Influence of crystallite size on the thermal conductivity in BaTiO3 nanoceramics

2007 ◽  
Vol 90 (11) ◽  
pp. 114104 ◽  
Author(s):  
A. Jeżowski ◽  
J. Mucha ◽  
R. Pazik ◽  
W. Strek
RSC Advances ◽  
2016 ◽  
Vol 6 (44) ◽  
pp. 37773-37783 ◽  
Author(s):  
Sumanta Kumar Karan ◽  
Amit Kumar Das ◽  
Ranadip Bera ◽  
Sarbaranjan Paria ◽  
Anirban Maitra ◽  
...  

Dependence of thermal conductivity and energy density on the amount of crystalline γ-phase and γ-crystallite size of PVDF in Fe-rGO/PVDF nanocomposites has been explored.


Author(s):  
Cristina V. Manzano ◽  
Olga Caballero-Calero ◽  
Maxime Tranchant ◽  
Enrico Bertero ◽  
Pablo Cervino-Solana ◽  
...  

The thermal conductivity of CuNi alloys grown by pulsed electrodeposition is reduced by the nanostructuration to a value of 9.0 ± 0.9 W m−1 K−1 due to the incorporation of saccharine in the electrolyte which allowed reduction of the crystallite size.


RSC Advances ◽  
2016 ◽  
Vol 6 (94) ◽  
pp. 91171-91178 ◽  
Author(s):  
T. N. M. Ngo ◽  
T. T. M. Palstra ◽  
G. R. Blake

The thermoelectric performance of CuCrO2 with different particle size and morphology is influenced more by electrical resistivity than thermal conductivity.


2019 ◽  
Vol 51 (1) ◽  
pp. 101-114 ◽  
Author(s):  
M.U. Siddiqui ◽  
U. Hayat ◽  
Abul Arif ◽  
N. Saheb

In the current work, an improved model to estimate the thermal conductivity of spark plasma sintered nanocomposites is presented. In the developed model, the thermal conductivity of the matrix was modeled as a function of the average matrix crystallite size rather than taking a constant matrix thermal conductivity. The model has been validated against experimentally measured thermal conductivity of Al2O3-SiC-CNT hybrid nanocomposites. Using the experimental and modeling results, it was shown that the addition of SiC and CNT inclusions to alumina resulted in a decrease in its thermal conductivity. The main reason for this decrease was found to be the reduction in the thermal conductivity of the alumina matrix itself because of the reduction in the crystallite size. Additional reduction in the composite thermal conductivity was due to the matrix-inclusion interface resistance and porosity. The predicted and measured thermal conductivities were found to be in good agreement.


2010 ◽  
Vol 667-669 ◽  
pp. 1089-1094 ◽  
Author(s):  
Gerda Rogl ◽  
Michael Zehetbauer ◽  
Michael Kerber ◽  
Peter Rogl ◽  
Ernst Bauer

For thermoelectrics it is important to produce thermodynamically stable bulk nanostructured materials. Ball milling/hot pressing was shown to reduce the crystallite size by a factor of 100 and to reach about 100 nm with dislocation densities of 1012 – 1013m-2. Thereby thermoelectric properties of single, double and multifilled Sb-based skutterudites were improved significantly leading to figures of merit ZT, which in some cases are twice as high as those of their microstructured counterparts. With HPT treatment the crystallite size can be decreased to even 50 nm with dislocation densities as high as 1015m-2. The small grains as well as the high dislocation density result in a further lowering of thermal conductivity holding a high potential for future enhancement of ZT.


Author(s):  
Thomas R. McKee ◽  
Peter R. Buseck

Sediments commonly contain organic material which appears as refractory carbonaceous material in metamorphosed sedimentary rocks. Grew and others have shown that relative carbon content, crystallite size, X-ray crystallinity and development of well-ordered graphite crystal structure of the carbonaceous material increases with increasing metamorphic grade. The graphitization process is irreversible and appears to be continous from the amorphous to the completely graphitized stage. The most dramatic chemical and crystallographic changes take place within the chlorite metamorphic zone.The detailed X-ray investigation of crystallite size and crystalline ordering is complex and can best be investigated by other means such as high resolution transmission electron microscopy (HRTEM). The natural graphitization series is similar to that for heat-treated commercial carbon blacks, which have been successfully studied by HRTEM (Ban and others).


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