scholarly journals Exponential volume dependence of entropy-current fluctuations at first-order phase transitions in chemical reaction networks

2020 ◽  
Vol 102 (2) ◽  
Author(s):  
Basile Nguyen ◽  
Udo Seifert
Soft Matter ◽  
2021 ◽  
Author(s):  
Jonas Heckel ◽  
Fabio Batti ◽  
Robert T. Mathers ◽  
Andreas Walther

Out-of-equilibrium phase transitions driven by dissipation of chemical energy are a common mechanism for morphological organization and temporal programming in biology. Inspired by this, dissipative self-assembly utilizes chemical reaction networks...


2009 ◽  
Vol 15 (5) ◽  
pp. 578-597
Author(s):  
Marcello Farina ◽  
Sergio Bittanti

Author(s):  
L. T. Pawlicki ◽  
R. M. Siegoczyński ◽  
S. Ptasznik ◽  
K. Marszałek

AbstractThe main purpose of the experiment was a thermodynamic research with use of the electric methods chosen. The substance examined was olive oil. The paper presents the resistance, capacitive reactance, relative permittivity and resistivity of olive. Compression was applied with two mean velocities up to 450 MPa. The results were shown as functions of pressure and time and depicted on the impedance phase diagram. The three first order phase transitions have been detected. All the changes in material parameters were observed during phase transitions. The material parameters measured turned out to be the much more sensitive long-time phase transition factors than temperature. The values of material parameters and their dependence on pressure and time were compared with the molecular structure, arrangement of molecules and interactions between them. Knowledge about olive oil parameters change with pressure and its phase transitions is very important for olive oil production and conservation.


2021 ◽  
Author(s):  
Samuel M. Blau ◽  
Hetal D Patel ◽  
Evan Walter Clark Spotte-Smith ◽  
Xiaowei Xie ◽  
Shyam Dwaraknath ◽  
...  

Modeling reactivity with chemical reaction networks could yield fundamental mechanistic understanding that would expedite the development of processes and technologies for energy storage, medicine, catalysis, and more. Thus far, reaction...


2020 ◽  
Vol 2020 (12) ◽  
Author(s):  
Francesco Bigazzi ◽  
Alessio Caddeo ◽  
Aldo L. Cotrone ◽  
Angel Paredes

Abstract Using the holographic correspondence as a tool, we study the dynamics of first-order phase transitions in strongly coupled gauge theories at finite temperature. Considering an evolution from the large to the small temperature phase, we compute the nucleation rate of bubbles of true vacuum in the metastable phase. For this purpose, we find the relevant configurations (bounces) interpolating between the vacua and we compute the related effective actions. We start by revisiting the compact Randall-Sundrum model at high temperature. Using holographic renormalization, we compute the derivative term in the effective bounce action, that was missing in the literature. Then, we address the full problem within the top-down Witten-Sakai-Sugimoto model. It displays both a confinement/deconfinement and a chiral symmetry breaking/restoration phase transition which, depending on the model parameters, can happen at different critical temperatures. For the confinement/deconfinement case we perform the numerical analysis of an effective description of the transition and also provide analytic expressions using thick and thin wall approximations. For the chiral symmetry transition, we implement a variational approach that allows us to address the challenging non-linear problem stemming from the Dirac-Born-Infeld action.


2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Yuchi He ◽  
Kang Yang ◽  
Mark Oliver Goerbig ◽  
Roger S. K. Mong

AbstractIn recent experiments, external anisotropy has been a useful tool to tune different phases and study their competitions. In this paper, we look at the quantum Hall charge density wave states in the N = 2 Landau level. Without anisotropy, there are two first-order phase transitions between the Wigner crystal, the 2-electron bubble phase, and the stripe phase. By adding mass anisotropy, our analytical and numerical studies show that the 2-electron bubble phase disappears and the stripe phase significantly enlarges its domain in the phase diagram. Meanwhile, a regime of stripe crystals that may be observed experimentally is unveiled after the bubble phase gets out. Upon increase of the anisotropy, the energy of the phases at the transitions becomes progressively smooth as a function of the filling. We conclude that all first-order phase transitions are replaced by continuous phase transitions, providing a possible realisation of continuous quantum crystalline phase transitions.


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