Adsorption of molecular size fractions of humic acid onto anion-doped TiO2specimens

2015 ◽  
Vol 57 (6) ◽  
pp. 2455-2465 ◽  
Author(s):  
P. Akan ◽  
N.C. Birben ◽  
M. Bekbolet
2019 ◽  
Vol 38 (6) ◽  
pp. 863-871 ◽  
Author(s):  
Mohamed E. A. El-Sayed ◽  
Moustafa M. R. Khalaf ◽  
James A. Rice

2011 ◽  
Vol 11 (6) ◽  
pp. 692-698 ◽  
Author(s):  
S. Valencia ◽  
J. Marín ◽  
G. Restrepo ◽  
F. H. Frimmel

Much research has been undertaken on the photocatalytic degradation of humic substances with titanium dioxide using commercial humic acids (HA), which are extracts from either peat or coal. Most of the research has been focused on the changes in dissolved organic carbon (DOC) and UV254 absorption. These parameters only give a general assessment. This work studies the changes in the physical and structural properties of a commercial humic acid by size exclusion chromatography with DOC and UV254 absorption detection (SEC-DOC, SEC-UV254), and the evolution of halogenated organic compounds (AOX) and trihalomethanes (THMs) during the photocatalytic degradation with simulated solar UV irradiation and Degussa P-25 TiO2. These changes are compared with those reported for natural organic matter (NOM). The photodegradation of commercial HA and NOM proceeds in a similar and sequential manner, initially with the preferential adsorption of larger molecules, then the degradation of these larger molecular size fractions and proceeding towards smaller molecular size fractions, while decreasing THMs and AOX formation potential.


2015 ◽  
Vol 14 (3) ◽  
pp. 576-582 ◽  
Author(s):  
M. Bekbolet ◽  
S. Sen-Kavurmaci

Photocatalytic oxidation leads to a drastic change in excitation emission matrix (EEM) fluorescence features of humic acid molecular size fractions.


Geoderma ◽  
2011 ◽  
Vol 163 (1-2) ◽  
pp. 24-29 ◽  
Author(s):  
Claire Richard ◽  
Christian Coelho ◽  
Ghislain Guyot ◽  
Lubov Shaloiko ◽  
Oleg Trubetskoj ◽  
...  

Chemosphere ◽  
2009 ◽  
Vol 77 (6) ◽  
pp. 829-837 ◽  
Author(s):  
Edoardo Puglisi ◽  
George Fragoulis ◽  
Patrizia Ricciuti ◽  
Fabrizio Cappa ◽  
Riccardo Spaccini ◽  
...  

2018 ◽  
Vol 254 ◽  
pp. 241-247 ◽  
Author(s):  
Zinnat A. Begum ◽  
Ismail M.M. Rahman ◽  
Yousuke Tate ◽  
Toshiharu Ichijo ◽  
Hiroshi Hasegawa

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