scholarly journals Testing ultra-high-temperature ceramics for thermal protection and rocket applications

2018 ◽  
Vol 117 (sup1) ◽  
pp. s9-s18 ◽  
Author(s):  
R. Savino ◽  
S. Mungiguerra ◽  
G. D. Di Martino
2010 ◽  
Vol 3 (1) ◽  
pp. 9-9
Author(s):  
Raffaele Savino

Improved interest in ultra-high-temperature ceramics (UHTCs) is being animating the scientific community. This emerging attention is driven by the demand of developing re-usable hot structures as thermal protection systems of aerospace vehicles, able to re-enter in planetary atmospheres at relatively high speed (order of 8-11 Km/s). In contrast to traditional blunt capsules or Shuttle-like vehicles, characterised by poor gliding capabilities and complex thermal protection systems, the future use of UHTCs opens new horizons for the development of spaceplanes with slender fuselage noses and sharp wing leading edges. Advanced aerodynamic configurations reduce the vehicles drag, enhance the vehicles performances, due to a larger manoeuvrability resulting in larger down range, cross range and abort windows, and reduce electromagnetic interferences and communications black-out. Analysis has shown that materials with temperature capability approaching 2000°C and above will be required for these space vehicles, but the state of the art Reinforced Carbon-Carbon (RCC) material, currently used on the Space Shuttle, have maximum use temperatures of approximately 1650°C. The articles collected in this issue provide state-of-art scientific advancements on the subject with particular attention to the potential technological applications. The papers specifically deal with research studies on monolithic ceramic materials, composed primarily of Zirconium and Hafnium Diborides with different additives. The activities are carried out at materials level, with furnace or arc-jet testing, or include developments of UHTC-based hot structures at sub-component level. In the latter case, ultra-high temperature ceramic prototype structures have been developed and tested with embedded structural health monitoring systems. I want to thank all the article contributors for their manuscripts. I hope they will be useful for future basic and applied researches on the subject.


Author(s):  
J.K. Sonber ◽  
T.S.R. Ch. Murthy ◽  
C. Subramanian ◽  
R.C. Hubli ◽  
A.K. Suri

Ultra-high-temperature ceramics (UHTCs) are a group of materials that can withstand ultra high temperatures (1600-3000 oC) which will be encountered by future hypersonic re-entry vehicles. Future re-entry vehicles will have sharp edges to improve flight performance. The sharp leading edges result in higher surface temperature than that of the actual blunt edged vehicles that could not be withstood by the conventional thermal protection system materials. To withstand the intense heat generated when these vehicles dip in and out of the upper atmosphere, UHTC materials are needed. UHTC materials are composed of borides of early transition metals. From the larger list of borides, ZrB2 and HfB2 have received the most attention as potential candidates for leading edge materials because their oxidation resistance is superior to that of other borides due to the stability of the ZrO2 and HfO2 scales that form on these materials at elevated temperatures in oxidizing environments. Processing of these materials is very difficult as these materials are very refractory in nature. In this chapter, processes available for powder synthesis, fabrication of dense bodies, and coating processes is discussed.


Author(s):  
Lun Feng ◽  
William G. Fahrenholtz ◽  
Donald W. Brenner

Herein, we critically evaluate computational and experimental studies in the emerging field of high-entropy ultra-high-temperature ceramics. High-entropy ultra-high-temperature ceramics are candidates for use in extreme environments that include temperatures over 2,000°C, heat fluxes of hundreds of watts per square centimeter, or irradiation from neutrons with energies of several megaelectron volts. Computational studies have been used to predict the ability to synthesize stable high-entropy materials as well as the resulting properties but face challenges such asthe number and complexity of unique bonding environments that are possible for these compositionally complex compounds. Experimental studies have synthesized and densified a large number of different high-entropy borides and carbides, but no systematic studies of composition-structure-property relationships have been completed. Overall, this emerging field presents a number of exciting research challenges and numerous opportunities for future studies. Expected final online publication date for the Annual Review of Materials Science, Volume 51 is July 2021. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.


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