scholarly journals The ALMA-PILS survey: complex nitriles towards IRAS 16293–2422

2018 ◽  
Vol 616 ◽  
pp. A90 ◽  
Author(s):  
H. Calcutt ◽  
J. K. Jørgensen ◽  
H. S. P. Müller ◽  
L. E. Kristensen ◽  
A. Coutens ◽  
...  
Keyword(s):  
Organic Molecules ◽  
Functional Group ◽  
Evolutionary Stage ◽  
Warm Up ◽  
Star Forming ◽  
Star Forming Regions ◽  
Solar System Bodies ◽  
Using Data ◽  
First Time ◽  
Complex Organic

Context. Complex organic molecules are readily detected in the inner regions of the gaseous envelopes of forming protostars. Their detection is crucial to understanding the chemical evolution of the Universe and exploring the link between the early stages of star formation and the formation of solar system bodies, where complex organic molecules have been found in abundance. In particular, molecules that contain nitrogen are interesting due to the role nitrogen plays in the development of life and the compact scales such molecules have been found to trace around forming protostars. Aims. The goal of this work is to determine the inventory of one family of nitrogen-bearing organic molecules, complex nitriles (molecules with a –C≡N functional group) towards two hot corino sources in the low-mass protostellar binary IRAS 16293–2422. This work explores the abundance differences between the two sources, the isotopic ratios, and the spatial extent derived from molecules containing the nitrile functional group. Methods. Using data from the Protostellar Interferometric Line Survey (PILS) obtained with ALMA, we determine abundances and excitation temperatures for the detected nitriles. We also present a new method for determining the spatial structure of sources with high line density and large velocity gradients – Velocity-corrected INtegrated emission (VINE) maps. Results. We detect methyl cyanide (CH3CN) as well as five of its isotopologues, including CHD2CN, which is the first detection in the interstellar medium (ISM). We also detect ethyl cyanide (C2H5CN), vinyl cyanide (C2H3CN), and cyanoacetylene (HC3N). We find that abundances are similar between IRAS 16293A and IRAS 16293B on small scales except for vinyl cyanide which is only detected towards the latter source. This suggests an important difference between the sources either in their evolutionary stage or warm-up timescales. We also detect a spatially double-peaked emission for the first time in molecular emission in the A source, suggesting that this source is showing structure related to a rotating toroid of material. Conclusions. With high-resolution observations, we have been able to show for the first time a number of important similarities and differences in the nitrile chemistry in these objects. These illustrate the utility of nitriles as potential tracers of the physical conditions in star-forming regions.

scholarly journals Detection of glyceraldehyde and glycerol in VUV processed interstellar ice analogues containing formaldehyde: a general formation route for sugars and polyols

2020 ◽  
Vol 496 (4) ◽  
pp. 5292-5307
Author(s):  
Y Layssac ◽  
A Gutiérrez-Quintanilla ◽  
T Chiavassa ◽  
F Duvernay
Keyword(s):  
Laboratory Experiments ◽  
Organic Molecules ◽  
General Scheme ◽  
Star Forming ◽  
Star Forming Regions ◽  
Vuv Photolysis ◽  
Different Temperatures ◽  
Low Mass ◽  
Species Production ◽  
Complex Organic

ABSTRACT Complex organic molecules (COMs) have been identified toward high- and low-mass protostars as well as molecular clouds. Among them, sugar-like and polyol two carbon-bearing molecules such as glycolaldehyde (GA) and ethylene glycol (EG) are of special interest. Recent laboratory experiments have shown that they can efficiently be formed via atom addition reactions between accreting H-atoms and CO molecules or via energetic processes (UV, electrons) on ice analogues containing methanol or formaldehyde. In this study, we report new laboratory experiments on the low-temperature solid state formation of complex organic molecules – the first sugar glyceraldehyde and its saturated derivative glycerol – through VUV photolysis performed at three different temperatures (15, 50, and 90 K) of astrochemically relevant ices composed of water and formaldehyde. We get evidence that the species production depends on the ice temperature during photolysis. The results presented here indicate that a general scheme of aldose and polyol formation is plausible and that heavier COMs than GA and EG could exist in interstellar environments. We propose a general pathway involving radical-formaldehyde reactions as common initiation step for aldose and polyol formation. Future telescope observations may give additional clues on their presence in star-forming regions as observations are currently limited because of the detection thresholds.

scholarly journals A study of interstellar aldehydes and enols as tracers of a cosmic ray-driven nonequilibrium synthesis of complex organic molecules

2016 ◽  
Vol 113 (28) ◽  
pp. 7727-7732 ◽  
Author(s):  
Matthew J. Abplanalp ◽  
Samer Gozem ◽  
Anna I. Krylov ◽  
Christopher N. Shingledecker ◽  
Eric Herbst ◽  
...  
Keyword(s):  
Organic Molecules ◽  
Cosmic Ray ◽  
Formation Mechanisms ◽  
Molecular Precursors ◽  
Star Forming ◽  
Star Forming Regions ◽  
Interstellar Ices ◽  
A Chain ◽  
Nonequilibrium Chemistry ◽  
Complex Organic

Complex organic molecules such as sugars and amides are ubiquitous in star- and planet-forming regions, but their formation mechanisms have remained largely elusive until now. Here we show in a combined experimental, computational, and astrochemical modeling study that interstellar aldehydes and enols like acetaldehyde (CH3CHO) and vinyl alcohol (C2H3OH) act as key tracers of a cosmic-ray-driven nonequilibrium chemistry leading to complex organics even deep within low-temperature interstellar ices at 10 K. Our findings challenge conventional wisdom and define a hitherto poorly characterized reaction class forming complex organic molecules inside interstellar ices before their sublimation in star-forming regions such as SgrB2(N). These processes are of vital importance in initiating a chain of chemical reactions leading eventually to the molecular precursors of biorelevant molecules as planets form in their interstellar nurseries.

scholarly journals Complex Organic Molecules in Star-Forming Regions of the Magellanic Clouds

2019 ◽  
Vol 3 (10) ◽  
pp. 2088-2109 ◽  
Author(s):  
Marta Sewiło ◽  
Steven B. Charnley ◽  
Peter Schilke ◽  
Vianney Taquet ◽  
Joana M. Oliveira ◽  
...  
Keyword(s):  
Organic Molecules ◽  
Magellanic Clouds ◽  
Star Forming ◽  
Star Forming Regions ◽  
Complex Organic

Searching for methylamine in Orion-KL using ALMA archival data

2018 ◽  
Vol 14 (S345) ◽  
pp. 386-387
Author(s):  
Harumi Minamoto ◽  
Yoko Oya ◽  
Hirota Tomoya ◽  
Hideko Nomura
Keyword(s):  
Molecular Clouds ◽  
Organic Molecules ◽  
Rotational Temperature ◽  
Archival Data ◽  
Diagram Method ◽  
Star Forming ◽  
Robust Detection ◽  
Star Forming Regions ◽  
Complex Organic ◽  
Amino Acid Glycine

AbstractMethylamine (CH3NH2) is the simplest amine and thought to be a potential interstellar precursor to the amino acid glycine (NH2CH2COOH). It is confirmed by the experimental work and in terms of exploration in the Solar system, CH3NH2 has been detected in two comets. However, in molecular clouds, a robust detection of CH3NH2 has been reported only for Sgr B2(N) so far, while a variety of complex organic molecules have been detected by radio observations in many star-forming regions. To search for CH3NH2, we used the ALMA Cycle 2 archival data toward Orion Kleinmann-Low nebula (Orion-KL) at Band 6 and found 5 candidate emission at the hot core region. By using the rotation diagram method, we evaluated its tentative column density and rotational temperature to be 4.9×10 cm−2 and 102 K, respectively.

scholarly journals The first detections of the key prebiotic molecule PO in star-forming regions

2017 ◽  
Vol 13 (S332) ◽  
pp. 409-414
Author(s):  
Víctor M. Rivilla ◽  
Francesco Fontani ◽  
Maite Beltrán ◽  
Anton Vasyunin ◽  
Paola Caselli ◽  
...  
Keyword(s):  
Massive Star ◽  
Abundance Ratio ◽  
Warm Up ◽  
Star Forming ◽  
Evolved Stars ◽  
Star Forming Regions ◽  
Prebiotic Molecule ◽  
Using Data ◽  
Molecular Abundances ◽  
Gas Phase Ion

AbstractPhosphorus is a crucial element in prebiotic chemistry, especially the P−O bond, which is key for the formation of the backbone of the deoxyribonucleic acid. So far, PO had only been detected towards the envelope of evolved stars, and never towards star-forming regions. We report the first detection of PO towards two massive star-forming regions, W51 e1/e2 and W3(OH), using data from the IRAM 30m telescope. PN has also been detected towards the two regions. The abundance ratio PO/PN is 1.8 and 3 for W51 and W3(OH), respectively. Our chemical model indicates that the two molecules are chemically related and are formed via gas-phase ion-molecule and neutral-neutral reactions during the cold collapse. The molecules freeze out onto grains at the end of the collapse and desorb during the warm-up phase once the temperature reaches ~35 K. The observed molecular abundances of 10−10 are predicted by the model if a relatively high initial abundance of 5× 10−9 of initial phosphorus is assumed.

scholarly journals Evolutionary study of complex organic molecules in high-mass star-forming regions

2020 ◽  
Vol 641 ◽  
pp. A54 ◽  
Author(s):  
A. Coletta ◽  
F. Fontani ◽  
V. M. Rivilla ◽  
C. Mininni ◽  
L. Colzi ◽  
...  
Keyword(s):  
Star Formation ◽  
Organic Molecules ◽  
High Mass ◽  
Physical Parameters ◽  
Mass Star ◽  
Evolutionary Trend ◽  
Star Forming ◽  
Star Forming Regions ◽  
Molecular Abundances ◽  
Complex Organic

We have studied four complex organic molecules (COMs), the oxygen-bearing methyl formate (CH3OCHO) and dimethyl ether (CH3OCH3) as well as the nitrogen-bearing formamide (NH2CHO) and ethyl cyanide (C2H5CN), towards a large sample of 39 high-mass star-forming regions representing different evolutionary stages, from early to evolved phases. We aim to identify potential correlations and chemical links between the molecules and to trace their evolutionary sequence through the star formation process. We analysed spectra obtained at 3, 2, and 0.9 mm with the IRAM-30m telescope. We derived the main physical parameters for each species by fitting the molecular lines. We compared them and evaluated their evolution while also taking several other interstellar environments into account. We report detections in 20 sources, revealing a clear dust absorption effect on column densities. Derived abundances range between ~ 10−10−10−7 for CH3OCHO and CH3OCH3, ~ 10−12−10−10 for NH2CHO, and ~ 10−11−10−9 for C2H5CN. The abundances of CH3OCHO, CH3OCH3, and C2H5CN are very strongly correlated (r ≥ 0.92) across ~ 4 orders of magnitude. We note that CH3OCHO and CH3OCH3 show the strongest correlations in most parameters, and a nearly constant ratio (~ 1) over a remarkable ~ 9 orders of magnitude in luminosity for the following wide variety of sources: pre-stellar to evolved cores, low- to high-mass objects, shocks, Galactic clouds, and comets. This indicates that COMs chemistry is likely early developed and then preserved through evolved phases. Moreover, the molecular abundances clearly increase with evolution, covering ~ 6 orders of magnitude in the luminosity/mass ratio. We consider CH3OCHO and CH3OCH3 to be most likely chemically linked. They could, for example, share a common precursor, or be formed one from the other. Based on correlations, ratios, and the evolutionary trend, we propose a general scenario for all COMs, involving a formation in the cold, earliest phases of star formation and a following increasing desorption with the progressive thermal and shock-induced heating of the evolving core.

scholarly journals Observations of Complex Molecules in Low-Mass Protostars

2011 ◽  
Vol 7 (S280) ◽  
pp. 43-52 ◽  
Author(s):  
Nami Sakai ◽  
Satoshi Yamamoto
Keyword(s):  
Organic Molecules ◽  
Carbon Chain ◽  
Chemical Diversity ◽  
Chemical Compositions ◽  
Evolutionary Stage ◽  
Mass Star ◽  
Star Forming ◽  
Key Factor ◽  
Low Mass ◽  
Complex Organic

AbstractLow-mass star forming regions are rich inventories of complex organic molecules. Furthermore, they show significant chemical diversity even among sources in a similar physical evolutionary stage (i.e. Class 0 sources). One distinct case is the hot corino chemistry characterized by rich existence of saturated complex organic molecules such as HCOOCH3 and C2H5CN, whereas the other is the warm carbon-chain chemistry (WCCC) characterized by extraordinary richness of unsaturated complex organic molecules such as carbon-chain molecules. We here summarize these observational achievements during the last decade, and present a unified picture of carbon chemistry in low-mass protostellar cores. The chemical diversity most likely originates from the source-to-source difference in chemical compositions of grain mantles. In particular, the gas-phase abundance of CH4 evaporated from grain mantles is thought to be a key factor for appearance of WCCC. The origin of the diversity and its evolution to protopranetary disks are discussed.

scholarly journals Astrochemistry During the Formation of Stars

2020 ◽  
Vol 58 (1) ◽  
pp. 727-778
Author(s):  
Jes K. Jørgensen ◽  
Arnaud Belloche ◽  
Robin T. Garrod
Keyword(s):  
Solar System ◽  
Organic Molecules ◽  
Galactic Center ◽  
Galactic Disk ◽  
System Size ◽  
High Mass ◽  
Star Forming ◽  
Star Forming Regions ◽  
Chemical Models ◽  
Complex Organic

Star-forming regions show a rich and varied chemistry, including the presence of complex organic molecules—in both the cold gas distributed on large scales and the hot regions close to young stars where protoplanetary disks arise. Recent advances in observational techniques have opened new possibilities for studying this chemistry. In particular, the Atacama Large Millimeter/submillimeter Array has made it possible to study astrochemistry down to Solar System–size scales while also revealing molecules of increasing variety and complexity. In this review, we discuss recent observations of the chemistry of star-forming environments, with a particular focus on complex organic molecules, taking context from the laboratory experiments and chemical models that they have stimulated. The key takeaway points include the following: ▪  The physical evolution of individual sources plays a crucial role in their inferred chemical signatures and remains an important area for observations and models to elucidate. ▪  Comparisons of the abundances measured toward different star-forming environments (high-mass versus low-mass, Galactic Center versus Galactic disk) reveal a remarkable similarity, which is an indication that the underlying chemistry is relatively independent of variations in their physical conditions. ▪  Studies of molecular isotopologues in star-forming regions provide a link with measurements in our own Solar System, and thus may shed light on the chemical similarities and differences expected in other planetary systems.

scholarly journals Complex organic molecules in low-mass protostars on Solar System scales

2020 ◽  
Vol 639 ◽  
pp. A87 ◽  
Author(s):  
M. L. van Gelder ◽  
B. Tabone ◽  
Ł. Tychoniec ◽  
E. F. van Dishoeck ◽  
H. Beuther ◽  
...  
Keyword(s):  
Star Formation ◽  
Solar System ◽  
Gas Phase ◽  
Organic Molecules ◽  
High Mass ◽  
Local Source ◽  
Star Forming ◽  
Star Forming Regions ◽  
Low Mass ◽  
Complex Organic

Context. Complex organic molecules (COMs) are thought to form on icy dust grains in the earliest phase of star formation. The evolution of these COMs from the youngest Class 0/I protostellar phases toward the more evolved Class II phase is still not fully understood. Since planet formation seems to start early, and mature disks are too cold for characteristic COM emission lines, studying the inventory of COMs on Solar- System scales in the Class 0/I stage is relevant. Aims. Our aim is to determine the abundance ratios of oxygen-bearing COMs in Class 0 protostellar systems on scales of ~100 AU radius. We aim to compare these abundances with one another, and to the abundances of other low-mass protostars such as IRAS 16293-2422B and HH 212. Additionally, using both cold and hot COM lines, the gas-phase abundances can be tracked from a cold to a hot component, and ultimately be compared with those in ices to be measured with the James Webb Space Telescope (JWST). The abundance of deuterated methanol allows us to probe the ambient temperature during the formation of this species. Methods. ALMA Band 3 (3 mm) and Band 6 (1 mm) observations are obtained for seven Class 0 protostars in the Perseus and Serpens star-forming regions. By modeling the inner protostellar region using local thermodynamic equilibrium models, the excitation temperature and column densities are determined for several O-bearing COMs including methanol (CH3OH), acetaldehyde (CH3CHO), methyl formate (CH3OCHO), and dimethyl ether (CH3OCH3). Abundance ratios are taken with respect to CH3OH. Results. Three out of the seven of the observed sources, B1-c, B1-bS (both Perseus), and Serpens S68N (Serpens), show COM emission. No clear correlation seems to exist between the occurrence of COMs and source luminosity. The abundances of several COMs such as CH3OCHO, CH3OCH3, acetone (CH3COCH3), and ethylene glycol ((CH2OH)2) are remarkably similar for the three COM-rich sources; this similarity also extends to IRAS 16293-2422B and HH 212, even though collectively these sources originate from four different star-forming regions (i.e., Perseus, Serpens, Ophiuchus, and Orion). For other COMs like CH3CHO, ethanol (CH3CH2OH), and glycolaldehyde (CH2OHCHO), the abundances differ by up to an order of magnitude, indicating that local source conditions become important. B1-c hosts a cold (Tex ≈ 60 K), more extended component of COM emission with a column density of typically a few percent of the warm/hot (Tex ~ 200 K) central component. A D/H ratio of 1–3% is derived for B1-c, S68N, and B1-bS based on the CH2DOH/CH3OH ratio (taking into account statistical weighting) suggesting a temperature of ~15 K during the formation of methanol. This ratio is consistent with other low-mass protostars, but is lower than for high-mass star-forming regions. Conclusions. The abundance ratios of most O-bearing COMs are roughly fixed between different star-forming regions, and are presumably set at an earlier cold prestellar phase. For several COMs, local source properties become important. Future mid-infrared facilities such as JWST/MIRI will be essential for the direct observation of COM ices. Combining this with a larger sample of COM-rich sources with ALMA will allow ice and gas-phase abundances to be directly linked in order to constrain the routes that produce and maintain chemical complexity during the star formation process.

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