Size and temperature effects on the thermoelectric power and electrical resistivity of bismuth telluride thin films

1988 ◽  
Vol 37 (9) ◽  
pp. 4552-4559 ◽  
Author(s):  
V. Damodara Das ◽  
N. Soundararajan



2006 ◽  
Vol 60 (17-18) ◽  
pp. 2059-2065 ◽  
Author(s):  
P.G. Ganesan ◽  
V. Damodara Das




Author(s):  
Koji Miyazaki ◽  
Jun-Ichiro Kurosaki ◽  
Masayuki Takashiri ◽  
Bertrand Lenoir ◽  
Hiroshi Tsukamoto

In this study, we fabricated bismuth-telluride thin films and their in-plane thermoelectric micro-coolers (4mm×4mm) by using the flash evaporation method. We prepared fine powders of Bi2.0Te2.7Se0.3 (n-type) and Bi0.4Te3.0Sb1.6 (p-type). The thermoelectric properties of as-grown thin films are lower than those of bulk materials. Therefore the as-grown thin films were annealed in hydrogen at atmospheric pressure for 1 hour in a temperature range of 200 to 400°C. By optimizing the annealing temperature, thin films with high thermoelectric power factors of 8.8 μW/(cm·K2) in n-type and 13.8 μW/(cm·K2) in p-type are obtained. To evaluate the figure of merit of the thin film, the thermal conductivity of the n-type thin film is measured by the 3ω method. The thin film annealed at 200 °C exhibited a cross-plane thermal conductivity of 1.2 W/(m·K). Micro-coolers of flash-evaporated bismuth-telluride thin films are fabricated using three shadow masks. The shadow masks are prepared by standard micro-fabrication processes such as nitridation of Si, dry etching, and wet etching. Thermoelectric power of the as-grown thin film devices with 16 pairs of p-n legs are measured by YAG laser heating at the center of the devices. The thermoelectric power of thermoelectric legs is evaluated to be 180μV/K per one p-n leg pair. According to the Kelvin’s law, it corresponds to 54mV Peltier coefficient per p-n pair.



1983 ◽  
Vol 54 (2) ◽  
pp. 977-981 ◽  
Author(s):  
V. Damodara Das ◽  
Jyotish Chandra Mohanty


Sb-Se thin films of varying composition have been deposited on glass substrates at room temperature. These films were annealed at temperature interval of 50 0K. The electrical resistivity (ρ) and thermoelectric power (α) of same films were measured. The resistance of semiconducting films decreases rapidly on heating showing negative temperature coefficient of resistance (T.C.R.). The composition dependent resistivity shows exponential change, sharp fall of resistivity may be attributed due to increase of metallic ‘Sb’ in Sb-Se thin films. The composition dependent activation energy of Sb-Se thin films has been calculated. The activation energy (∆E) of semiconducting films was found to increase with selenium concentration. For different compositions thermoelectric power (α) increases upto 70 at. wt.% of Se concentration and then slowly decreases. The I-V characteristics of Sb-Se thin films were measured using copper (Cu) contacts. The films show ohmic conduction for different applied voltages as well as various concentrations of Selenium (Se) in Sb-Se thin films



2001 ◽  
Author(s):  
Elena I. Rogacheva ◽  
Olga N. Nashchekina ◽  
Irina A. Korzh ◽  
Lidiya G. Voinova ◽  
Igor M. Krivulkin


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