Defective MnO2 nanosheets based free-standing and high mass loading electrodes for high energy density aqueous zinc ion batteries

Author(s):  
Ping Shang ◽  
Yuanhao Liu ◽  
Yingying Mei ◽  
Lisha Wu ◽  
Yanfeng Dong

Aqueous zinc ion batteries (ZIBs) hold great promises for large-scale energy storage and wearable devices due to their low cost and high safety, but suffer from low capacity and energy...

Nanoscale ◽  
2021 ◽  
Author(s):  
Chenxi Gao ◽  
Jiawei Wang ◽  
Yuan Huang ◽  
Zixuan Li ◽  
Jiyan Zhang ◽  
...  

Zinc-ion batteries (ZIBs) have attracted significant attention owing to their high safety, high energy density, and low cost. ZIBs have been studied as a potential energy device for portable and...


2015 ◽  
Vol 51 (91) ◽  
pp. 16381-16384 ◽  
Author(s):  
Yuelong Xin ◽  
Liya Qi ◽  
Yiwei Zhang ◽  
Zicheng Zuo ◽  
Henghui Zhou ◽  
...  

A novel organic solvent-assisted freeze-drying pathway, which can effectively protect and uniformly distribute active particles, is developed to fabricate a free-standing Li2MnO3·LiNi1/3Co1/3Mn1/3O2 (LR)/rGO electrode on a large scale.


Author(s):  
Sen Yang ◽  
Ting Li ◽  
Yiwei Tan

Potassium-ion batteries (PIBs) that serve as low-cost and large-scale secondary batteries are regarded as promising alternatives and supplement to lithium-ion batteries. Hybrid active materials can be featured with the synergistic...


2019 ◽  
Vol 11 (1) ◽  
Author(s):  
Lulu Lyu ◽  
Kwang-dong Seong ◽  
Jong Min Kim ◽  
Wang Zhang ◽  
Xuanzhen Jin ◽  
...  

Abstract Flexible supercapacitor electrodes with high mass loading are crucial for obtaining favorable electrochemical performance but still challenging due to sluggish electron and ion transport. Herein, rationally designed CNT/MnO2/graphene-grafted carbon cloth electrodes are prepared by a “graft-deposit-coat” strategy. Due to the large surface area and good conductivity, graphene grafted on carbon cloth offers additional surface areas for the uniform deposition of MnO2 (9.1 mg cm−2) and facilitates charge transfer. Meanwhile, the nanostructured MnO2 provides abundant electroactive sites and short ion transport distance, and CNT coated on MnO2 acts as interconnected conductive “highways” to accelerate the electron transport, significantly improving redox reaction kinetics. Benefiting from high mass loading of electroactive materials, favorable conductivity, and a porous structure, the electrode achieves large areal capacitances without compromising rate capability. The assembled asymmetric supercapacitor demonstrates a wide working voltage (2.2 V) and high energy density of 10.18 mWh cm−3.


2019 ◽  
Vol 12 (05) ◽  
pp. 1950073 ◽  
Author(s):  
Xiaoyong Fan ◽  
Kefan Ni ◽  
Jiaxing Han ◽  
Shan Wang ◽  
Lei Gou ◽  
...  

Rechargeable aqueous Zinc-ion batteries (ZIBs) are highly desirable for meeting ever-growing demands from large-scale energy storage fields due to their high energy density, high safety, low cost and environmental friendliness. Here, we report a binder-free porous MnO2 film achieved by cathodic electrodeposition coupled with subsequent high temperature heat treatment as cathode for aqueous ZIBs. Benefiting from the binder-free and porous structure, this electrode exhibits a stable capacity of about 94[Formula: see text]mAh[Formula: see text]g[Formula: see text] at 1.8[Formula: see text]A g[Formula: see text] over 1500 cycles. The capacity at 6.0[Formula: see text]A[Formula: see text]g[Formula: see text] remains 61[Formula: see text]mAh[Formula: see text]g[Formula: see text], which is 36% of that at 0.3[Formula: see text]A[Formula: see text]g[Formula: see text]. Electrochemical impedance spectroscopy (EIS) results indicate the MnO2 film after heat treatment has minor charge transfer impedance and high ions diffusion coefficient. The morphology revolution upon cycling suggests that the MnO2 film after heat treatment is easily transformed into nanosheet arrays with abundant voids facilitating ions transport and possess better structure stability. This work may offer an efficient pathway to explore a promising cathode for aqueous ZIBs.


Author(s):  
William C. Leighty

Alaska village survival is threatened by the high cost of imported fuels for heating, electricity generation, and vehicles. During Winter 2007–8, the price per gallon of heating oil and diesel generation fuel exceeded $8 in many villages. Many villagers were forced to move to Anchorage or Fairbanks. Although indigenous renewable energy (RE) resources may be adequate to supply a community’s total annual energy needs, the innate intermittent and seasonal output of the renewables — except geothermal, where available, which may be considered “baseload” — requires large-scale, low-cost energy storage to provide an annually-firm energy supply. Anhydrous ammonia, NH3, is the most attractive, carbon-free fuel for this purpose at Alaska village scale, because of its 17.8% mass hydrogen content and its high energy density as a low-pressure liquid, suitable for storage in inexpensive mild steel tanks. NH3 may be synthesized directly from renewable-source electricity, water, and atmospheric nitrogen (N2) via solid state ammonia synthesis (SSAS), a new process to be pioneered in Alaska.


Nanoscale ◽  
2021 ◽  
Author(s):  
Gunendra Prasad Ojha ◽  
Bishweshwar Pant ◽  
Jiwan Acharya ◽  
Mira Park

Commercial supercapacitors need high mass loading of more than 10 mg cm-2 and a high working potential window to resolve the low energy density concern. Herein, we have demonstrated a...


RSC Advances ◽  
2021 ◽  
Vol 11 (40) ◽  
pp. 24862-24871
Author(s):  
Binbin Liu ◽  
Yuan Huang ◽  
Jiawei Wang ◽  
Zixuan Li ◽  
Guoshen Yang ◽  
...  

Locust bean gum was utilized to prepare a free-standing quasi-solid-state ZnSO4/MnSO4 electrolyte. Zinc-ion batteries with locust bean gum electrolyte achieved high energy density and superior lifetime.


Sign in / Sign up

Export Citation Format

Share Document