scholarly journals Crystalline/amorphous CoP@CoB hierarchical core-shell nanorod array for enhanced hydrogen evolution

Author(s):  
Peidong Shi ◽  
Yu Zhang ◽  
Guanglu Zhang ◽  
Xiaojuan Zhu ◽  
Shao-Hua Wang ◽  
...  

Highly active, durable and cost-effective catalysts toward hydrogen evolution reaction (HER) are crucial for widespread use of electrochemical water splitting in hydrogen production. Herein, a hierarchical core-shell nanorod array comprising...

2020 ◽  
Vol 8 ◽  
Author(s):  
Wenjuan Han ◽  
Minhan Li ◽  
Yuanyuan Ma ◽  
Jianping Yang

Hydrogen has been considered as a promising alternative energy to replace fossil fuels. Electrochemical water splitting, as a green and renewable method for hydrogen production, has been drawing more and more attention. In order to improve hydrogen production efficiency and lower energy consumption, efficient catalysts are required to drive the hydrogen evolution reaction (HER). Cobalt (Co)-based metal-organic frameworks (MOFs) are porous materials with tunable structure, adjustable pores and large specific surface areas, which has attracted great attention in the field of electrocatalysis. In this review, we focus on the recent progress of Co-based metal-organic frameworks and their derivatives, including their compositions, morphologies, architectures and electrochemical performances. The challenges and development prospects related to Co-based metal-organic frameworks as HER electrocatalysts are also discussed, which might provide some insight in electrochemical water splitting for future development.


2018 ◽  
Vol 5 (10) ◽  
pp. 2425-2431 ◽  
Author(s):  
Zhaoqing Ding ◽  
Zhenghua Tang ◽  
Ligui Li ◽  
Kai Wang ◽  
Wen Wu ◽  
...  

Designing a highly active, robust and cost-effective electrocatalyst with multiple functionalities toward overall water splitting and rechargeable Zn–air battery applications is crucial and urgent for the development of sustainable energy sources.


Author(s):  
Min Liu ◽  
You Xu ◽  
Songliang Liu ◽  
Shuli Yin ◽  
Mengying Liu ◽  
...  

Hydrogen evolution reaction (HER) is an important process in electrochemical water splitting, and the key factor for HER technology lies in the development of cost-effective and highly efficient electrocatalysts. Herein,...


2018 ◽  
Vol 6 (21) ◽  
pp. 10028-10035 ◽  
Author(s):  
Jie Dong ◽  
Qiang Wu ◽  
Cunping Huang ◽  
Weifeng Yao ◽  
Qunjie Xu

Mo rich Mo2C synthesized via a facile two-step synthetic method is potentially a highly active non-noble metal electrocatalyst for hydrogen production via water electrolysis.


2021 ◽  
Author(s):  
Yaoxia Yang ◽  
Xuqin An ◽  
Mi Kang ◽  
Fengyao Guo ◽  
Lan Zhang ◽  
...  

The construction of excellent performance electrocatalysts for hydrogen evolution reaction (HER) with low-cost and economical strategy was still struggling with an enormous challenge in electrochemical water splitting. In this paper,...


Nanomaterials ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 929 ◽  
Author(s):  
Sajjad Hussain ◽  
Kamran Akbar ◽  
Dhanasekaran Vikraman ◽  
Rana Afzal ◽  
Wooseok Song ◽  
...  

To find an effective alternative to scarce, high-cost noble platinum (Pt) electrocatalyst for hydrogen evolution reaction (HER), researchers are pursuing inexpensive and highly efficient materials as an electrocatalyst for large scale practical application. Layered transition metal dichalcogenides (TMDCs) are promising candidates for durable HER catalysts due to their cost-effective, highly active edges and Earth-abundant elements to replace Pt electrocatalysts. Herein, we design an active, stable earth-abundant TMDCs based catalyst, WS(1−x)Sex nanoparticles-decorated onto a 3D porous graphene/Ni foam. The WS(1−x)Sex/graphene/NF catalyst exhibits fast hydrogen evolution kinetics with a moderate overpotential of ~−93 mV to drive a current density of 10 mA cm−2, a small Tafel slope of ~51 mV dec−1, and a long cycling lifespan more than 20 h in 0.5 M sulfuric acid, which is much better than WS2/NF and WS2/graphene/NF catalysts. Our outcomes enabled a way to utilize the TMDCs decorated graphene and precious-metal-free electrocatalyst as mechanically robust and electrically conductive catalyst materials.


2021 ◽  
Author(s):  
Hai-Lang Jia ◽  
Jiao Zhao ◽  
Zhiyuan Wang ◽  
Rui-Xin Chen ◽  
Mingyun Guan

Hydrogen production from water-splitting is one of the most promising hydrogen production methods, the preparation of hydrogen evolution reaction (HER) catalyst is very important. Although Pt based materials have the...


Nanoscale ◽  
2021 ◽  
Author(s):  
Zhuofan Gan ◽  
Chengyong Shu ◽  
Chengwei Deng ◽  
Wei Du ◽  
Bo HUANG ◽  
...  

Electrochemical water splitting is promising method to generate pollution-free and sustainable hydrogen energy. However, the specific activity and durability of noble metal catalysts is the main hindrance to hydrogen evolution...


Author(s):  
Xiaoqiang Zhan ◽  
Zhi Fang ◽  
Bing Li ◽  
Haitao Zhang ◽  
Leyao Xu ◽  
...  

Highly-active heterojunctions hold the pivotal function in photocatalytic hydrogen evolution reaction (HER). Herein, Ta3N5@ReS2 photocatalysts are rationally designed via the combination of template-assisted, hydrothermal and solution-adsorption processes, in which few...


Author(s):  
Hanwen Xu ◽  
Jiawei Zhu ◽  
Pengyan Wang ◽  
Ding Chen ◽  
Chengtian Zhang ◽  
...  

Rational design and construction of high-efficiency bifunctional catalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is crucial for large-scale hydrogen production by water splitting. Herein, by a...


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