ESTIMATION OF LIMITING EQUIVALENT CONDUCTIVITY AND IONIC RADIUS OF TETRABORATE ANION FROM CONDUCTIVITY MEASUREMENTS OF CONCENTRATED TETRABORATE SOLUTIONS

2007 ◽  
Vol 194 (7) ◽  
pp. 893-900 ◽  
Author(s):  
Sevda Ayata
Author(s):  
I. A. Rauf

To understand the electronic conduction mechanism in Sn-doped indium oxide thin films, it is important to study the effect of dopant atoms on the neighbouring indium oxide lattice. Ideally Sn is a substitutional dopant at random indium sites. The difference in valence (Sn4+ replaces In3+) requires that an extra electron is donated to the lattice and thus contributes to the free carrier density. But since Sn is an adjacent member of the same row in the periodic table, the difference in the ionic radius (In3+: 0.218 nm; Sn4+: 0.205 nm) will introduce a strain in the indium oxide lattice. Free carrier electron waves will no longer see a perfect periodic lattice and will be scattered, resulting in the reduction of free carrier mobility, which will lower the electrical conductivity (an undesirable effect in most applications).One of the main objectives of the present investigation is to understand the effects of the strain (produced by difference in the ionic radius) on the microstructure of the indium oxide lattice when the doping level is increased to give high carrier densities. Sn-doped indium oxide thin films were prepared with four different concentrations: 9, 10, 11 and 12 mol. % of SnO2 in the starting material. All the samples were prepared at an oxygen partial pressure of 0.067 Pa and a substrate temperature of 250°C using an Edwards 306 coating unit with an electron gun attachment for heating the crucible. These deposition conditions have been found to give optimum electrical properties in Sn-doped indium oxide films. A JEOL 2000EX transmission electron microscope was used to investigate the specimen microstructure.


1991 ◽  
Vol 18 (3) ◽  
pp. 611-627 ◽  
Author(s):  
Marta L. Fiorotto ◽  
William J. Klish

1979 ◽  
Vol 40 (C7) ◽  
pp. C7-303-C7-304
Author(s):  
M. Skowronek ◽  
L. Giry ◽  
Vu Tien Gia ◽  
P. Romeas

2019 ◽  
Vol 15 (34) ◽  
pp. 1-14
Author(s):  
Bushra A. Hasan

Lead selenide PbSe thin films of different thicknesses (300, 500, and 700 nm) were deposited under vacuum using thermal evaporation method on glass substrates. X-ray diffraction measurements showed that increasing of thickness lead to well crystallize the prepared samples, such that the crystallite size increases while the dislocation density decreases with thickness increasing. A.C conductivity, dielectric constants, and loss tangent are studied as function to thickness, frequency (10kHz-10MHz) and temperatures (293K-493K). The conductivity measurements confirm confirmed that hopping is the mechanism responsible for the conduction process. Increasing of thickness decreases the thermal activation energy estimated from Arhinus equation is found to decrease with thickness increasing. The increase of thickness lead to reduce the polarizability α while the increasing of temperature lead to increase α.


2018 ◽  
Author(s):  
Daniel Nelson
Keyword(s):  

2017 ◽  
Vol 68 (11) ◽  
pp. 2482-2487
Author(s):  
George Lazar ◽  
Claudiu Campureanu ◽  
Ioan Cirneanu ◽  
Danut Ionel Vaireanu

This paper intends to present the theoretical background as well as practical illustrations for good laboratory practices in conductivity measurements, ways to increase the accuracy of conductivity measurements as well as how one may evaluate the uncertainty of conductivity measurements for the electrolyte solutions. Practical measurements for prepared standards of 1 M KCl and 0.1 M KCl solutions are carried out and the values of repeatability, composed uncertainty and expanded uncertainty are presented.


1999 ◽  
Vol 30 (4-5) ◽  
pp. 333-360 ◽  
Author(s):  
Larry McKay ◽  
Johnny Fredericia ◽  
Melissa Lenczewski ◽  
Jørn Morthorst ◽  
Knud Erik S. Klint

A field experiment shows that rapid downward migration of solutes and microorganisms can occur in a fractured till. A solute tracer, chloride, and a bacteriophage tracer, PRD-1, were added to groundwater and allowed to infiltrate downwards over a 4 × 4 m area. Chloride was detected in horizontal filters at 2.0 m depth within 3-40 days of the start of the tracer test, and PRD-1 was detected in the same filters within 0.27 - 27 days. At 2.8 m depth chloride appeared in all the filters, but PRD-1 appeared in only about one-third of the filters. At 4.0 m depth chloride appeared in about one-third of the filters and trace amounts of PRD-1 were detected in only 2 of the 36 filters. Transport rates and peak tracer concentrations decreased with depth, but at each depth there was a high degree of variability. The transport data is generally consistent with expectations based on hydraulic conductivity measurements and on the observed density of fractures and biopores, both of which decrease with depth. Transport of chloride was apparently retarded by diffusion into the fine-grained matrix between fractures, but the rapid transport of PRD-1, with little dispersion, indicates that it was transported mainly through the fractures.


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