High proton conductivity in a charge carrier induced Ni(II)–metal–organic framework

2022 ◽  
Author(s):  
Debabrata Chakraborty ◽  
Arijit Ghorai ◽  
Piyali Bhanja ◽  
Susanta Banerjee ◽  
Asim Bhaumik
Keyword(s):  
Fuel Cell ◽  
Charge Carrier ◽  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Membrane Material ◽  
High Proton Conductivity ◽  
High Proton ◽  
Metal Organic ◽  
Higher Temperature ◽  
A Charge

Fuel cell technology for hydrogen production demands high proton conductivity of the membrane material at a relatively higher temperature. Thus, optimization of the proton conductivity of the membrane material is...

Ground to conduct: mechanochemical synthesis of a metal–organic framework with high proton conductivity

2015 ◽  
Vol 51 (36) ◽  
pp. 7637-7640 ◽  
Author(s):  
Dariusz Matoga ◽  
Marcin Oszajca ◽  
Marcin Molenda
Keyword(s):  
Proton Conductivity ◽  
Mechanochemical Synthesis ◽  
Metal Organic Framework ◽  
Environmentally Friendly ◽  
High Proton Conductivity ◽  
Proton Conducting ◽  
High Proton ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

A high proton-conducting metal–organic framework (PCMOF) is prepared for the first time by economical and environmentally-friendly mechanochemistry.

High Proton Conductivity and Spectroscopic Investigations of Metal–Organic Framework Materials Impregnated by Strong Acids

2014 ◽  
Vol 6 (7) ◽  
pp. 5161-5167 ◽  
Author(s):  
Danil N. Dybtsev ◽  
Valentina G. Ponomareva ◽  
Sokhrab B. Aliev ◽  
Alexei P. Chupakhin ◽  
Marsel R. Gallyamov ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
High Proton Conductivity ◽  
Framework Materials ◽  
Spectroscopic Investigations ◽  
High Proton ◽  
Metal Organic ◽  
Strong Acids ◽  
Organic Framework

Selective CO2 Capture and High Proton Conductivity of a Functional Star-of-David Catenane Metal-Organic Framework

2017 ◽  
Vol 29 (42) ◽  
pp. 1703301 ◽  
Author(s):  
You-Gui Huang ◽  
Shu-Qi Wu ◽  
Wei-Hua Deng ◽  
Gang Xu ◽  
Fa-Lu Hu ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Co2 Capture ◽  
Metal Organic Framework ◽  
High Proton Conductivity ◽  
High Proton ◽  
Metal Organic ◽  
Organic Framework

Proton Conductivity, Stability and Potential for Polymorphism in Metal-Organic Framework Minerals

2018 ◽  
Author(s):  
Igor Huskić ◽  
Novendra Novendra ◽  
Dae-Woo Lim ◽  
Filip Topic ◽  
Hatem M. Titi ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Rare Metal ◽  
Framework Structure ◽  
High Proton Conductivity ◽  
High Proton ◽  
High Thermodynamic Stability ◽  
Metal Organic ◽  
Complex Organic ◽  
Organic Framework

We demonstrate that rare metal-organic framework (MOF) minerals stepanovite and zhemchuzhnikovite can exhibit properties comparable to known oxalate MOFs, including high proton conductivity at 25 <sup>o</sup>C, and retention of the framework structure upon thermal dehydration. They also have high thermodynamic stability, with a pronounced stabilizing effect of substituting aluminium for iron, illustrating a simple design to access stable, highly proton-conductive MOFs without using complex organic ligands. <br>

Proton Conductivity, Stability and Potential for Polymorphism in Metal-Organic Framework Minerals

2018 ◽  
Author(s):  
Igor Huskić ◽  
Novendra Novendra ◽  
Dae-Woo Lim ◽  
Filip Topic ◽  
Hatem M. Titi ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Rare Metal ◽  
Framework Structure ◽  
High Proton Conductivity ◽  
High Proton ◽  
High Thermodynamic Stability ◽  
Metal Organic ◽  
Complex Organic ◽  
Organic Framework

We demonstrate that rare metal-organic framework (MOF) minerals stepanovite and zhemchuzhnikovite can exhibit properties comparable to known oxalate MOFs, including high proton conductivity at 25 <sup>o</sup>C, and retention of the framework structure upon thermal dehydration. They also have high thermodynamic stability, with a pronounced stabilizing effect of substituting aluminium for iron, illustrating a simple design to access stable, highly proton-conductive MOFs without using complex organic ligands. <br>

A new europium metal–organic framework with both high proton conductivity and highly sensitive detection of ascorbic acid

CrystEngComm ◽  
2018 ◽  
Vol 20 (43) ◽  
pp. 6989-6994 ◽  
Author(s):  
Yue-Ying Yuan ◽  
Shuai-Liang Yang ◽  
Chen-Xi Zhang ◽  
Qing-Lun Wang
Keyword(s):  
Ascorbic Acid ◽  
Aqueous Solutions ◽  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Sensitive Detection ◽  
High Proton Conductivity ◽  
High Proton ◽  
Highly Sensitive ◽  
Metal Organic ◽  
Highly Sensitive Detection

The highest proton conductivity of the new Eu-MOF reaches up to 1.0 × 10−4 S cm−1. Furthermore, it is an excellent luminescence-based sensor for detection of ascorbic acid (AA) in aqueous solutions.

Multifunctional luminescent Zn(ii)-based metal–organic framework for high proton-conductivity and detection of Cr3+ ions in the presence of mixed metal ions

2018 ◽  
Vol 47 (5) ◽  
pp. 1383-1387 ◽  
Author(s):  
Xing Meng ◽  
Mei-Jie Wei ◽  
Hai-Ning Wang ◽  
Hong-Ying Zang ◽  
Zi-Yan Zhou
Keyword(s):  
Metal Ions ◽  
Proton Conductivity ◽  
Metal Organic Framework ◽  
High Proton Conductivity ◽  
Sensing Properties ◽  
Mixed Metal ◽  
High Proton ◽  
Rectangular Channels ◽  
Metal Organic ◽  
Organic Framework

A luminescent MOF with rectangular channels shows high proton conductivity up to 0.95 × 10−2 S cm−1 and selective Cr3+ sensing properties in presence of mixed metal ions.

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