Synthesis and crystal structure of a new alluaudite-like iron phosphate Na2CaMnFe(PO4)3
2016 ◽
Vol 72
(12)
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pp. 1806-1808
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Keyword(s):
A new iron phosphate, disodium calcium manganese(II) iron(III) tris(phosphate), Na2CaMnFe(PO4)3, has been synthesized as single crystals by the flux technique. This compound crystallizes in the monoclinic space groupC2/c. The structure belongs to the alluaudite structural type and thus, it obeys theX(2)X(1)M(1)M(2)2(PO4)3general formula. Both theX(2) andX(1) sites are fully occupied by sodium, whileM(1) is occupied by calcium andM(2) exhibits a statistical distribution of iron and manganese.
1997 ◽
Vol 52
(1)
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pp. 102-106
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Keyword(s):
1994 ◽
Vol 49
(10)
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pp. 1329-1333
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1990 ◽
Vol 45
(2)
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pp. 107-110
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2015 ◽
Vol 70
(3)
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pp. 191-196
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1993 ◽
Vol 48
(7)
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pp. 1009-1012
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2011 ◽
Vol 66
(8)
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pp. 868-870
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Keyword(s):