Study of the d-f Emission, and f-d Ground-State and Excited-State Absorption of Nd3+in Crystals Using the Simple Model

2010 ◽  
Vol 43 (5) ◽  
pp. 423-430 ◽  
Author(s):  
Chang-Kui Duan ◽  
Sha Jiang
1990 ◽  
Vol 26 (5) ◽  
pp. 320 ◽  
Author(s):  
M. Monerie ◽  
T. Georges ◽  
P.L. Francois ◽  
J.Y. Allain ◽  
D. Neveux

1991 ◽  
Vol 244 ◽  
Author(s):  
Jau-Sheng Wang ◽  
Elias Snitzer ◽  
George H. Sigel

ABSTRACTThe results to be presented focus on the optimization of tellurite glass compositions which are suitable both for doping with erbium oxide as well as subsequent for fiber drawing. The laser related properties, such as fluorescence spectrum, lifetime, and optical transition cross sections will be presented. Judd-Ofelt parameters for erbium in the glasses have been exploited to predict fluorescence lifetime, excited state absorption(ESA), ground state absorption(GSA) and ground state fluorescence(GSF). For comparison, the absorption cross section, emission cross section, excited state absorption(ESA)/ground state absorption(GSA)(0.8μm pumping) and fluorescence terminating in the ground state(GSF)/excited state absorption(ESA) ratios are calculated for both Al2O3-SiO2 and tellurite glasses.


1989 ◽  
Vol 172 ◽  
Author(s):  
S. Zemon ◽  
G. Lambert ◽  
W. J. Miniscalco ◽  
L. J. Andrews ◽  
B. T. Hall

AbstractPump-excited-state-absorption (ESA) measurements on Er3+-doped phosphates, fluorophosphates, and silicate bulk glasses indicate that ESA cross sections are approximately equal to ground state absorption (GSA) cross sections in the 800-nm band. The oscillator strengths of the ESA and GSA bands are also approximately equal, in qualitative agreement with Judd-Ofelt calculations. Fluorozirconate samples were found to have substantial populations in the upper excited states for the measurement conditions used and ESA transitions originating from four excited states were identified. Fluorozirconate fiber amplifiers and lasers at 1.55 μm, therefore, would have decreased efficiency for 800-nm pumping.


Author(s):  
Wu Wang ◽  
Hanxu Zhang ◽  
Xu Wang

Abstract We show how two apparently unrelated research areas, namely, strong-field atomic physics and $^{229}$Th nuclear physics, are connected. The connection is possible due to the existence of a very low-lying excited state of the $^{229}$Th nucleus, which is only about 8 eV above the nuclear ground state. The connection is physically achieved through an electron recollision process, which is the core process of strong-field atomic physics. The laser-driven recolliding electron is able to excite the nucleus, and a simple model is presented to explain this recollision-induced nuclear excitation (RINE) process. The connection of these two research areas provides novel opportunities for each area and intriguing possibilities from the direct three-partite interplay between atomic physics, nuclear physics, and laser physics.


1977 ◽  
Vol 55 (3) ◽  
pp. 243-251
Author(s):  
Tuan-Kay Lim ◽  
Jerald R. Izatt ◽  
George F. Caudle

The saturation behavior of molecular absorbers characterized by absorption coefficients expressible as the ratio of two polynomials in the intensity is analyzed. Two cases are considered in detail. In the first, the absorption coefficient is the ratio of a linear equation in I to a quadratic equation in I. In the second, the highest order of the intensity occurring in both numerator and denominator is increased by two. The absorption coefficients are derived from two specific five-level models which are pertinent to the interpretation of the absorption of CO2 laser radiation at 937 cm−1 by SF6, but the analysis of the saturation curves is independent of the models from which they are derived. The saturation curves display as many as three extrema and provide considerable flexibility for fitting complicated experimental data. Both five-level models include excited-state absorption with the terminal level of the ground-state absorption distinct from the initial level of the excited-state absorption. Each of the five levels can be considered as a composite of many rotational states which interact in a like manner with the incident radiation. In one of the models the ratio of the excited-state and ground-state absorption cross sections is taken to be intensity dependent.


2008 ◽  
Vol 8 (12) ◽  
pp. 6564-6568 ◽  
Author(s):  
Márcio A. R. C. Alencar ◽  
Glauco S. Maciel ◽  
Cid B. de Araújo ◽  
Amitava Patra

We investigated the frequency upconversion (UC) process in BaTiO3:Er3+ nanocrystals for excitation wavelengths in the range 638 to 660 nm. Green upconversion emissions at 526 and 547 nm corresponding to 2H11/2 → 4I15/2 and 4S3/2 → 4I15/2 to transitions of the Er3+ were observed. The excitation spectrum for UC emissions presented three bands, due to ground state and excited state absorption of Er3+ ions. The UC intensity as a function of the laser power was investigated and it was found this a two-photon absorption process.


Chemija ◽  
2021 ◽  
Vol 32 (2) ◽  
Author(s):  
Andrius Laurikėnas ◽  
Aivaras Kareiva

In this study, Y1-xLn3+x(BTC)(DMF)2(H2O) and Y0.8-xYb0.2Ln3+x(BTC)(DMF)2(H2O) metal organic frameworks (MOFs), which structure included lanthanide ions, Ln3+ (Er3+, Ho3+, Tm3+, Yb3+, Nd3+), suitable for monitoring the upconversion phenomenon, have been synthesised. For this purpose the precursor of the organic moiety, benzene-1,3,5-tricarboxylic acid (BTC), as one of the simplest and very frequently cited carboxylic acid analogues in MOF syntheses, has been selected. By characterising upconversion properties of new MOFs it was determined that only Er3+ can be used as an activator for one centre luminescence upconversion by a ground state absorption/ excited-state absorption (GSA/ESA) mechanism, while with Yb3+, Ho3+, Tm3+ and Nd3+ ions the upconversion was not observed. It was also established that BTC cannot initiate triplet–triplet annihilation upconversion (TTA-UC) as this mechanism sensitizer. Yb3+–Er3+ and Yb3+–Ho3+ ion pairs as a sensitizeractivator were suitable for two-centre luminescence upconversion by a GSA/ excited-state upconversion (GSA/ESU) mechanism. A pair of Yb3+–Tm3+, contrary as shown in the literature review, does not exhibit upconversion properties in the synthesised MOFs.


Sign in / Sign up

Export Citation Format

Share Document