Aluminum-Ion-Intercalation Nickel Oxide Thin Films for High Performance Electrochromic Energy Storage Devices

Author(s):  
Hongliang Zhang ◽  
Sheng Liu ◽  
Tao Xu ◽  
Weiping Xie ◽  
Guoxin Chen ◽  
...  

Aluminum-ion electrochromic energy storage device (EESD) is one of the most promising alternatives to lithium-ion device. Nevertheless, it faces a substantial challenge in the successful application due to the difficulties...

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4000
Author(s):  
Eunhwan Kim ◽  
Juyeon Han ◽  
Seokgyu Ryu ◽  
Youngkyu Choi ◽  
Jeeyoung Yoo

For decades, improvements in electrolytes and electrodes have driven the development of electrochemical energy storage devices. Generally, electrodes and electrolytes should not be developed separately due to the importance of the interaction at their interface. The energy storage ability and safety of energy storage devices are in fact determined by the arrangement of ions and electrons between the electrode and the electrolyte. In this paper, the physicochemical and electrochemical properties of lithium-ion batteries and supercapacitors using ionic liquids (ILs) as an electrolyte are reviewed. Additionally, the energy storage device ILs developed over the last decade are introduced.


2021 ◽  
Vol 1 (3) ◽  
pp. 49-56
Author(s):  
S.M. Zuyev ◽  
◽  
R.A. Maleyev ◽  
YU.M. Shmatkov ◽  
M.YU. Khandzhalov ◽  
...  

This article provides a comparative analysis of various energy storage devices. A detailed review and analysis of molecular energy storage units is carried out, their main characteristics and parame-ters, as well as their application areas, are determined. The main types of molecular energy storage are determined: electric double layer capacitors, pseudo capacitors, hybrid capacitors. Comparison of the characteristics of various batteries is given. The parameters of various energy storage devices are presented. The analysis of molecular energy storage devices and accumulators is carried out. Ttheir advantages and disadvantages are revealed. It has been shown that molecular energy storage or double layer electrochemical capacitors are ideal energy storage systems due to their high specific energy, fast charging and long life compared to conventional capacitors. The article presents oscillograms of a lithium-ion battery with a voltage of 10.8 V at a pulsed load current of 2A of a laptop with and without a molecular energy storage device, as well as oscil-lograms of a laptop with DVD lithium-ion battery with a voltage of 10.8 V with a parallel shutdown of a molecular energy storage device with a capacity of 7 F and without it. The comparative analysis shows that when the molecular energy storage unit with a 7 F capacity is switched on and off, transient processes are significantly improved and there are no supply voltage dips. The dependenc-es of the operating time of a 3.6 V 600 mAh lithium-ion battery at a load of 2 A for powering mo-bile cellular devices with and without a molecular energy storage are given. It is shown that when the molecular energy storage device is switched on, the battery operation time increases by almost 20%.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jing Hu ◽  
Xiaomin Tang ◽  
Qing Dai ◽  
Zhiqiang Liu ◽  
Huamin Zhang ◽  
...  

AbstractMembranes with fast and selective ions transport are highly demanded for energy storage devices. Layered double hydroxides (LDHs), bearing uniform interlayer galleries and abundant hydroxyl groups covalently bonded within two-dimensional (2D) host layers, make them superb candidates for high-performance membranes. However, related research on LDHs for ions separation is quite rare, especially the deep-going study on ions transport behavior in LDHs. Here, we report a LDHs-based composite membrane with fast and selective ions transport for flow battery application. The hydroxide ions transport through LDHs via vehicular (standard diffusion) & Grotthuss (proton hopping) mechanisms is uncovered. The LDHs-based membrane enables an alkaline zinc-based flow battery to operate at 200 mA cm−2, along with an energy efficiency of 82.36% for 400 cycles. This study offers an in-depth understanding of ions transport in LDHs and further inspires their applications in other energy-related devices.


RSC Advances ◽  
2019 ◽  
Vol 9 (60) ◽  
pp. 35045-35049
Author(s):  
Xu Chen ◽  
Jian Zhou ◽  
Jiarui Li ◽  
Haiyan Luo ◽  
Lin Mei ◽  
...  

High-performance lithium ion batteries are ideal energy storage devices for both grid-scale and large-scale applications.


2020 ◽  
Author(s):  
Jing Hu ◽  
Xiaomin Tang ◽  
Qing Dai ◽  
Zhiqiang Liu ◽  
Huamin Zhang ◽  
...  

Abstract Membranes with fast and selective ions transport are highly demanded for energy storage devices. Layered double hydroxides (LDHs), bearing uniform interlayer galleries and abundant hydroxyl groups covalently bonded within two-dimensional (2D) host layers, make them superb candidates for high-performance membranes. However, related research on LDHs for ions separation is quite rare, especially the deep-going study on ions transport behavior in LDHs. Here, we report a LDHs-based composite membrane with fast and selective ions transport for flow battery application. The hydroxide ions transport through LDHs via vehicular (standard diffusion) & Grotthuss (proton hopping) mechanisms is uncovered. The LDHs-based membrane enables an alkaline zinc-based flow battery to operate at 200 mA cm− 2, along with an energy efficiency of 82.36% for 400 cycles, which is among the highest efficiencies for zinc-based flow batteries. This study offers an in-depth understanding of ions transport in LDHs and further inspires their applications in other energy-related devices.


2021 ◽  
Author(s):  
Muhammad Irfan ◽  
Xianhua Liu ◽  
Suraya Mushtaq ◽  
Jonnathan Cabrera ◽  
Pingping Zhang

Abstract Development of sustainable electrochemical energy storage devices faces great challenge in exploring highly efficient and low cost electrode materials. Biomass waste derived carbonaceous materials can be used as an alternative to expensive metals in supercapacitor. However, their application limited by low performance. In this study, the combination use of persimmon waste derived carbon and transition metal nitride demonstrated strong potential for supercapacitor application. Persimmon based carbonaceous gel decorated with bimetallic-nitride (N-NiCo/PC) was firstly synthesized through a green hydrothermal method. Electrochemical properties of N-NiCo/PC as electrode in 6 M KOH electrolyte solution were evaluated by using cyclic voltammetry (CV) and charge-discharge measurements. The N-NiCo/PC exhibited 895.5 F/g specific capacitance at 1 A/g current density and maintained 91.5% capacitance retention after 900 cycles. Hence, the bimetallic nitride-based-composite catalyst is a potentially suitable material for high-performance energy storage devices. In addition, this work demonstrated a promising pathway for transforming environmental waste into sustainable energy conversion materials.


Author(s):  
Juan Yu ◽  
Xuyang Wang ◽  
Jiaxin Peng ◽  
Xuefeng Jia ◽  
Linbo Li ◽  
...  

Abstract Biomass-activated carbon materials are promising electrode materials for lithium-ion hybrid capacitors (LiCs) because of their natural hierarchical pore structure. The efficient utilization of structural pores in activated carbon is very important for their electrochemical performance. Herein, porous biomass-activated carbon (PAC) with large specific surface area was prepared using a one-step activation method with biomass waste as the carbon source and ZnCl2 as the activator. To further improve its pore structure utilization efficiency, the PAC was doped with nitrogen using urea as the nitrogen source. The experimental results confirmed that PAC-1 with a high nitrogen doping level of 4.66% exhibited the most efficient pore utilization among all the samples investigated in this study. PAC-1 exhibited 92% capacity retention after 8000 cycles, showing good cycling stability. Then, to maximize the utilization of high-efficiency energy storage devices, LiNi0.8Co0.15Al0.05O2 (NCA), a promising cathode material for lithium-ion batteries with high specific capacity, was compounded with PAC-1 in different ratios to obtain NCA@PC composites. The NCA@PC-9 composite exhibited excellent capacitance in LiCs and an energy density of 210.9 Wh kg-1 at a high power density of 13.3 kW kg-1. These results provide guidelines for the design of high-performance and low-cost energy storage devices.


2017 ◽  
Vol 5 (31) ◽  
pp. 16404-16411 ◽  
Author(s):  
Daily Rodríguez-Padrón ◽  
Alain R. Puente-Santiago ◽  
Alvaro Caballero ◽  
Almudena Benítez ◽  
Alina M. Balu ◽  
...  

A bionanomaterial based on horse hemoglobin and cobalt oxide magnetic nanoparticles was synthesized using a mechanochemical protocol and further employed in the design of an energy storage device.


2018 ◽  
Vol 19 (6) ◽  
pp. 22-28
Author(s):  
Petru Valentin Radu

The purpose of the article is to present mathematical models of energy storage devices with supercapacitors and accumulators. To control the energy storage device, it was proposed to use DC/DC buck/boost invertors and mathematical models are presented. The article gives example of simulation results of the proposed model of energy storage devices simulated in Matlab/Simulink.


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