Measurement of the temperature variation of virial coefficients. III. The second virial coefficient of Carbon Disulphide, Methyl Chloride, Acetone, and Methanol, and certain of their binary mixtures
Keyword(s):
Second virial coefficients have been determined for carbon disulphide, methyl chloride, acetone, and methanol over the temperature range of 50-150� with some additional results at lower temperatures. Similar work has been conducted on the selected mixtures methyl chloride-carbon disulphide, methyl chloride-acetone, acetone-carbon disulphide, and methyl chloride-argon. Methanol, exceptionally, shows very significant third virial contributions in the sub-atmospheric pressure range. A comparison is made with recent models pertaining to molecular interactions between unlike molecules possessing dipolar and quadrupolar contributions to the intermolecular forces.
1959 ◽
Vol 249
(1258)
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pp. 414-426
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2001 ◽
Vol 66
(6)
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pp. 833-854
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1952 ◽
Vol 210
(1103)
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pp. 557-564
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1954 ◽
Vol 221
(1147)
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pp. 508-516
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1987 ◽
Vol 42
(5)
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pp. 447-450
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1942 ◽
Vol 10
(7)
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pp. 476-477
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