Direct Synthesis of Enones by Visible-Light-Promoted Oxygenation of Trisubstituted Olefins Using Molecular Oxygen
Keyword(s):
A one-step synthesis of enones from olefins is described. The reaction was performed under visible-light irradiation in the presence of molecular oxygen and a photocatalyst. The reaction proceeded with various types of trisubstituted olefins to give enones in good yields with high regioselectivity. In particular, oxygen- and nitrogen-containing functional groups, heteroaromatic rings, and cyclopropanes were tolerated. Mechanistic studies and previous reports indicated that the active oxygen species generated in the reaction system is singlet oxygen.
Keyword(s):
2014 ◽
Vol 47
(3)
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pp. 740-749
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Keyword(s):
2015 ◽
Vol 408
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pp. 172-178
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Keyword(s):
Keyword(s):
2003 ◽
Vol 107
(18)
◽
pp. 4364-4373
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Keyword(s):
2014 ◽
Vol 4
(1)
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pp. 1
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