The Role of Surface Transport in the Stability and Breakdown of Foams

1952 ◽  
Vol 5 (4) ◽  
pp. 697 ◽  
Author(s):  
WE Ewers ◽  
KL Sutherland

A new theory of foam stability is proposed which demonstrates that the transport of substrate. accompanying a movement of the surface of the bubble film, is a dominant factor in the stability of foams and in the action of foam breakers. The surface moves from a region of low surface tension (high surface pressure) to a region of high surface tension. The surface tension gradients arise from disturbances which may be caused by mechanical or thermal shocks, or by the addition to the surface of particles, droplets, or vapour of a surface-active material. When the surface tension is highest at the centre of disturbance the film mill be stable ; when the surface tension is lowest at this point the surface film and hence the substrate will be moved away from this point and the film will rupture.

1975 ◽  
Vol 38 (3) ◽  
pp. 461-466 ◽  
Author(s):  
I. Wyszogrodski ◽  
K. Kyei-Aboagye ◽  
H. W. Taeusch ◽  
M. E. Avery

Hyperventilation, defined as repeated hyperinflations, for three hours in open-chested anesthetized cats increased elastic recoil and elevated minimum surface tension of lung extracts as measured on a surface film balance. Equivalent hyperventilation from an elevated lung volume did not alter the pressure-volume relationships. When a mixture of [3H]glycerol and [14C]palmitate had been injected 17 h before the three hour period of phyerventilation, an increase in the ratio of specific activity in wash to tissue lecithin occurred in the hyperventilated cats compared to controls. These findings suggest that hyperventilation promotes release of surface active material from tissue to alveolus, but the released material is inactivated. The application of 2.5 cmH2O positive end-expiratory pressure prevented the adverse effects of hyperventilation. The same increase in wash to tissue lecithin occurred during this study; since the material was appropriately surface active, we conclude that the positive end-expiratory pressure prevented its inactivation.


1979 ◽  
Vol 47 (3) ◽  
pp. 604-611 ◽  
Author(s):  
J. N. Hildebran ◽  
J. Goerke ◽  
J. A. Clements

Stability of pulmonary alveoli at end expiration requires a very low air-water surface tension (e.g., less than 10 mN.m-1). Another important requirement is that the surface film maintain this low surface tension for a sufficiently long time at fixed lung volume. We measured monolayer collapse rates at 37 degrees C of lung surface-active material (SAM) and certain lipids found in this material and compared them with alveolar monolayer collapse rates calculated from published lung compliance changes. We found collapse rates for purified SAM or a mixture of dipalmitoyl lecithin (DPPC):monoenoic lecithin (PC):cholesterol (CHOL) (3.03:1.65:1 molar ratios) to be much greater than collapse rates of alveolar films estimated from indirect measurements. Monolayers of pure DPPC or DPPC with 10 mol% monoenoic PC and/or CHOL had collapse rates equal to or less than those estimated from lungs. We conclude that the alveolar monolayer is enriched in DPPC to the extent of 90 mol% or greater. Enrichment may exclude more mobile components from the monolayer during expiration when surface tension reaches verry low values.


1961 ◽  
Vol 16 (3) ◽  
pp. 444-450 ◽  
Author(s):  
John A. Clements ◽  
Robert F. Hustead ◽  
Rudolph P. Johnson ◽  
Irwin Gribetz

Human and rat lungs were degassed and filled with air and physiological salt solution for determination of pressure-volume relationships. Extracts were prepared from the specimens and examined for their surface film-forming activity. Both the aeration of the alveolar structure of the lungs at functional residual pressure and the surface activity of the extracts showed wide variation. Numerical ratios were defined to express these two properties quantitatively, and a high degree of correlation was observed between them. The range of correlation was extended by treating the rat lungs with nonionic detergents. These findings support the hypothesis that the stability of the pulmonary alveolar structure is dependent on intrinsic surface-active material and have encouraged further attempts at formulating a theory of alveolar mechanics, taking surface forces into account. The theory is presented, and some of its weaknesses are pointed out. Submitted on October 21, 1960


1946 ◽  
Vol 14 (3) ◽  
pp. 316-329 ◽  
Author(s):  
R. Aschaffenburg

As moderate dilution causes little change in the surface tension of milk, it is shown to be advantageous to use σ-dilution curves in place of the σ-values of the undiluted fluid as a characteristic of the surface properties of milk. The complications arising from the presence of the milk fat are described, and it is suggested that the influence of the fat is of a physical rather than of a chemical nature. A study of the role of the various milk proteins shows the casein to be of great importance, whilst the heat-coagulable proteins have little influence. The serum obtained after removal of the casein and heat-coagulable proteins contains a residual fraction of protein-like material which is markedly surface active though constituting only about 3% of the total milk proteins. The surface-active material (σ-proteose) has been concentrated and isolated, and its properties are described in some detail.


2015 ◽  
Vol 774 ◽  
Author(s):  
P. C. Petit ◽  
M. Le Merrer ◽  
A.-L. Biance

The classical problem of foam film rupture dynamics has been investigated when the film interfaces exhibit very high rigidity due to the presence of specific surfactants. Two new features are reported. First, a strong deviation from the well-known Taylor–Culick law is observed. Second, crack-like patterns can be visualized in the film; these patterns are shown to appear at a well-defined film shrinkage. The key role of surface-active material on these features is quantitatively investigated, pointing to the importance of surface elasticity to describe these fast dynamical processes and thus providing an alternative tool to characterize surface elasticity in conditions extremely far from equilibrium. The origin of the cracks and their consequences on film rupturing dynamics are also discussed.


1972 ◽  
Vol 54 (1) ◽  
pp. 129-141 ◽  
Author(s):  
Jan Berghmans

The present work is an analytical study of the stability of interfaces between fluids in motion, special attention being given to the role of surface tension without consideration of viscous effects. A variational approach based upon the principle of minimum free energy, which was first formulated for stagnant fluids, is applied to fluids in motion. This generalization is possible if viscous and inertia effects are unimportant as far as stability is concerned. One stability problem is studied in detail: a gas jet impinging on a free liquid. The analytical results obtained by this variational technique lie within the range of accuracy (15%) of the experimental results for this gas-jet problem. The method is very general and therefore can be applied to quite a number of interface stability problems.


1985 ◽  
Vol 25 (02) ◽  
pp. 176-190 ◽  
Author(s):  
G.J. Hirasaki ◽  
J.B. Lawson

Abstract The apparent viscosity of foam flowing through smooth capillaries was measured experimentally, and a mathematical model was developed. Foam texture (a measure of bubble volume) is a key parameter in determining the following properties of foam flowing through a capillary:whether the foam exists as bulk foam or as a chain of bubbles where each pair of bubbles is separated by an individual lamella,the number of lamellae per unit length of the capillary, andthe radius of curvature of the gas-liquid interface. The apparent viscosity is the sum of three contributions:that from slugs of liquid between bubbles,the resistance to deformation of the interface of a bubble passing through a capillary, andthe surface tension gradient that results when surface active material is swept from the front of a bubble and accumulates at the back of it. The sensitivity of both measured and calculated apparent viscosity is presented as a function of bubble size, capillary radius, ratio of bubble radius to capillary radius, velocity, quality, and surface tension gradient. Introduction An early conceptual model for the relative permeability of two-phase flow was the bundle of capillary tubes model. In this model, the wetting phase flowed in the smaller capillaries and the nonwetting phase flowed in the larger capillaries. The relationship between the flow rate and pressure drop in a capillary was described by the pressure drop in a capillary was described by the Hagen-Poiseuille law. The flow of a discontinuous nonwetting phase, such as a foam, cannot be described by the Hagen-Poiseuille law. The purpose of this investigation was to determine the relationship between flow rate and pressure drop for the flow of foam through a capillary. This relationship is described by an apparent viscosity that is required to modify the Hagen-Poiseuille law for the flow of foam. Our previous observations of flow of foam lamellae in transparent porous models showed that lamellae move from pore to pore by translation. Breaking and re-forming of lamellae were rare; so was bubble coalescence. These observations suggest that the apparent viscosity of foam or lamellae in uniform, smooth capillaries is related to and, indeed, is one component of the mobility of foam in porous media. A reasonable conceptual model of a natural porous medium is a bundle of interconnected capillaries of different sizes and containing constrictions. All capillary sections, or pores, near to one another have the same capillary pressure. Thus, phase saturations may differ from pore to pore, but the radii of curvature of the gas/ liquid interfaces are equal. When flow in such an array of capillaries is modeled, resistance to flow in parallel channels of both the same and different sizes is conceived to be in parallel. Flow in smooth, uniform pore sections is in series with flow through constrictions. The component of resistance owing to smooth, uniform pore sections is approximated by resistance to flow in smooth, uniform capillaries. Measurements and theory presented here show that the most important variable affecting foam viscosity in uniform, smooth capillaries is foam texture (bubble size). Foam of finer texture has more lamellae per unit length and, as a result, greater resistance to flow. This is true both for flow of bulk foam and series of lamellae. The principal factors affecting apparent viscosity of foam in uniform capillaries are dynamic changes at gas/liquid interfaces. These are illustrated in Fig. 1.Slugs of liquid between gas bubbles resist flow.Viscous and capillary forces result in interfaces that are deformed against the restoring force of surface tension. The extent of this deformation and the resulting bubble shape partially determine apparent viscosity as a function of flow rate.Another factor determining apparent viscosity as a function of velocity is expansion of the interface at the leading end of a bubble, accompanied by compression at the trailing end. This sweeping action causes surface active material to be depleted at the front and to accumulate at the back of the bubble. The result is a surface tension gradient that resists flow. Scaling of Foam Texture and Capillary Radius Since foam texture is a measure of the average volume or equivalent radius of its bubbles, one would expect that an important scale factor is the ratio of this equivalent radius to the equivalent radius of a porous medium or the radius of a capillary. This ratio can be expressed either as the wetted perimeter per unit area of the solid or as the number of lamellae per unit length of capillary. These quantities are denoted as nL and are referred to as the number of equivalent lamellae per unit length. This concept is illustrated in Fig. 2. SPEJ P. 176


1964 ◽  
Vol 19 (4) ◽  
pp. 769-777 ◽  
Author(s):  
John W. C. Johnson ◽  
S. Permutt ◽  
John H. Sipple ◽  
El Sayed Salem

In 17 anesthetized dogs, 50–150 ml of isotonic saline or human amniotic fluid were instilled into a degassed lobe and after 2–6 hr of spontaneous or artificial ventilation, the lungs were excised. Static pressure-volume and extract surface tension values were then determined on a fluid- and a nonfluid-instilled lobe from each animal. When compared with nonfluid-instilled lobes the fluid-instilled lobes were found to have proportionately smaller volumes at maximum inflation ( P < .02) and during deflation ( P < .001) as well as regional areas with higher surface tension properties ( P < .001). It is proposed that the pressure-volume studies may furnish a useful means of assessing the anatomical extent of alterations in lung surface tension. There was a significant negative correlation between maximum inflation volumes and maximum surface tensions ( P < .001) as well as between the volumes during deflation and the minimum surface tensions ( P < .001). It is concluded that intra-alveolar fluid may inactivate or displace the surface-active material from the alveolar lining membrane. amniotic fluid; lung pressure-volume studies; lung surfactant Submitted on April 11, 1963


2012 ◽  
Vol 174-177 ◽  
pp. 1433-1436 ◽  
Author(s):  
Zong Cheng Miao ◽  
Fang Wang ◽  
Deng Deng ◽  
Yong Ming Zhang ◽  
Xiao Ping Huo ◽  
...  

In order to obtain some novel cationic surfactants with high surface activity, n-octadecyldimethylamine and epichlorohydrin were used to synthesize 2-hydroxy-1, 3-dis (chloride octadecyl dimethyl ammonium) propane, which was a kind of gemini quaternary ammonium salt. N-octadecyldimethylamine and epichlorohydrin were used to prepare active epoxy intermediate glycidyloctadecyldimethyl ammonium chlorided, and then glycidyloctadecyldimethyl ammonium chlorided was reacted with octadecyldimethyl amine hydrochloride to synthesize the gemini cationic surfactant. FTIR and 1H NMR were used to represent structure of the gemini cationic surfactant. The interface characteristics were studied in detail. The critical micellar concentration (CMC) was determined by surface tension test to obtain the values of CMC and surface tension at CMC. The foam ability and foam stability of the gemini cationic surfactant were also discussed through contrast octadecyltrimethyl ammonium chloride and cetyltrimethyl ammonium chloride.


1989 ◽  
Vol 56 (3) ◽  
pp. 495-502 ◽  
Author(s):  
Denis Lorient ◽  
Brigitte Closs ◽  
Jean Luc Courthaudon

SummaryIn order to optimize the use of caseins as surfactants, the surface tension, foaming capacity and stability were measured as a function of pH, ionic strength, protein concentration and polarity (modified by covalent binding of carbohydrates). We found that the caseins differ in their behaviour at the air/water interface with β-casein showing the greatest ability to decrease surface tension and to produce foams, due probably to its amphipathic structure. In experiments carried out at pH values close to pI, with low ionic strength and constant solubility (optimal conditions for foam formation), we observed a high surface hydrophobicity, a good accessibility and flexibility of peptidic side chains (evaluated by proteolysis), and a high foaming capacity parallelled by increased surface pressure. Foam stability of caseins was low compared to those of globular proteins such as β lactoglobulin.


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