assembly of individual nanometre-sized particles into arrays of micrometre-sized aggregates, whose size and characteristic spacing can be tuned by varying the cooling rate. This fully reversible process offers hierarchical control over structural order on the molecular, nanoscopic, and microscopic level and is an interesting model system for the programmable patterning of nanocomposites with access to micrometre-sized periodicities.


ACS Nano ◽  
2018 ◽  
Vol 13 (1) ◽  
pp. 839-846 ◽  
Author(s):  
Hui-Qing Peng ◽  
Bin Liu ◽  
Peifa Wei ◽  
Pengfei Zhang ◽  
Haoke Zhang ◽  
...  

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
L. N. Carenza ◽  
G. Gonnella ◽  
A. Lamura ◽  
D. Marenduzzo ◽  
G. Negro ◽  
...  

Abstract We use computer simulations to study the morphology and rheological properties of a bidimensional emulsion resulting from a mixture of a passive isotropic fluid and an active contractile polar gel, in the presence of a surfactant that favours the emulsification of the two phases. By varying the intensity of the contractile activity and of an externally imposed shear flow, we find three possible morphologies. For low shear rates, a simple lamellar state is obtained. For intermediate activity and shear rate, an asymmetric state emerges, which is characterized by shear and concentration banding at the polar/isotropic interface. A further increment in the active forcing leads to the self-assembly of a soft channel where an isotropic fluid flows between two layers of active material. We characterize the stability of this state by performing a dynamical test varying the intensity of the active forcing and shear rate. Finally, we address the rheological properties of the system by measuring the effective shear viscosity, finding that this increases as active forcing is increased—so that the fluid thickens with activity.


Author(s):  
Naveed Zafar Ali ◽  
Branton J. Campbell ◽  
Martin Jansen

CsCoO2, featuring a two-dimensional layered architecture of edge- and vertex-linked CoO4 tetrahedra, is subjected to a temperature-driven reversible second-order phase transformation (α → β) at 100 K, which corresponds to a structural relaxation with concurrent tilting and breathing modes of edge-sharing CoO4 tetrahedra. In the present investigation, it was found that pressure induces a phase transition, which encompasses a dramatic change in the connectivity of the tetrahedra. At 923 K and 2 GPa, β-CsCoO2 undergoes a first-order phase transition to a new quenchable high-pressure polymorph, γ-CsCoO2. It is built up of a three-dimensional cristobalite-type network of vertex-sharing CoO4 tetrahedra. According to a Rietveld refinement of high-resolution powder diffraction data, the new high-pressure polymorph γ-CsCoO2 crystallizes in the tetragonal space group I41/amd:2 (Z = 4) with the lattice constants a = 5.8711 (1) and c = 8.3214 (2) Å, corresponding to a shrinkage in volume by 5.7% compared with the ambient-temperature and atmospheric pressure β-CsCoO2 polymorph. The pressure-induced transition (β → γ) is reversible; γ-CsCoO2 stays metastable under ambient conditions, but transforms back to the β-CsCoO2 structure upon heating to 573 K. The transformation pathway revealed is remarkable in that it is topotactic, as is demonstrated through a clean displacive transformation track between the two phases that employs the symmetry of their common subgroup Pb21 a (alternative setting of space group No. 29 that matches the conventional β-phase cell).


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Anusuya Pal ◽  
Amalesh Gope ◽  
John D. Obayemi ◽  
Germano S. Iannacchione

Abstract Multi-colloidal systems exhibit a variety of structural and functional complexity owing to their ability to interact amongst different components into self-assembled structures. This paper presents experimental confirmations that reveal an interesting sharp phase transition during the drying state and in the dried film as a function of diluting concentrations ranging from 100% (undiluted whole blood) to 12.5% (diluted concentrations). An additional complementary contact angle measurement exhibits a monotonic decrease with a peak as a function of drying. This peak is related to a change in visco-elasticity that decreases with dilution, and disappears at the dilution concentration for the observed phase transition equivalent to 62% (v/v). This unique behavior is clearly commensurate with the optical image statistics and morphological analysis; and it is driven by the decrease in the interactions between various components within this bio-colloid. The implications of these phenomenal systems may address many open-ended questions of complex hierarchical structures.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Gunnar Claussen ◽  
Alexander K. Hartmann

Abstract The determination of the parameters of cylindrical optical waveguides, e.g. the diameters $$\vec {d}=(d_1,\ldots ,d_r)$$ d → = ( d 1 , … , d r ) of r layers of (semi-) transparent optical fibres, can be executed by inverse evaluation of the scattering intensities that emerge under monochromatic illumination. The inverse problem can be solved by optimising the mismatch $$R(\vec {d})$$ R ( d → ) between the measured and simulated scattering patterns. The global optimum corresponds to the correct parameter values. The mismatch $$R(\vec {d})$$ R ( d → ) can be seen as an energy landscape as a function of the diameters. In this work, we study the structure of the energy landscape for different values of the complex refractive indices $$\vec {n}$$ n → , for $$r=1$$ r = 1 and $$r=2$$ r = 2 layers. We find that for both values of r, depending on the values of $$\vec {n}$$ n → , two very different types of energy landscapes exist, respectively. One type is dominated by one global minimum and the other type exhibits a multitude of local minima. From an algorithmic viewpoint, this corresponds to easy and hard phases, respectively. Our results indicate that the two phases are separated by sharp phase-transition lines and that the shape of these lines can be described by one “critical” exponent b, which depends slightly on r. Interestingly, the same exponent also describes the dependence of the number of local minima on the diameters. Thus, our findings are comparable to previous theoretical studies on easy-hard transitions in basic combinatorial optimisation or decision problems like Travelling Salesperson and Satisfiability. To our knowledge our results are the first indicating the existence of easy-hard transitions for a real-world optimisation problem of technological relevance.


Langmuir ◽  
2012 ◽  
Vol 28 (11) ◽  
pp. 4989-4995 ◽  
Author(s):  
N. Idayu Zahid ◽  
Osama K. Abou-Zied ◽  
Rauzah Hashim ◽  
Thorsten Heidelberg

1974 ◽  
Vol 63 ◽  
pp. 335-339
Author(s):  
R. Omnès ◽  
J. L. Puget

In a big bang cosmology in which the Universe is initially filled with thermal radiation at a very high temperature the number of nucleon-antinucleon pairs decreases exponentially with temperature when the latter falls below a value such that kT ~ 1 GeV. To explain the observed ratio η = N/Nph ~ 10-9 where N is the average baryon density and Nph the photon density, nucleons and antinucleons must have been separated in the thermal radiation at a temperature greater than 30 MeV. A mechanism has been suggested which would lead to a phase transition in thermal radiation for kT > 300 MeV resulting in two phases with opposite non zero baryon number. The interaction between nucleons and antinucleons at intermediate energy is repulsive according to the mesonic theory of nuclear forces. This can be checked experimentally by measuring with enough precision the energy of X-rays emitted by the protonium atom and this experiment is now under way at CERN. Different models have been made to investigate their consequences and in each case a phase transition has been found above a temperature of the order of 300 MeV (Omnes, 1972; Aldrovandi and Caser, 1973; Cisneros, 1973).


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