The effect of the alkyl chain length on the mesomorphic properties of new lactic acid derivatives

2014 ◽  
Vol 41 (8) ◽  
pp. 1179-1187 ◽  
Author(s):  
Miroslav Kašpar ◽  
Věra Hamplová ◽  
Vladimíra Novotná ◽  
Oliva Pacherová
Keyword(s):  
Lactic Acid ◽  
Chain Length ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Mesomorphic Properties

scholarly journals Effect of alkyl chain length in the terminal ester group on mesomorphic properties of new chiral lactic acid derivatives

2016 ◽  
Vol 43 (10) ◽  
pp. 1472-1485 ◽  
Author(s):  
Michal Kohout ◽  
Alexej Bubnov ◽  
Jiří Šturala ◽  
Vladimíra Novotná ◽  
Jiří Svoboda
Keyword(s):  
Lactic Acid ◽  
Chain Length ◽  
Alkyl Chain ◽  
Ester Group ◽  
Alkyl Chain Length ◽  
Mesomorphic Properties

The Effect of Terminal Alkyl Chain Length on Mesomorphic Properties of 4-Alkoxyphenyl-4'-Alkylbenzoates

1980 ◽  
Vol 59 (3-4) ◽  
pp. 253-272 ◽  
Author(s):  
Mary E. Neubert ◽  
L. T. Carlino ◽  
D. L. Fishel ◽  
R. M. D'sidocky
Keyword(s):  
Chain Length ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Mesomorphic Properties

scholarly journals Silver Nanoparticles Stabilized with Phosphorus-Containing Heterocyclic Surfactants: Synthesis, Physico-Chemical Properties, and Biological Activity Determination

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1883
Author(s):  
Martin Pisárčik ◽  
Miloš Lukáč ◽  
Josef Jampílek ◽  
František Bilka ◽  
Andrea Bilková ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Biological Activity ◽  
Zeta Potential ◽  
Chain Length ◽  
Alkyl Chain ◽  
Chemical Properties ◽  
Alkyl Chain Length ◽  
Microbial Pathogens ◽  
Physico Chemical ◽  
Phosphorus Containing

Phosphorus-containing heterocyclic cationic surfactants alkyldimethylphenylphospholium bromides with the alkyl chain length 14 to 18 carbon atoms were used for the stabilization of silver nanodispersions. Zeta potential of silver nanodispersions ranges from +35 to +70 mV, which indicates the formation of stable silver nanoparticles (AgNPs). Long-chain heptadecyl and octadecyl homologs of the surfactants series provided the most intensive stabilizing effect to AgNPs, resulting in high positive zeta potential values and smaller diameter of AgNPs in the range 50–60 nm. A comparison with non-heterocyclic alkyltrimethylphosphonium surfactants of the same alkyl chain length showed better stability and more positive zeta potential values for silver nanodispersions stabilized with heterocyclic phospholium surfactants. Investigations of biological activity of phospholium-capped AgNPs are represented by the studies of antimicrobial activity and cytotoxicity. While cytotoxicity results revealed an increased level of HepG2 cell growth inhibition as compared with the cytotoxicity level of silver-free surfactant solutions, no enhanced antimicrobial action of phospholium-capped AgNPs against microbial pathogens was observed. The comparison of cytotoxicity of AgNPs stabilized with various non-heterocyclic ammonium and phosphonium surfactants shows that AgNPs capped with heterocyclic alkyldimethylphenylphospholium and non-heterocyclic triphenyl-substituted phosphonium surfactants have the highest cytotoxicity among silver nanodispersions stabilized by the series of ammonium and phosphonium surfactants.

Sign in / Sign up

Export Citation Format

Share Document