scholarly journals Contamination risk assessment of the Transboundary Zeravshan River using chemical and isotopic studies

2019 ◽  
Vol 98 ◽  
pp. 07021
Author(s):  
Parviz Normatov ◽  
Inom Normatov

The results of chemical and isotope analyses of water of the Zeravshan River are presented. Results show that the low salinity of the river water in the upstream reach is formed mainly by water dissolution of minerals in natural rocks, i.e. the existence of a water-rock interaction process. The detection of heavy cations in the composition of the river water is due to their transport long distances in the form of microparticles by wind and accumulation in snow cover and glaciers. During the melting of snow and glaciers, and during rain events, pollutants are carried by streams, small rivers, and finally by Zeravshan River that distributes the pollutants over long distances.

Clay Minerals ◽  
1994 ◽  
Vol 29 (4) ◽  
pp. 591-608 ◽  
Author(s):  
M. Osborne ◽  
R. S. Haszeldine ◽  
A. E. Fallick

AbstractDiagenetic kaolinite in reservoir sandstones of the Brent Group precipitated following the dissolution of detrial feldspar. Two distinct morphologies of kaolinite occur: (1) early diagenetic vermiform kaolinite which is often associated with expanded detrital micas; (2) later diagenetic ‘blocky’ kaolinite. Combined hydrogen and oxygen isotopic studies suggest that vermiform kaolinite precipitated at 25–50°C, and blocky kaolinite at 50–80°C, from pore-waters of a similar isotopic composition (δ18O = −6.5 to −3.5‰). These pore-waters are interpreted to be either a mixture of meteoric and compactional waters, or alternatively a meteoric water that had evolved isotopically due to water-rock interaction. Kaolinite precipitation occurred predominantly during the late Cretaceous to early Eocene. Influx of meteoric water into the Brent Group, probably occurred during the Palaeocene. Fluid flow across the entire basin was driven by a hydrostatic head on the East Shetland Platform palaeo-landmass to the west. The development of the two kaolinite morphologies is possibly related to the degree of supersaturation at the time of precipitation. At low degrees of supersaturation, vermiform kaolinite precipitated slowly upon detrital mica surfaces. Blocky kaolinite precipitated more rapidly into open pore-space at higher degrees of supersaturation. Precipitation of blocky kaolinite was perhaps triggered by the decay of oxalate.


2008 ◽  
Vol 39 (3) ◽  
pp. 209-222 ◽  
Author(s):  
N. O. Jørgensen ◽  
J. Heinemeier

A multi-isotope approach in combination with hydrochemical data and borehole logging is applied to identify the source of brackish groundwater in a borehole in the well field of Neksø Municipal Waterworks in Bornholm, Denmark. The aquifer lithology consists of fractured Lower Cambrian sandstones resting on Proterozoic crystalline basement. The water body in the studied borehole is significantly stratified with respect to the hydrochemical and isotopic signatures and reveal a Na–Ca–Cl–HCO3 water type and TDS values >1,000 mg/L below a halocline at 40–55 m below measurement point (bmp). The occurrence of brackish groundwater is remarkable for this aquifer, which otherwise yields potable groundwater of good quality. The stable isotope (18O and 2H) compositions indicate a meteoric origin of the brackish groundwater, which rules out seawater intrusion into the aquifer. 14C activities show apparent 14C ages of the brackish groundwater in the range 2200–4300 yr (BP), whereas the freshwater samples above the halocline indicate modern age. Hydrochemical (Cl/Br and Sr) and isotopic studies (18O, 2H and 87Sr/86Sr) of the brackish groundwater point to a well-mixed and homogeneous water body reflecting long water–rock interaction and suggest a contribution of palaeowater from the fractured crystalline basement which has intruded into the Lower Cambrian sandstone aquifer.


1987 ◽  
Vol 112 ◽  
Author(s):  
D. G. Brookins ◽  
S. J. Lambert

AbstractDefense-generated transuranic (TRU) waste will be stored at WIPP in the bedded halite of the Salado Formation (Permian), which is overlain by the impure Permian evaporites of the Rustler Formation and the Dewey Lake Red Beds. Both the Rustler and Dewey Lake contain abundant to less common secondary selenite veins of uncertain origin, and dissolution zones occur in the Rustler. The Rustler Formation also contains two dolomite aquifers, the Magenta and Culebra members. The purpose of this study is to determine whether vein selenite is locally derived, or has been introduced in moving groundwater solutions. We have used Sr isotopic studies and REE, U and other trace element data to address the problem. The Sr isotopic data show that neither the Salado nor Rustler anhydrites have exchanged with secondary sources of Sr, and this is supported by the REE and U data. Further, selenite veins from the Rustler possess Sr isotopic compositions identical to the Rustler, indicating local origin, and this is also supported by the U and REE data. Selenite veins from the Dewey Lake Red Beds possess Sr isotopic compositions closer to surface caliche deposits, and may contain near-surface derived Sr. U and REE data show more scatter and evidence for extrinsic sources than the vein/host-rock pairs from the Rustler. Sr isotopic compositions of the Magenta and Culebra indicate that the Magenta has undergone less water/rock interaction than the Culebra. Collectively, the data argue for more possible surface or near-surface water/rock interactions in the Dewey Lake Red Beds than in the Rustler Formation; such interactions in the Salado Formation have been minimal.


2020 ◽  
Author(s):  
Marie Haut-Labourdette ◽  
◽  
Daniele Pinti ◽  
André Poirier ◽  
Marion Saby ◽  
...  

2021 ◽  
Vol 3 (7) ◽  
Author(s):  
Otman EL Mountassir ◽  
Mohammed Bahir ◽  
Driss Ouazar ◽  
Abdelghani Chehbouni ◽  
Paula M. Carreira

AbstractThe city of Essaouira is located along the north-west coast of Morocco, where groundwater is the main source of drinking, domestic and agricultural water. In recent decades, the salinity of groundwater has increased, which is why geochemical techniques and environmental isotopes have been used to determine the main sources of groundwater recharge and salinization. The hydrochemical study shows that for the years 1995, 2007, 2016 and 2019, the chemical composition of groundwater in the study area consists of HCO3–Ca–Mg, Cl–Ca–Mg, SO4–Ca and Cl–Na chemical facies. The results show that from 1995 to 2019, electrical conductivity increased and that could be explained by a decrease in annual rainfall in relation to climate change and water–rock interaction processes. Geochemical and environmental isotope data show that the main geochemical mechanisms controlling the hydrochemical evolution of groundwater in the Cenomanian–Turonian aquifer are the water–rock interaction and the cation exchange process. The diagram of δ2H = 8 * δ18O + 10 shows that the isotopic contents are close or above to the Global Meteoric Water Line, which suggests that the aquifer is recharged by precipitation of Atlantic origin. In conclusion, groundwater withdrawal should be well controlled to prevent groundwater salinization and further intrusion of seawater due to the lack of annual groundwater recharge in the Essaouira region.


Author(s):  
Carleton R. Bern ◽  
Justin E. Birdwell ◽  
Aaron M. Jubb

Comparisons of hydrocarbon-produced waters from multiple basins and experiments using multiple shales illustrate water–rock interaction influence on produced water chemistry.


1990 ◽  
Vol 84 (1-4) ◽  
pp. 322-325 ◽  
Author(s):  
C.I. Steefel ◽  
P. Van Capellen ◽  
K.L Nagy ◽  
A.C. Lasaga

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