Mn-doped AlN nanowires with room temperature ferromagnetic ordering

2007 ◽  
Vol 90 (9) ◽  
pp. 092118 ◽  
Author(s):  
Y. Yang ◽  
Q. Zhao ◽  
X. Z. Zhang ◽  
Z. G. Liu ◽  
C. X. Zou ◽  
...  
2008 ◽  
Vol 8 (9) ◽  
pp. 4500-4505 ◽  
Author(s):  
Gotluru Kedarnath ◽  
Sandip Dey ◽  
Vimal K. Jain ◽  
Gautam K. Dey ◽  
Ramakant M. Kadam

The Reaction of [HgCl2(tmeda)] with NaTeCH2CH2NMe2 gave a mercury tellurolate, [Hg(TeCH2CH2·NMe2)2] (1) as a yellow crystalline solid, which was characterized by elemental analysis, UV-vis, mass and NMR (1H, 13C, 125Te, 199Hg) spectroscopy. Thermolysis of 1 in hexadecylamine (HDA) at 90 °C in the absence and presence of Mn(OAc)2·4H2O gave undoped and Mn-doped HgTe nanoparticles which were characterized by XRD, EDAX, TEM, EPR and magnetic measurements. These particles could be synthesized with mean particle size of 6–7 nm (from TEM). Manganese substitution at Hg site in HgTe lead to a linear decrease in lattice parameter with increasing concentration of Mn. Magnetization measurements showed ferromagnetic ordering at room temperature with very small coercive field (Hc, 50 Oe) for Hg0.973Mn0.027 Te sample. This sample also exhibited distinct ferromagnetic resonance (FMR) in the EPR spectrum.


2013 ◽  
Vol 1552 ◽  
pp. 83-88 ◽  
Author(s):  
Sreekanth K. Mahadeva ◽  
Zhi-Yong Quan ◽  
J. C. Fan ◽  
K. S. Sreelatha ◽  
L. Belova ◽  
...  

ABSTRACTWe report on preliminary studies of low (14 at.%) and high (53at.%) concentration Mn doped MgO films deposited by co-sputtering from metallic Mn and Mg targets. The structural, surface morphologies and magnetic properties of the films of different thickness were studied. All the as grown films are found to be amorphous and film surfaces are found to be flawless and homogeneous. We observe at room temperature robust ferromagnetic loops with a saturation magnetization value that is a function of film thickness reaching a maximum of ∼38.5 emu/cm3 in the Mn0.53Mg0.47O film at a thickness of ∼92 nm. In thicker films room-temperature ferromagnetic ordering is suppressed and eventually at a thickness around 120nm the expected diamagnetism of the bulk appears. The origin of ferromagnetism may be attributed to cation defects at the Mg-site.


2009 ◽  
Vol 23 (08) ◽  
pp. 2029-2040 ◽  
Author(s):  
R. K. SINGHAL ◽  
S. N. DOLIA ◽  
M. S. DHAWAN ◽  
S. K. GAUR ◽  
SUDHISH KUMAR ◽  
...  

Following the theoretical prediction of ferromagnetism in Mn - and Co -doped ZnO , there has been an immense experimental search for dilute semiconductors that show ferromagnetic ordering above room temperature, and several workers have reported ferromagnetism in bulk samples as well as in thin films of these materials. Mn -doped ZnO is the key material in this regard, which has been, in the recent past, shown to exhibit such magnetic properties. Many more such attempts have either led to failure or to a much lower Tc, and there have been a lot of confronting reports casting considerable doubts on the magnetism in this system. In order to shed some light, we have prepared and characterized dilute Mn -doped (2 and 4%) ZnO pellets. SQUID measurements confirm that the 2% sample shows above room temperature ferromagnetic ordering, the ferromagnetic contribution coming mainly from the bulk. The ordering gets completely quenched for 4% Mn doping. Upon cooling down, the 2% Mn doped sample showed further enhancement in magnetic properties appreciably. On the other hand, the 4% sample did not show any ferromagnetic ordering, even down to 5 K, and has been found to retain the paramagnetic character.


2006 ◽  
Vol 35 (4) ◽  
pp. 635-640 ◽  
Author(s):  
W. Y. Shim ◽  
K. A. Jeon ◽  
K. I. Lee ◽  
S. Y. Lee ◽  
M. H. Jung ◽  
...  

2009 ◽  
Vol 1183 ◽  
Author(s):  
Mukes Kapilashrami ◽  
Jun Xu ◽  
Valter Ström ◽  
K V Rao ◽  
Lyubov Belova

AbstractEvidence for long range ferromagnetic order above room-temperature, RTFM, in pristine ZnO, In2O3, TiO2 nanoparticles and thin films, containing no nominal magnetic elements have been reported recently. This could question the origin of RTFM in doped dilute alloys if for example the ZnO matrix itself develops a defect induced magnetic order with a significant moment per unit cell. In this presentation we report a systematic study of the film thickness dependence of RTFM in pure ZnO deposited by DC Magnetron Sputtering. We observe a maximum in the saturation magnetization, MS, value of 0.62 emu/g (0,018 μB/unit cell), for a ˜480 nm film deposited in an oxygen ambience of appropriate pressure. Above a thickness of around 1 μm the films are diamagnetic as expected. We thus see a sequential transition from ferromagnetism to para- and eventual diamagnetism as a function of film thickness in ZnO. We also find that in such a ZnO matrix with a maximum intrinsic defect induced moment, on doping with Mn the maximum enhanced MS value of 0.78 emu/g is obtained for 1at.% Mn doping. With this approach of appropriate doping in a defect tailored matrix, we routinely obtain RTFM in both undoped and Mn- doped ZnO thin films.


2007 ◽  
Vol 101 (6) ◽  
pp. 063526 ◽  
Author(s):  
Rong Huang ◽  
Hiroyuki Hayashi ◽  
Fumiyasu Oba ◽  
Isao Tanaka

2017 ◽  
Vol 11 (5) ◽  
pp. 1367-1373 ◽  
Author(s):  
Burak Demirhan ◽  
Buket Er Demirhan ◽  
Nusret Ertas ◽  
Hayriye Eda Satana Kara

Author(s):  
D. Sanyal ◽  
Mahuya Chakrabarti ◽  
Vaishali Naik ◽  
Tapatee Kundu Roy ◽  
Debasis Bhowmick ◽  
...  

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