Quantitative Determination of Benzaldehyde in Flavors by Gas-Liquid Chromatography

1963 ◽  
Vol 46 (6) ◽  
pp. 950-951
Author(s):  
Richard L Brunelle ◽  
Glenn E Martin
Keyword(s):  
Liquid Chromatography ◽  
Liquid Phase ◽  
Benzoic Acid ◽  
Quantitative Determination ◽  
Solid Support ◽  
Specific Method ◽  
Gas Liquid Chromatography ◽  
Ultraviolet Spectrophotometry ◽  
Liquid Chromatography Separation

Abstract A rapid and specific method is given for determination of benzaldehyde in the presence of interfering substances by gas-liquid chromatography. Separation is effected on a ¼ column containing 2 5% Apiezon M as the liquid phase on a solid support of Chromoport XXX (60—80 mesh) at isothermal conditions, 100°C. The determination can be performed in the presence of benzoic acid and other interfering substances. Results are compared with those obtained by ultraviolet spectrophotometry on a variety of almond and cherry flavors.

Fusel Oil Determination by Gas-Liquid Chromatography

1963 ◽  
Vol 46 (2) ◽  
pp. 294-297
Author(s):  
Glenn E Martin ◽  
Gian Caggiano ◽  
Howard Schlesinger
Keyword(s):  
Liquid Chromatography ◽  
Liquid Phase ◽  
Isothermal Condition ◽  
Solid Support ◽  
Gas Liquid Chromatography ◽  
Fusel Oil ◽  
Liquid Chromatography Separation

Abstract A method was developed for the determination of fusel oil by gas-liquid chromatography. Separation is effected in a ¼” column containing 20% Ucon polar as the liquid phase, on a solid support of Gas Chrom P at isothermal condition 90° C. The method is simple and expeditious, and the amount of each component alcohol can be determined individually.

Micro-Determination of p-Hydroxybenzoic Esters in Pharmaceuticals and Cosmetics

1977 ◽  
Vol 60 (1) ◽  
pp. 56-59 ◽  
Author(s):  
Emil Weisenberg ◽  
Baruch Gershon ◽  
Judith Schoenberg
Keyword(s):  
Liquid Chromatography ◽  
Phosphate Ester ◽  
Specific Method ◽  
Gas Liquid Chromatography ◽  
Direct Extraction ◽  
Flame Photometric Detector ◽  
Phenol Derivatives ◽  
Margin Of Error ◽  
Diethyl Phosphate

Abstract A rapid and specific method is described for the determination of microamounts of methyl, propyl, and butyl p-hydroxybenzoic esters (parabens) in pharmaceuticals and cosmetics. The method involves the direct extraction of parabens into benzene or chloroform followed by derivatization with phosphorochloridate. The diethyl phosphate ester derivatives are cleaned up on a Florisil minicolumn and finally measured by gas-liquid chromatography on 5% OV-210 on Gas-Chrom Q. A flame photometric detector or a KCl thermionic detector may be used. The concentration response was linear up to 40 ng parabens. The reproducibility and margin of error were tested with fortified samples. This method may be applied to the estimation of other phenol derivatives.

DETERMINATION OF PLASMA OESTRIOL IN NORMAL PREGNANCY AND LABOUR USING GAS-LIQUID CHROMATOGRAPHY

1971 ◽  
Vol 51 (3) ◽  
pp. 447-454 ◽  
Author(s):  
W. COOPER ◽  
M. G. COYLE ◽  
J. A. MILLS
Keyword(s):  
Gas Chromatography ◽  
Liquid Chromatography ◽  
Quantitative Determination ◽  
Internal Standard ◽  
Normal Pregnancy ◽  
Gas Liquid Chromatography ◽  
Chemical Purification ◽  
Peripheral Plasma ◽  
Pregnancy And Delivery

SUMMARY A method is described for estimating oestriol in 2–10 ml samples of human pregnancy peripheral plasma. It incorporates acid hydrolysis, chemical purification, methylation, chromatography on alumina columns, formation of a derivative and quantitative determination by gas chromatography. A radioactive internal standard was added to correct for procedural losses. Plasma oestriol determinations in five normal patients throughout pregnancy and delivery are reported.

Quantitative Determination of Sorbic Acid in Cheddar Cheese by Gas-Liquid Chromatography

1971 ◽  
Vol 54 (2) ◽  
pp. 361-363
Author(s):  
D E LaCroix ◽  
N P Wong
Keyword(s):  
Liquid Chromatography ◽  
Ethylene Glycol ◽  
Quantitative Determination ◽  
Sorbic Acid ◽  
Cheddar Cheese ◽  
Gas Liquid Chromatography ◽  
Glycol Adipate ◽  
Average Recovery ◽  
Ethylene Glycol Adipate

Abstract A rapid method is described for the extraction and quantitative determination of sorbic acid in Cheddar cheese. Cheddar cheese is impregnated onto a Celite 545 column, extracted with acetonitrile, and analyzed for sorbic acid by gas-liquid chromatography, using a 7.5% ethylene glycol adipate + 2% H3PO4 column. Average recovery values for known amounts of sorbic acid were 107%.

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