Modulating Hardness in Sc2(Ru5-xTMx)B4 through Empirical Considerations and Computational Analysis

Author(s):  
Jacob Hickey ◽  
Jakoah Brgoch

Ternary and higher-order borides remain an underexplored area in the search for hard materials. The difficulties associated with purely systematic experimental investigations have largely hindered the consideration of such complex...

2008 ◽  
Vol 07 (02) ◽  
pp. 337-343 ◽  
Author(s):  
T. SEKAR ◽  
R. MARAPPAN

Electrochemical machining (ECM) is a non-traditional process used mainly to cut hard or difficult to cut metals, where the application of a more traditional process is not convenient. Those difficult to cut metals demand high energy to form chips, which can result in thermal effects due to the high temperatures inherent to the process in the chip–tool interface. In traditional processes, the heat generated during the cut is dissipated to the tool, chip, workpiece and environment, affecting the surface integrity of the workpiece, mainly for those hard materials. In this work, experimental investigations have been made on the various influencing parameters involved in the Metal removal rate (MRR) and Surface roughness using ECM on AISI 202 steel. The major intervening parameters are studied and the relationship between the parameters has been determined to achieve maximum metal removal rate and minimum surface roughness by using NaNO 3-Aqua solution.


2011 ◽  
Vol 418-420 ◽  
pp. 1478-1481 ◽  
Author(s):  
Manoj Modi ◽  
Gopal Agarwal

Abstract: Ti-6Al-4V are used extensively in aerospace, medical, marine and surgical implants etc. but it is hard to machine. Machining of advanced difficult-to-machine very hard materials (Ti-6Al-4V, composites and ceramics) is a big challenge. By conventional machining processes, their machining is not only costly but results in poor surface finish and shorter tool life. To meet these challenges, new hybrid machining process (HMP) has been developed. This article is focused on hybrid machining process comprising of conventional surface grinding along with electro-discharge machining between the periphery of metal bonded diamond grinding wheel and flat rectangular shape workpiece. This process has the advantage of shaping advance engineering materials and difficult-to- machine very hard materials. The experimental investigations of various input parameters like wheel RPM, duty factor, current and pulse on-time on material removal rate of Ti-6Al-4V in EDDSG process have been reported here on newly self designed & fabricated set up. Keywords: Electro-Discharge Diamond Surface Grinding (EDDSG), Hybrid Machining Process (HMP), Ti-6Al-4V.


2019 ◽  
Vol Volume-3 (Issue-3) ◽  
pp. 1708-1711
Author(s):  
Rishabh Kumar Sahu ◽  
Saurabh Sharma ◽  
Vivek Swaroop | Vishal Kumar ◽  

2021 ◽  
Author(s):  
John Maynard ◽  
Bartomeu Galmés ◽  
Athanasios Stergiou ◽  
Mark Symes ◽  
Antonio Frontera ◽  
...  

We report a series of rotaxane-based anion-π catalysts in which the mechanical bond between a bipyridine macrocycle and an axle containing an NDI unit is intrinsic to the activity observed, including a [3]rotaxane that catalyses an otherwise disfavoured Michael addition in >60 fold selectivity over a competing decarboxylation pathway that dominates under Brønsted base conditions. The results are rationalized by detailed experimental investigations, electrochemical and computational analysis.


2014 ◽  
Vol 136 (4) ◽  
Author(s):  
M. Pasquali ◽  
W. Lacarbonara ◽  
P. Marzocca

Higher-order spectral (HOS) analysis tools are employed to extract the nonlinear dynamic response features of elastic and laminated plates by using both physics-based mechanical plate models and experimental data. Bispectral and trispectral densities are computed to highlight the presence and relative importance of quadratic and cubic nonlinearities. The former are associated with the presence of asymmetry either in the excitation or in the mechanical response of predeflected plates while the latter are due to midplane stretching effects. Besides the detection of these structural nonlinearities in perfect (baseline) fully clamped plates, the changes of such nonlinearities induced by the presence of small inertial imperfections (i.e., lumped masses) are identified and exploited to localize the imperfections. The numerical and experimental investigations are carried out both on isotropic and laminated composite plates subject to Gaussian white noise excitation. The effectiveness of the HOS-based procedure for detection of the nonlinearities is fully demonstrated for both types of plates.


Author(s):  
Roberto Martinez-Maldonado ◽  
Vanessa Echeverria ◽  
Katerina Mangaroska ◽  
Antonette Shibani ◽  
Gloria Fernandez-Nieto ◽  
...  

Teachers’ spatial behaviours in the classroom can strongly influence students’ engagement, motivation and other behaviours that shape their learning. However, classroom teaching behav-iour is ephemeral, and has largely remained opaque to computational analysis. This paper presents a library called ‘Moodoo’ that can serve to automatically model how teachers make use of the classroom space by analysing indoor positioning traces. The system automatically ex-tracts spatial metrics (e.g. teacher-student ratios, frequency of visits to students’ personal spaces, presence in classroom spaces of interest, index of dispersion and entropy), mapping from the teachers’ low-level positioning data to higher-order spatial constructs.


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