scholarly journals Tuning the Selectivity of Biomass Oxidation over Oxygen Evolution on NiO-OH Electrodes

2021 ◽  
Author(s):  
Laxman Gouda ◽  
Laurent Sévery ◽  
Thomas Moehl ◽  
Elena Mas Marzá ◽  
Pardis Adams ◽  
...  

Electrochemical reactions powered by renewable electricity are an important means of reducing the carbon footprint of large-scale chemical processes. Here, we investigate the efficient conversion of biomass-derived 5-hydroxymethylfurfural (HMF) to...

2021 ◽  
Author(s):  
Ulrich Sigmar Schubert ◽  
Oliver Nolte ◽  
Ivan Volodin ◽  
Christian Stolze ◽  
Martin D. Hager

Flow Batteries (FBs) currently are one of the most promising large-scale energy storage technologies for energy grids with a large share of renewable electricity generation. Among the main technological challenges...


2013 ◽  
Vol 3 (1) ◽  
pp. 77-99 ◽  
Author(s):  
Aletta G. Dorst ◽  
W.Gudrun Reijnierse ◽  
Gemma Venhuizen

The manual annotation of large corpora is time-consuming and brings about issues of consistency. This paper aims to demonstrate how general rules for determining basic meanings can be formulated in large-scale projects involving multiple analysts applying MIP(VU) to authentic data. Three sets of problematic lexical units — chemical processes, colours, and sharp objects — are discussed in relation to the question of how the basic meaning of a lexical unit can be determined when human and non-human senses compete as candidates for the basic meaning; these analyses can therefore be considered a detailed case study of problems encountered during step 3.b. of MIP(VU). The analyses show how these problematic cases were tackled in a large corpus clean-up project in order to streamline the annotations and ensure a greater consistency of the corpus. In addition, this paper will point out how the formulation of general identification rules and guidelines could provide a first step towards the automatic detection of linguistic metaphors in natural discourse.


Author(s):  
Ketil Søyland ◽  
Christer Wolden ◽  
Christopher Garmann ◽  
Debbie Harrison

<p>How can large-scale infrastructure projects be sustainable? The purpose of this paper is to discuss how engineering practices were changed in order to reduce the carbon footprint of the E39 Rogfast project, the world’s longest roadway sub-sea tunnel. The project will generate greenhouse gas (GHG)-emissions exceeding 1% of Norway’s total annual GHG-emissions. The paper covers the project process, including some of the challenges to be overcome.</p>


2021 ◽  
Author(s):  
Fengjiao Yu ◽  
Qi Ying ◽  
Shaofeng Ni ◽  
Chenxue Li ◽  
Daxiang Xue ◽  
...  

Large-scale application of rechargeable Zn-air batteries requires low-cost electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) as alternatives to noble metals. Herein, FeCo nanoparticles embedded in N-doped...


Author(s):  
Yordanka Stefanova ◽  

For the future life of young people their scientific education will allow them to live and act adequately in a society influenced by the ideas and values of science. Therefore, in the center of many educational systems an emphasis is placed on forming and developing scientific literacy in students. Inquiry-based approach in education is one of the important means for its formation and development as it puts the students in a situation where they carry out research activity, describe and analyze its results. In this article is presented an attempt to use inquiry-based approach in the study of chemical processes in Chemistry and environmental protection in the 10th. class. For its implementation a methodical model for application of scientific approach based on constructivist theories in education is developed. The results of a conducted experimental training for the determination of the expediency of the model are presented. A test is developed for establishing the training of students with an emphasis on scientific literacy. Testing results show that the developed methodical model creates good conditions for the development of scientific literacy.


Author(s):  
Hanwen Xu ◽  
Jiawei Zhu ◽  
Pengyan Wang ◽  
Ding Chen ◽  
Chengtian Zhang ◽  
...  

Rational design and construction of high-efficiency bifunctional catalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is crucial for large-scale hydrogen production by water splitting. Herein, by a...


2020 ◽  
Vol 34 (2) ◽  
pp. 353-363
Author(s):  
F. Kanwal ◽  
A. Batool ◽  
R. Akbar ◽  
S. Asim ◽  
M. Saleem

Electrochemical water splitting is the most promising pathway to produce high-purity hydrogen to alleviate global energy crisis. This reaction demands inexpensive, efficient and robust electrocatalyst for its commercial use. Herein, we demonstrate an effective, facile and scalable method for the synthesis of cerium doped Ni3Fe nanostructures as an electrocatalyst for oxygen evolution reaction (OER) by following simple chemical bath deposition route. The different molar ratios (3, 6 and 12 mM) of cerium in the chemical bath were used to study its effect on the structural and the electrochemical properties of the Ni3Fe nanostructured films. Doping of cerium contents induced variations in the morphology of deposited Ni3Fe nanostructures. The optimized electrocatalyst Ni3Fe/Ce-6 yielded high surface area catalyst nanosheets uniformly deposited on three-dimensional conductive scaffold to ensure increase in the exposure of doped Ni3Fe catalytic sites with high electrical conductivity. As a result, this earth-abundant electrocatalyst affords high OER performance with a small overpotential of 310 mV versus reversible hydrogen electrode (RHE) at 10 mA cm-2 and retains good stability up to ~ 10 h in alkaline electrolyte. This scalable strategy has great potential in future advancement of efficient and low-cost electrocatalysts for their large-scale application in energy conversion systems.                     KEY WORDS: Oxygen evolution, Electrocatalyst, Ni3Fe nanostructures, Cerium, Alkaline electrolyte   Bull. Chem. Soc. Ethiop. 2020, 34(2), 353-363 DOI: https://dx.doi.org/10.4314/bcse.v34i2.12


Information ◽  
2019 ◽  
Vol 10 (2) ◽  
pp. 61
Author(s):  
Xiaohuan Shan ◽  
Chunjie Jia ◽  
Linlin Ding ◽  
Xingyan Ding ◽  
Baoyan Song

A labeled graph is a special structure with node identification capability, which is often used in information networks, biological networks, and other fields. The subgraph query is widely used as an important means of graph data analysis. As the size of the labeled graph increases and changes dynamically, users tend to focus on the high-match results that are of interest to them, and they want to take advantage of the relationship and number of results to get the results of the query quickly. For this reason, we consider the individual needs of users and propose a dynamic Top-K interesting subgraph query. This method establishes a novel graph topology feature index (GTSF index) including a node topology feature index (NTF index) and an edge feature index (EF index), which can effectively prune and filter the invalid nodes and edges that do not meet the restricted condition. The multi-factor candidate set filtering strategy is proposed based on the GTSF index, which can be further pruned to obtain fewer candidate sets. Then, we propose a dynamic Top-K interesting subgraph query method based on the idea of the sliding window to realize the dynamic modification of the matching results of the subgraph in the dynamic evolution of the label graph, to ensure real-time and accurate results of the query. In addition, considering the factors, such as frequent Input/Output (I/O) and network communication overheads, the optimization mechanism of the graph changes and an incremental maintenance strategy for the index are proposed to reduce the huge cost of redundant operation and global updates. The experimental results show that the proposed method can effectively deal with a dynamic Top-K interesting subgraph query on a large-scale labeled graph, at the same time the optimization mechanism of graph changes and the incremental maintenance strategy of the index can effectively reduce the maintenance overheads.


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