Electronic motion: the hydrogen atom

Author(s):  
Ajit J Thakkar
2014 ◽  
Vol 92 (11) ◽  
pp. 1405-1410 ◽  
Author(s):  
N. Kryukov ◽  
E. Oks

In our previous paper (Can. J. Phys. 91, 715 (2013) doi: 10.1139/cjp-2013-0077 ) we studied a system consisting of a proton, a muon, and an electron; the muon and the electron being in circular states. The study was motivated by numerous applications of muonic atoms and molecules, where one of the electrons is substituted by the heavier lepton μ–. We demonstrated that in such a μpe quasi molecule, the muonic motion can represent a rapid subsystem while the electronic motion can represent a slow subsystem — a result that may seem counterintuitive. In other words, the muon rapidly revolves in a circular orbit about the axis connecting the proton and electron while this axis slowly rotates following a relatively slow electronic motion. We showed that the spectral lines, emitted by the muon in the quasi molecule, μpe, experience a red shift compared to the corresponding spectral lines that would have been emitted by the muon in a muonic hydrogen atom. In the present paper we generalize this study by replacing the proton in the μpe quasi molecule by a fully stripped ion of nuclear charge Z > 1. We show that in this case, just as in the previously studied case of Z = 1, the muonic motion can represent a rapid subsystem while the electronic motion can represent a slow subsystem. For this to be valid, the ratio of the muonic and electronic angular momenta should be slightly greater than in the case of Z = 1. We demonstrate that the binding energies of the muon for Z > 1 are much greater than for Z = 1 at any finite value of the nucleus–electron distance. Finally we show that the red shift of the spectral lines emitted by the muon (compared to the spectral lines of the corresponding muonic hydrogen-like ion of nuclear charge Z) decreases as Z increases. However, the relative red shift remains within the spectral resolution of available spectrometers at least up to Z = 5. Observing this red shift should be one of the ways to detect the formation of the quasi molecules, μZe.


1982 ◽  
Vol 138 (10) ◽  
pp. 347 ◽  
Author(s):  
Yurii L. Sokolov ◽  
V.P. Yakovlev
Keyword(s):  

2019 ◽  
Author(s):  
Shiori Date ◽  
Kensei Hamasaki ◽  
Karen Sunagawa ◽  
Hiroki Koyama ◽  
Chikayoshi Sebe ◽  
...  

<div>We report here a catalytic, Markovnikov selective, and scalable synthetic method for the synthesis of saturated sulfur heterocycles, which are found in the structures of pharmaceuticals and natural products, in one step from an alkenyl thioester. Unlike a potentially labile alkenyl thiol, an alkenyl thioester is stable and easy to prepare. The powerful Co catalysis via a cobalt hydride hydrogen atom transfer and radical-polar crossover mechanism enabled simultaneous cyclization and deprotection. The substrate scope was expanded by the extensive optimization of the reaction conditions and tuning of the thioester unit.</div>


2019 ◽  
Author(s):  
Florian Bartels ◽  
Manuela Weber ◽  
Mathias Christmann

<div>An efficient strategy for the synthesis of the potent phospholipase A2 inhibitors spongidine A and D is presented. The tetracyclic core of the natural products was assembled via an intramolecular hydrogen atom transfer‐initiated Minisci reaction. A divergent late‐stage functionalization of the tetracyclic ring system was also used to achieve a concise synthesis of petrosaspongiolide L methyl ester.</div>


2020 ◽  
Author(s):  
Shunya Ohuchi ◽  
Hiroki Koyama ◽  
Hiroki Shigehisa

A catalytic synthesis of cyclic guanidines, which are found in many biologically active compounds and natu-ral products, was developed, wherein transition-metal hydrogen atom transfer and radical-polar crossover were employed. This mild and functional-group tolerant process enabled the cyclization of alkenyl guanidines bearing common protective groups, such as Cbz and Boc. This powerful method not only provided the common 5- and 6-membered rings but also an unusual 7-membered ring. The derivatization of the products afforded various heterocycles. We also investigated the se-lective cyclization of mono-protected or hetero-protected (TFA and Boc) alkenyl guanidines and their further derivatiza-tions.


2019 ◽  
Author(s):  
Melanie Short ◽  
Mina Shehata ◽  
Matthew Sanders ◽  
Jennifer Roizen

Sulfamides guide intermolecular chlorine transfer to gamma-C(sp<sup>3</sup>) centers. This unusual position-selectivity arises because accessed sulfamidyl radical intermediates engage in otherwise rare 1,6-hydrogen-atom transfer processes. The disclosed chlorine-transfer reaction relies on a light-initiated radical chain-propagation mechanism to oxidize C(sp<sup>3</sup>)-H bonds.


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