Nonisothermal Crystallization Behaviors of Poly(butylene terephthalate) Nucleated with Elastomer-Modified Nano-SiO2, a Commercial Nucleating Agent (P250), and Talc

2010 ◽  
Vol 49 (3) ◽  
pp. 514-527 ◽  
Author(s):  
Ling Zhang ◽  
Yuerong Hong ◽  
Tianshui Zhang ◽  
Chunzhong Li
2013 ◽  
Vol 652-654 ◽  
pp. 501-507
Author(s):  
Nai Xu ◽  
Li Sha Pan ◽  
Su Juan Pang ◽  
Qiang Lin

The nonisothermal crystallization kinetics of isotactic polypropylene (iPP) filled with a novel nucleating agent (TMC328) was studied by using differential scanning calorimetric. The commonly used Arami, Ozawa, and Mo models were used to model the crystallization kinetics, and it appears that Arami and Mo models can well describe the nonisothermal crystallization behaviors of iPP/TMC328 blends. The results indicate that a small amount of TMC328 can obviously enhance the kinetic crystallizability of iPP due to its heterogeneous nucleation effect.


2014 ◽  
Vol 1015 ◽  
pp. 381-384
Author(s):  
Li Liu ◽  
Li Hai Cai ◽  
Dan Liu ◽  
Jun Xu ◽  
Bao Hua Guo

The poly (butylene succinate) (PBS) and 3 wt% attapulgite (ATP) reinforced PBS/ATP nanocomposites with 1,6-hexanediol were fabricated using an in situ polymerization method. The crystallization behaviors indicated that ATP had effectively acted as nucleating agent, resulting in the enhancement on the crystallization temperature. The SEM results showed a superior interfacial linkage between ATP and PBS. Also, ATP could disperse as a single fiber and embed in the polymer matrix, which resulted in the improved mechanical properties.


2013 ◽  
Vol 013 (8) ◽  
pp. 949-955
Author(s):  
Lan Xiao-rong ◽  
Wu Feng ◽  
Ji De-yun ◽  
Feng Jian-min ◽  
Liu Zheng-ying ◽  
...  

2009 ◽  
Vol 48 (5) ◽  
pp. 927-940 ◽  
Author(s):  
De-Yi Wang ◽  
Lian-Lian Wei ◽  
Xin-Guo Ge ◽  
Ke-Ke Yang ◽  
Xiu-Li Wang ◽  
...  

2017 ◽  
Vol 52 (4) ◽  
pp. 503-517 ◽  
Author(s):  
Zheng-Ian Lin ◽  
Ching-Wen Lou ◽  
Yi-Jun Pan ◽  
Chien-Teng Hsieh ◽  
Chien-Lin Huang ◽  
...  

This study adopts the melt compounding method to prepare /mutli-walled carbon nanotubes composites. The effects of different lengths of the mutli-walled carbon nanotubes on the isothermal crystallization behaviors, crystalline structure, and thermal stability of the polypropylene/mutli-walled carbon nanotubes composites are examined. The PLM results show that the combination of mutli-walled carbon nanotubes prevents the growth of polypropylene spherulites, and thus results in a small size of spherulites. The differential scanning calorimetry results show that the short (S-) or long (L-) mutli-walled carbon nanotubes can function as the nucleating agent of polypropylene, which accelerates the crystallization rate of polypropylene. Avrami theory analyses indicate that the addition of short-mutli-walled carbon nanotubes particularly provides polypropylene/mutli-walled carbon nanotubes composites with a high crystallization rate. The X-ray diffraction results show that the combination of mutli-walled carbon nanotubes does not pertain to the crystal structure. The TGA test results show that long-mutli-walled carbon nanotubes outperform short -mutli-walled carbon nanotubes in improving the thermal stability of polypropylene, and both can significantly improve it.


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