Dienylation of N-benzoylhydrazones with CF3-substituted Homoallenylboronates in Water

Organic & Biomolecular Chemistry ◽

10.1039/d1ob02335g ◽

2022 ◽

Author(s):

Wei-Wei Ma ◽

Chao Yang ◽

Qiang Xie ◽

Yun-He Xu

Keyword(s):

Convenient Method ◽

Inert Gas

A convenient method for the dienylation of N-benzoylhydrazones was developed in water without any inert gas protection. The 2-methylamino-1,3-diene derivatives could be produced in water without additional catalyst and additive....

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Thickness and composition determinations from T.E.M. specimens using both x-ray and backscattered electron data

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100112816 ◽

1984 ◽

Vol 42 ◽

pp. 576-577

Author(s):

M.D. Ball ◽

H. Lagace ◽

M.C. Thornton

Keyword(s):

Electron Microscope ◽

Atomic Number ◽

Transmission Electron Microscope ◽

Convenient Method ◽

Flow Chart ◽

X Ray ◽

Intensity Measurements ◽

Transmission Electron ◽

Electron Intensity ◽

Backscattered Electron

The backscattered electron coefficient η for transmission electron microscope specimens depends on both the atomic number Z and the thickness t. Hence for specimens of known atomic number, the thickness can be determined from backscattered electron coefficient measurements. This work describes a simple and convenient method of estimating the thickness and the corrected composition of areas of uncertain atomic number by combining x-ray microanalysis and backscattered electron intensity measurements.The method is best described in terms of the flow chart shown In Figure 1. Having selected a feature of interest, x-ray microanalysis data is recorded and used to estimate the composition. At this stage thickness corrections for absorption and fluorescence are not performed.

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Stereo imaging in the shadow electron microscope

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100107745 ◽

1978 ◽

Vol 36 (1) ◽

pp. 120-121

Author(s):

W. C. T. Dowell

Keyword(s):

Electron Microscopy ◽

Electron Microscope ◽

Convenient Method ◽

Patent Application ◽

Standard Technique ◽

Stereo Imaging ◽

Stereo Images ◽

Specimen Height

Stereo imaging is not new to electron microscopy. Von Ardenne, who first published transmission pairs nearly forty hears ago, himself refers to a patent application by Ruska in 1934. In the early days of the electron microscope von Ardenne employed a pair of magnetic lenses to view untilted specimens but soon opted for the now standard technique of tilting the specimen with respect to the beam.In the shadow electron microscope stereo images can, of course, be obtained by tilting the specimen between micrographs. This obvious method suffers from the disadvantage that the magnification is very sensitive to small changes in specimen height which accompany tilting in the less sophisticated stages and it is also time consuming. A more convenient method is provided by horizontally displacing the specimen between micrographs. The specimen is not tilted and the technique is both simple and rapid, stereo pairs being obtained in less than thirty seconds.

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Rotary Beveling for In Situ Thin-Section Microscopy of Cell Cultures

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100099192 ◽

1981 ◽

Vol 39 ◽

pp. 550-551

Author(s):

Dean A. Handley ◽

Jack T. Alexander ◽

Shu Chien

Keyword(s):

Cell Growth ◽

Cell Cultures ◽

Molecular Interactions ◽

Convenient Method ◽

Petri Dish ◽

Simple Method ◽

Thin Section Microscopy ◽

Thin Sectioning ◽

Organic Fluids

In situ preparation of cell cultures for ultrastructural investigations is a convenient method by which fixation, dehydration and embedment are carried out in the culture petri dish. The in situ method offers the advantage of preserving the native orientation of cell-cell interactions, junctional regions and overlapping configurations. In order to section after embedment, the petri dish is usually separated from the polymerized resin by either differential cryo-contraction or solvation in organic fluids. The remaining resin block must be re-embedded before sectioning. Although removal of the petri dish may not disrupt the native cellular geometry, it does sacrifice what is now recognized as an important characteristic of cell growth: cell-substratum molecular interactions. To preserve the topographic cell-substratum relationship, we developed a simple method of tapered rotary beveling to reduce the petri dish thickness to a dimension suitable for direct thin sectioning.

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Fission Gas Bubbles in Fractured UO2

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100101177 ◽

1968 ◽

Vol 26 ◽

pp. 286-287

Author(s):

O. M. Katz

Keyword(s):

Electron Microscopy ◽

Thermal Gradient ◽

Gas Bubbles ◽

Inert Gas ◽

Thermal Gradients ◽

Fission Gas ◽

Beam Heating ◽

Limited Application ◽

Bubble Characteristics ◽

Electron Beam Heating

The swelling of irradiated UO2 has been attributed to the migration and agglomeration of fission gas bubbles in a thermal gradient. High temperatures and thermal gradients obtained by electron beam heating simulate reactor behavior and lead to the postulation of swelling mechanisms. Although electron microscopy studies have been reported on UO2, two experimental procedures have limited application of the results: irradiation was achieved either with a stream of inert gas ions without fission or at depletions less than 2 x 1020 fissions/cm3 (∼3/4 at % burnup). This study was not limited either of these conditions and reports on the bubble characteristics observed by transmission and fractographic electron microscopy in high density (96% theoretical) UO2 irradiated between 3.5 and 31.3 x 1020 fissions/cm3 at temperatures below l600°F. Preliminary results from replicas of the as-polished and etched surfaces of these samples were published.

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