Dibenzophospholes: Phase Behavior of Novel Phosphorus-Based Chiral Liquid Crystals

2002 ◽  
Vol 381 (1) ◽  
pp. 43-57 ◽  
Author(s):  
Ernesto Durán ◽  
Dolores Velasco ◽  
Francisco López-Calahorra ◽  
Heino Finkelmann
2018 ◽  
Vol 19 (9) ◽  
pp. 2715 ◽  
Author(s):  
Takuma Nozawa ◽  
Paul Brumby ◽  
Kenji Yasuoka

Monte Carlo simulations of chiral liquid-crystals, represented by a simple coarse-grained chiral Gay–Berne model, were performed to investigate the effect of central longitudinal dipole interactions on phase behavior. A systematic analysis of the structural properties and phase behavior of both achiral and chiral systems, with dipole interactions, reveals differing effects; strong dipole interactions enhance the formation of layered structures; however, chiral interactions may prevent the formation of such phases under certain conditions. We also observed a short-ranged smectic structure within the cholesteric phases with strong dipole interactions. This constitutes possible evidence of presmectic ordering and/or the existence of chiral line liquid phases, which have previously been observed in X-ray experiments to occur between the smectic twisted grain boundary and cholesteric phases. These results provide a systematic understanding of how the phase behavior of chiral liquid-crystals changes when alterations are made to the strength of dipole interactions.


1990 ◽  
Vol 2 (2) ◽  
pp. 147-149 ◽  
Author(s):  
N.K. Shankar ◽  
J.A. Morris ◽  
C.P. Yakymyshyn ◽  
C.R. Pollock

Langmuir ◽  
2017 ◽  
Vol 33 (48) ◽  
pp. 13849-13860 ◽  
Author(s):  
Joydip De ◽  
Santosh Prasad Gupta ◽  
Indu Bala ◽  
Sandeep Kumar ◽  
Santanu Kumar Pal

1992 ◽  
Vol 06 (08) ◽  
pp. 425-446 ◽  
Author(s):  
PETER J. COLLINGS

Theoretical and experimental optical activity and light scattering work in highly chiral liquid crystals is reviewed, starting from the early studies twenty years ago and ending with the most current investigations. Pretransitional effects in the isotropic and smectic A phases of highly chiral liquid crystals are discussed, as well as optical activity and light scattering effects in both the blue phases and smectic A * phase.


1998 ◽  
Vol 58 (1) ◽  
pp. 595-601 ◽  
Author(s):  
G. S. Iannacchione ◽  
C. W. Garland ◽  
J. Mieczkowski ◽  
E. Gorecka

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