scholarly journals VI. The specific heats of metals and the relation of specific heat to atomic weight.—Part III

The law of Neumann assumes that when an atom enters into chemical combination it retains the same capacity for heat as when in the uncombined or elemental state. This generalisation is, however, based on the values observed for the mean specific heats of elements and their compounds between 0° and 100° C. Attention was directed in Part II. of this investigation to the great differences found in the influence of temperature on the specific heats of various metals, such as aluminium on the one hand, and silver or platinum on the other. The experiments now about to be described were undertaken with the object of ascertaining to what extent these differences persist in the compounds of such elements.

1903 ◽  
Vol 71 (467-476) ◽  
pp. 220-221 ◽  

The following values have been obtained for the mean specific heats, of pure aluminium, nickel, cobalt, silver, and platinum, within the several limits of temperature indicated: From these results the specific heats at successive temperatures on the absolute scale have been calculated, and it appears that the assumption of a constant atomic heat at absolute zero is untenable. The mean specific heat of a sample of nickel steel, containing 36 percent, of nickel and having remarkably small dilatation, was found to be as follows.


In the Bakerian Lecture for 1900 (‘Phil. Trans.,' A, vol. 194, p. 233) it was shown that the specific heats of very pure cobalt and nickel, when compared at temperatures from 100°C. down to the boiling-point of liquid oxygen, — 182°.5 C., steadily approach each other and together tend towards a least value which is at present unknown. It was thought desirable to increase the number of determinations at successive points on the thermometric scale, and to extend the total range of the experiments so as to afford better data for calculation of the form of the curves. The following is an account of the results obtained.


The present paper is occupied with an experimental investigation into the variation of the specific heat at constant volume of carbon dioxide attending change of absolute density. The investigation is in continuation of a previous one, in which Carbon Dioxide, Air, and Hydrogen were the subjects of a similar enquiry over low ranges of density. It appeared to me desirable to extend the observations more especially in the case of carbon dioxide, because of the extended knowledge we already possess of its isothermals, and the fact that its critical temperature is within convenient reach. Other physical properties of the gas have also received much attention of recent years. It is also readily procured in a nearly pure state. The observations recorded in this paper extend, in the one direction, to densities, such that liquid is present at the lower temperature; and in the other, to a junction with the highest densities of the former paper. A plotting of the new observations is in satisfactory agreement with the record of the old. It reveals, however, the fact that the linear nature of the variation of the specific heat with density, deduced from the former results, is not truly applicable over the new, much more extended range observation. For convenience the chart at the end of this paper embraces the former results, and the present paper is extended to include the entire results on the variation of specific heat with density where the range of temperature, obtaining at each experiment, is approximately the same: that from air temperature to 100° C.


1981 ◽  
Vol 11 (1) ◽  
pp. 44-46 ◽  
Author(s):  
D.P. Fourie

It is increasingly realized that hypnosis may be seen from an interpersonal point of view, meaning that it forms part of the relationship between the hypnotist and the subject. From this premise it follows that what goes on in the relationship prior to hypnosis probably has an influence on the hypnosis. Certain of these prior occurences can then be seen as waking suggestionns (however implicitly given) that the subject should behave in a certain way with regard to the subsequent hypnosis. A study was conducted to test the hypothesis that waking suggestions regarding post-hypnotic amnesia are effective. Eighteen female subjects were randomly divided into two groups. The groups listened to a tape-recorded talk on hypnosis in which for the one group amnesia for the subsequent hypnotic experience and for the other group no such amnesia was suggested. Thereafter the Stanford Hypnotic Susceptibility Scale was administered to all subjects. Only the interrogation part of the amnesia item of the scale was administered. The subjects to whom post-hypnotic amnesia was suggested tended to score lower on the amnesia item than the other subjects, as was expected, but the difference between the mean amnesia scores of the two groups was not significant.


1940 ◽  
Vol 36 (3) ◽  
pp. 314-322 ◽  
Author(s):  
R. d'E. Atkinson

The derivation given by Hoyle and Lyttleton for an accretion formula proposed by them is examined. A number of arguments against its validity are put forward, especially that on the one hand their capture radius depends on the theorem that if the velocity of certain masses of gas after collision is less than the velocity of escape at the point, they will not in fact escape, while on the other hand it is clear (and is now admitted) that the gas cannot in fact move with this velocity at all. It is also shown that since, ex hypothesi, the individual molecules will all, on the average, retain their hyperbolic velocities, there is not the compelling reason for their capture that there appeared to be in Hoyle and Lyttleton's argument, where only the mean radial velocity of the centre of gravity of the mass was considered. Further, it seems improbable that the temperature of the interstellar matter can be low enough for the initial assumptions of their theory to hold.


1990 ◽  
Vol 25 (2) ◽  
pp. 277-283
Author(s):  
G. C. Rock ◽  
R. E. Stinner

Effects of constant temperatures of 10, 15, 20, 25, 30 and 35°C on the preoviposition period and the effects of a constant 25°C on oviposition, fecundity, and longevity of the redbanded leafroller, Argyrotaenia velutinana (Walker), and the tufted apple bud moth, Platynota idaeusalis (Walker), were investigated. Oviposition did not occur at 35°C for either species and only the redbanded leafroller oviposited at 10°C. The threshold for oviposition for RBLR was calculated to be 8.7°C with 29.4 DD necessary for oviposition, while the oviposition threshold for TABM was calculated to be 10.5°C with 33.5 DD needed for oviposition. The mean oviposition periods for the two species did not differ; however, tufted apple bud moth longevity was significantly greater at 25°C. Fecundity was greater for the tufted apple bud moth (301 eggs/female) than for the redbanded leafroller (221 eggs/female).


1976 ◽  
Vol 31 (1) ◽  
pp. 90-101 ◽  
Author(s):  
Peter Lamparter ◽  
Siegfried Steeb ◽  
Walter Knoll

Neutron diffraction work (λ = 0.695 Å) was done with molten Bi-Sb-alloys in the temperature range between 550 and 750 °C. Furthermore molten Bi was investigated at 300 °C. The interference functions show subsidiary maxima especially for alloys with higher Sb-concentrations. Evaluation yields, that the melts contain two different kinds of structure:a) The one kind shows coordination number 9 and a statistical distribution of the atoms of two components. This kind is more inetal-like.b) The other kind shows coordination number 3, consists of non-centered tetrahedra with smaller nearest neighbour distance. It shows covalent binding.In molten Sb the nearest neighbour distance amounts up to 3.16 - 3.19 Å for theo ne kind and up to 2.64 -2.78 Å fort he other kind, which yields an mean distance of 2.99 Å, which was observed. The dependence of the concentration of the statistical kind of meld, of the (Sb)4-, and the (Bi)4-kind from the concentration of the whole melt is given.By the model described the run of the measured mean coordination number and the mean distance versus concentration can be well explained.


2000 ◽  
Vol 32 (2) ◽  
pp. 363-375
Author(s):  
Marie-Ange Remiche

The isotropic planar point processes of phase-type are natural generalizations of the Poisson process on the plane. On the one hand, those processes are isotropic and stationary for the mean count, as in the case of the Poisson process. On the other hand, they exhibit dependence of counts in disjoint sets. In a recent paper, we have proved that the number of points in a square window has a Poisson distribution asymptotically as the window is located far away from the origin of the process. We extend our work to the case of a window of arbitrary shape.


Keyword(s):  
The Mean ◽  

From the Tables here given, the author draws the following conclusions:— 1 The barometer is higher under the lunar apogee, than under the perigee; the mean height in the former case being 29·84517, and in the latter, 29·75542. 2. The mean temperature is lower under the apogee than under the perigee; that of the former being 48°·7126, and of the latter, 49°·0356. The mean of the whole year was 48°·7126. 3. The rain of the weeks following the apsis exceeds that under the perigee; but with two striking exceptions in the annual result of nine years, the one in the wettest, and the other in the driest year of the cycle.


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