Alkyl chain length dependent mobility of organic field-effect transistors based on thienyl-furan oligomers determined by the transfer line method

2006 ◽  
Vol 88 (8) ◽  
pp. 083514 ◽  
Author(s):  
Takeo Minari ◽  
Yasuo Miyata ◽  
Miki Terayama ◽  
Takashi Nemoto ◽  
Tohru Nishinaga ◽  
...  
MRS Advances ◽  
2016 ◽  
Vol 1 (38) ◽  
pp. 2653-2658
Author(s):  
S. Inoue ◽  
H. Minemawari ◽  
J. Tsutsumi ◽  
T. Hamai ◽  
S. Arai ◽  
...  

ABSTRACTHere we discuss requirements for high performance and solution processable organic semiconductors, by presenting a systematic investigation of 7-alkyl-2-phenyl[1]benzothieno[3,2-b][1]benzothiophenes (Ph-BTBT-Cn’s). We found that the solubility and thermal properties of Ph-BTBT-Cn’s depend systematically on the substituted alkyl-chain length n. The observed features are well understood in terms of the change of molecular packing motif with n: The compounds with n ≤ 4 do not form independent alkyl chain layers, whereas those with n ≥ 5 form isolated alkyl chain layers. The latter compounds afford a series of isomorphous bilayer-type crystal structures that form two-dimensional carrier transport layers within the crystals. We also show that the Ph-BTBT-C10 afford high performance single-crystalline field-effect transistors the mobility of which reaches as high as 15.9 cm2/Vs. These results demonstrate a crucial role of the substituted alkyl chain length for obtaining high performance organic semiconductors and field-effect transistors.


2020 ◽  
Vol 8 (44) ◽  
pp. 15759-15770
Author(s):  
Alexandra Harbuzaru ◽  
Iratxe Arrechea-Marcos ◽  
Alberto D. Scaccabarozzi ◽  
Yingfeng Wang ◽  
Xugang Guo ◽  
...  

Different charge transport mechanisms at the device interface are found for a series of ladder-type semiconductors with increasing chain length.


2014 ◽  
Vol 7 (1) ◽  
pp. 351-358 ◽  
Author(s):  
Jang Yeol Back ◽  
Tae Kyu An ◽  
Ye Rim Cheon ◽  
Hyojung Cha ◽  
Jaeyoung Jang ◽  
...  

2000 ◽  
Vol 39 (Part 2, No. 8B) ◽  
pp. L872-L874 ◽  
Author(s):  
Keiichi Kaneto ◽  
Wee Y. Lim ◽  
Wataru Takashima ◽  
Takeshi Endo ◽  
Masahiro Rikukawa

2010 ◽  
Vol 97 (6) ◽  
pp. 063302 ◽  
Author(s):  
Yong Xu ◽  
R. Gwoziecki ◽  
I. Chartier ◽  
R. Coppard ◽  
F. Balestra ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (13) ◽  
pp. 7526-7530 ◽  
Author(s):  
Jung Hun Lee ◽  
Young Hun Lee ◽  
Yeon Hee Ha ◽  
Jaehyuk Kwon ◽  
Seungmoon Pyo ◽  
...  

DPP-based semiconducting polymers with different lengths of alkyl chain spacer were blended with PMMA for fabricating OFETs.


Sign in / Sign up

Export Citation Format

Share Document