From structural phase transition to highly sensitive lifetime based luminescent thermometer: multifaceted modification of thermometric performance in Y0.9-xNdxYb0.1PO4 nanocrystals

Author(s):  
Kamila Maciejewska ◽  
Marcin Szalkowski ◽  
Artur Bednarkiewicz ◽  
Lukasz Marciniak

The development of highly sensitive luminescent thermometer requires deep understanding of the correlation between structural properties of the host material with temperature-dependent luminescent properties of lanthanide emitters embedded in these...

Author(s):  
Linfei Yang ◽  
Jianjun Jiang ◽  
Lidong Dai ◽  
Haiying Hu ◽  
Meiling Hong ◽  
...  

The vibrational, electrical and structural properties of Ga2S3 were explored by Raman spectroscopy, EC measurements, HRTEM and First-principles theoretical calculations under different pressure environments up to 36.4 GPa.


2001 ◽  
Vol 74 (4) ◽  
pp. 391-408 ◽  
Author(s):  
M. Hidaka ◽  
K. Tanaka ◽  
M. Yoshimura ◽  
M. Ohba ◽  
K. Yamada ◽  
...  

2016 ◽  
Vol 122 (2) ◽  
Author(s):  
Kung-Liang Lin ◽  
Chih-Ming Lin ◽  
Yu-Sheng Lin ◽  
Sheng-Rui Jian ◽  
Yen-Fa Liao ◽  
...  

2020 ◽  
Vol 2 (10) ◽  
pp. 4390-4394 ◽  
Author(s):  
Jun Yi ◽  
Xueying Ge ◽  
Exian Liu ◽  
Tong Cai ◽  
Chujun Zhao ◽  
...  

We report a correlation between the structural phase transition of CsPbX3 (X = Cl, Br, I) nanocrystals (NCs) and their temperature dependent steady-state photoluminescence (PL) and time-resolved PL (TRPL).


Author(s):  
U. Schwarz ◽  
S. Bräuninger ◽  
U. Burkhardt ◽  
K. Syassen ◽  
M. Hanfland

AbstractStructural properties of the intermetallic compound GdGa


2014 ◽  
Vol 92 (5) ◽  
pp. 415-419 ◽  
Author(s):  
Bhoopendra Dhar Diwan

There has been significant concern in analyzing the structural stability, structural properties, and pressure-induced structural phase transition of refractory metal carbides, RC (R = Ti, Zr, Hf, V, Nb, and Ta), by using the three-body force potential model calculation modified approach. The more accurate description of the interionic spacing (r0) suggests that the interactions considered in the present computation are capable of correctly predicting the structural properties of these materials. In the preset paper, we have investigated the relative stability of the two competitive phases of metal carbides and discussed the possible phase transitions from its parental NaCl (B1) type phase to its most stable CsCl (B2) type phase in the pressure range 344–572 GPa. The computed interionic spacing (r0) and phase transition pressures (PT) are in reasonable agreement with the other reported data.


2018 ◽  
Author(s):  
Alyssa Henderson ◽  
Lianyang Dong ◽  
Sananda Biswas ◽  
Hannah Revell ◽  
Yan Xin ◽  
...  

The nature of the structural phase transition in the quantum magnets barlowite, Cu4(OH)6FBr, and claringbullite, Cu4(OH)6FCl was investigated. These materials consist of parallel-stacked Cu2+ kagome layers, separated by planes that contain Cu2+ cations and halide anions. The structural transition is of an order-disorder type, where at ambient temperature the interlayer Cu2+ ions are disordered over three equivalent positions. In barlowite, the dynamic disorder becomes static as the temperature is decreased, resulting in a lowering of the overall symmetry from hexagonal P63/mmc to orthorhombic. The dynamic disorder in claringbullite persists to lower temperatures, with a transition to orthorhombic space group Pnma observed in some samples. Ab initio density functional theory calculations explain this temperature-dependent structural phase transition and provide additional insights regarding the differences between these two materials.


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