scholarly journals Perylenemonoimide as a Versatile Fluoroprobe: The Past, Present, and Future

2021 ◽  
Author(s):  
Rupam Roy ◽  
Aasif Khan ◽  
Oendrila Chatterjee ◽  
Sukomal Bhunia ◽  
Apurba Lal Koner
Keyword(s):  
Quantum Yield ◽  
Absorption Coefficient ◽  
Self Assembly ◽  
Fluorescence Quantum Yield ◽  
Photophysical Properties ◽  
Fluorescence Sensing ◽  
The Past ◽  
Functional Dyes ◽  
High Absorption Coefficient ◽  
High Absorption

Perylene dyes have transcended their role as simple colorants and have been reinvigorated as functional dyes. Based on the substitution at the peri position by six-membered carboxylic imides, the perylene family is principally embellished with perylene diimides (PDIs) and perylene monoimides (PMIs). Perylene dyes are widely acclaimed and adorned on account of their phenomenal thermal, chemical, and photostability juxtaposed with their high absorption coefficient and near-unity fluorescence quantum yield. Although symmetric PDIs have always been in the limelight, its asymmetrical counterpart PMI is already rubbing shoulders, thanks to the consistent efforts of several scientific minds. Recently, there has been an upsurge in engendering PMI-based versatile organic architectures decked with intriguing photophysical properties and pertinent applications. In this review, the synthesis and photophysical features of various PMI-based derivatives along with their relevant applications in the arena of organic photovoltaics, photocatalysis, self-assembly, fluorescence sensing, and bioimaging are accrued and expounded, hoping to enlighten the less delved but engrossing realm of PMIs.

scholarly journals Rational Design of Aqueous Conjugated Polymer Nanoparticles as Potential Theranostic Agents of Breast Cancer

2021 ◽  
Author(s):  
Panagiota Koralli ◽  
Spyridon Tsikalakis ◽  
Maria Goulielmaki ◽  
Stella Arelaki ◽  
Janina Müller ◽  
...  
Keyword(s):  
Breast Cancer ◽  
Absorption Coefficient ◽  
Conjugated Polymer ◽  
Rational Design ◽  
Polymer Nanoparticles ◽  
Quantum Yields ◽  
Conjugated Polymer Nanoparticles ◽  
Theranostic Agents ◽  
High Absorption Coefficient ◽  
High Absorption

Conjugated polymer nanoparticles (CPNs) have emerged as a new promising class of cancer theranostic agents due to their desirable optical features, such as high absorption coefficient and photoluminescence quantum yields,...

Mechanical and optical behaviors: strain synergy effects in high temperature phase oxide of lead

2021 ◽  
Author(s):  
Qidong Kang ◽  
Fei Yang ◽  
Xinyu Zhang ◽  
Ziyu Hu
Keyword(s):  
High Temperature ◽  
Absorption Coefficient ◽  
Bulk Material ◽  
High Temperature Phase ◽  
Temperature Phase ◽  
Synergy Effects ◽  
High Absorption Coefficient ◽  
Very High ◽  
High Absorption

Since lead has a very high absorption coefficient μ, that the radiations from within the bulk material do not penetrate the layers. While, the oxygen and water (O2 and H2O)...

9.6%- Efficient All-Inorganic Sb2(S,Se)3 Solar Cell with MnS Hole-Transporting Laye

2022 ◽  
Author(s):  
Chen Qian ◽  
Jianjun Li ◽  
Kaiwen Sun ◽  
Chenhui Jiang ◽  
Jialiang Huang ◽  
...  
Keyword(s):  
Solar Cell ◽  
Absorption Coefficient ◽  
Light Harvesting ◽  
Low Cost ◽  
The Poor ◽  
Hole Transporting ◽  
Low Toxic ◽  
High Absorption Coefficient ◽  
Poor Stability ◽  
High Absorption

Antimony selenosulfide, Sb2(S,Se)3, has emerged as a promising light-harvesting material for its high absorption coefficient, suitable bandgap, low-toxic and low-cost constituents. However, the poor stability and high cost of widely...

Photophysical properties of microencapsulated phthalocyanines

2010 ◽  
Vol 14 (03) ◽  
pp. 278-283 ◽  
Author(s):  
Virginia E. Diz ◽  
Gabriela A. Gauna ◽  
Cristian A. Strassert ◽  
Josefina Awruch ◽  
Lelia E. Dicelio
Keyword(s):  
Differential Scanning Calorimetry ◽  
Light Scattering ◽  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Photophysical Properties ◽  
Oxygen Production ◽  
Electronic Microscopy ◽  
Scanning Calorimetry ◽  
Singlet Molecular Oxygen ◽  
Photophysical Parameters

Lipophilic substituted zinc(II) phthalocyanines: 2,3,9,10,16,17,23,24-octakis[(N,N-dimethylaminoethylsulfanyl)]phthalocyaninatozinc(II) (S1) and tetrakis(N,N-dibutylaminoethoxy)phthalocyaninatozinc(II) (3) were incorporated into soybean L-α-phosphatidylcholine (SPC) liposomes of 100 nm diameter. Liposomes were characterized by static light scattering (SLS), transmission electronic microscopy (TEM), and differential scanning calorimetry. The fluorescence quantum yield and singlet molecular oxygen production of 3 are Φ F = 0.15 and ΦΔ = 0.24, respectively, whereas the same photophysical parameters for S1 are Φ F = 0.13 and ΦΔ = 0.51. Higher values of Φ F and ΦΔ are obtained in organic solvent for both dyes. Synthesis of compound 3 has also been reported.

scholarly journals Oxidation of 3-amino-1-phenylprop-1-enes by monoamine oxidase and their use in a continuous assay of the enzyme

1988 ◽  
Vol 256 (3) ◽  
pp. 911-915 ◽  
Author(s):  
C H Williams ◽  
J Lawson ◽  
F R C Backwell
Keyword(s):  
Monoamine Oxidase ◽  
Absorption Coefficient ◽  
Mitochondrial Protein ◽  
Bovine Liver ◽  
Spectrophotometric Assay ◽  
Monoamine Oxidase A ◽  
Monoamine Oxidase B ◽  
High Absorption Coefficient ◽  
Continuous Assay ◽  
High Absorption

3-Amino-1-phenylprop-1-ene (cinnamylamine) and some derivatives were examined as substrates for monoamine oxidases A and B in mitochondria. All of the amines examined were readily oxidized by monoamine oxidase B but much less readily by monoamine oxidase A. E-Cinnamylamine was found to have Km 0.025 mM and Vmax. 3.9 nmol/min per mg of mitochondrial protein. Corresponding values with monoamine oxidase A were 0.026 mM and 0.85 nmol/min per mg respectively. Despite their different stereochemistry, E- and Z-N-methylcinnamylamines were almost equally effective as substrates for monoamine oxidase B. The characteristic u.v. absorbance and high absorption coefficient of cinnamaldehyde, the product produced by enzymic oxidation of cinnamylamine, is utilized in a sensitive continuous spectrophotometric assay for both enzymes in the rat and for the assay of a purified monoamine oxidase B from bovine liver.

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