Covalent Organic Polymers with Solid-State Dual-Color Fluorescence Tunable by Ultraviolet Irradiation

Author(s):  
Yan Chen ◽  
Wei Li ◽  
Rong-Zhi Gao ◽  
Xiao-Han Wang ◽  
An-na Tang ◽  
...  

An aldol condensation-based strategy is developed for preparing covalent organic polymers (COPs) with strong solution and solid-state dual fluorescence. Moreover, the fluorescence property can be facilely tuned by two ways:...

2017 ◽  
Vol 70 (11) ◽  
pp. 1227 ◽  
Author(s):  
Carol Hua ◽  
Stone Woo ◽  
Aditya Rawal ◽  
Floriana Tuna ◽  
James M. Hook ◽  
...  

A series of electroactive triarylamine porous organic polymers (POPs) with furan, thiophene, and selenophene (POP-O, POP-S, and POP-Se) linkers have been synthesised and their electronic and spectroscopic properties investigated as a function of redox state. Solid state NMR provided insight into the structural features of the POPs, while in situ solid state Vis-NIR and electron paramagnetic resonance spectroelectrochemistry showed that the distinct redox states in POP-S could be reversibly accessed. The development of redox-active porous organic polymers with heterocyclic linkers affords their potential application as stimuli responsive materials in gas storage, catalysis, and as electrochromic materials.


2021 ◽  
Author(s):  
Zhi-Hao Zhang ◽  
Shan-Qing Peng ◽  
Shumeng Chi ◽  
Hanyuan Chen ◽  
Lei Fan ◽  
...  

Porous organic polymers (POPs) represented a class of promising materials for delivering environmental and energy issues worldwide. However, the nature of amorphous makes their structure characterization in the solid state...


Nanoscale ◽  
2014 ◽  
Vol 6 (5) ◽  
pp. 2937-2944 ◽  
Author(s):  
Raj Kumar Koninti ◽  
Abhigyan Sengupta ◽  
Krishna Gavvala ◽  
Nirmalya Ballav ◽  
Partha Hazra

Sensing of bio-molecules using the fluorescence-switch/dual fluorescence property of an eminent anticancer drug, ellipticine, has been explored to directly monitor its efficient loading onto graphene oxide and subsequent release to biomolecules like DNA/RNA.


2017 ◽  
Vol 34 ◽  
pp. 803-820 ◽  
Author(s):  
M. Venkataravanappa ◽  
H. Nagabhushana ◽  
B. Daruka Prasad ◽  
G.P. Darshan ◽  
R.B. Basavaraj ◽  
...  
Keyword(s):  

CrystEngComm ◽  
2015 ◽  
Vol 17 (3) ◽  
pp. 498-502 ◽  
Author(s):  
Katarzyna Ostrowska ◽  
Łukasz Dudek ◽  
Jarosław Grolik ◽  
Marlena Gryl ◽  
Katarzyna Stadnicka

The article describes the synthesis of selective dual emissive intramolecular charge transfer (ICT) receptor for zinc ion in acetonitrile, exhibiting aggregation induced emission enhancement (AIEE) in solid state.


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